Inhibited Polymerization of N,N,N-Trimethylammonioethyl Methacrylate Methyl Sulfate

The kinetic features of initiation of N,N,N-trimethylammonioethyl methacrylate methyl sulfate polymerization in the presence of manganese(III) bis(acetylacetonate) nitrate and p-nitrosoaniline were studied by the inhibited polymerization method. The kinetic parameters of initiation were calculated, and participation of the monomer in the initiation stage was established.     

Study of Polymerization of Ammonium Salts of N,N-Dimethylaminoethyl Methacrylate by Differential Scanning Calorimetry

The kinetics of thermal polymerization of ammonium salts of N,N-dimethylaminoethyl methacrylate and mineral acids (HCl, HNO₃, H₂SO₄, and H₃PO₄) were studied by dynamic differential scanning calorimetry. The apparent rate constants, reaction orders, and thermal effect of polymerization of the salts were determined.     

Copolymerization of Vinyl Monomers with Different Water Solubilities in the Presence of Manganese Sulfonate Complexes

Mixed-ligand Mn(III) complexes were prepared from manganese tris(acetylacetonate) and alkyl- benzenesulfonic acid, and their surface activity and initiating power with respect to polymerization of vinyl monomers differing in reactivity and water solubility were studied.