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A combined standardless method (no calibration of the device against standard solutions or use of the method of additives is required) for determination of lead, copper, and cadmium in aqueous solutions is suggested. The method operates on principles of inversion voltammetry and potentiostatic coulometry. It is convenient for automated analysis of technological solutions and wastewater from electroplating and hydrometallurgical shops. 相似文献
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D. N. Kolomiets I. D. Troshkina M. F. Sheremet’ev L. V. Konopleva 《Russian Journal of Applied Chemistry》2005,78(5):722-726
The equilibrium and kinetic characteristics of uranium sorption from simulated sulfuric acid leaching solutions by AMP, Lewatit K 6367, Purolite A 500, Purolite A 600, and AM-p gel-like and porous strongly basic anion exchangers were studied.__________Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 5, 2005, pp. 736–740.Original Russian Text Copyright © 2005 by Kolomiets, Troshkina, Sheremet’ev, Konopleva. 相似文献
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G. V. Kuznetsov V. I. Maksimov M. A. Sheremet 《Journal of Applied Mechanics and Technical Physics》2013,54(4):588-595
An experimental and numerical analysis was performed to investigate the laminar regimes of conjugate thermogravitational convection in a closed parallelepiped with heat-conducting walls of finite thickness in the presence of a local energy source with convective heat exchange with the environment. The numerical studies were performed using the Fluent software. The experimental data and numerical results agree well each other. 相似文献
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The effect of surface tension on laminar natural convection in a vertical cylindrical cavity filled with a weak evaporating liquid has been analyzed numerically. The cylindrical enclosure is insulated at the bottom, heated by a constant heat flux from the side, and cooled by a non-uniform evaporative heat flux from the top free surface having temperature-dependent surface tension. Governing equations with corresponding boundary conditions formulated in dimensionless stream function, vorticity, and temperature have been solved by finite difference method of the second-order accuracy. The influence of Rayleigh number, Marangoni number, and aspect ratio on the liquid flow and heat transfer has been studied. Obtained results have revealed that the heat transfer rate at free surface decreases with Marangoni number and increases with Rayleigh number, while the average temperature inside the cavity has an opposite behavior; namely, it growths with Marangoni number and reduces with Rayleigh number. 相似文献
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O. S. Mishina M. Scherman P. Lombardi J. Ortalo D. Felinto A. S. Sheremet D. V. Kupriyanov J. Laurat E. Giacobino 《Optics and Spectroscopy》2011,111(4):583-588
Electromagnetically induced transparency (EIT) has led to several quantum optics effects such as lasing without inversion
or squeezed light generation. More recently quantum memories based on EIT have been experimentally implemented in different
systems such as alkali metal atoms. In this system the excited state of the optical transition splits into several sublevels
due to the hyperfine interaction. However, most of the theoretical models used to describe the experimental results are based
on a Λ-system with only one excited state. In this article, we present a theoretical model for the Λ-type interaction of two
light, fields and an atomic system with multiple excited state. In particular we show that if the control and probe fields
are orthogonally circularly polarized the EIT effect in an alkali-metal vapor can almost disappears. We also identify the
reasons of this reduction and propose a method to recover the transparency via velocity selective optical pumping. 相似文献
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Biology‐Oriented Synthesis of a Withanolide‐Inspired Compound Collection Reveals Novel Modulators of Hedgehog Signaling 下载免费PDF全文
Dr. Jakub Švenda Dipl.‐Biochem. Michael Sheremet M. Sc. Lea Kremer Lukáš Maier Dr. Jonathan O. Bauer Prof. Dr. Carsten Strohmann Dr. Slava Ziegler Dr. Kamal Kumar Prof. Dr. Herbert Waldmann 《Angewandte Chemie (International ed. in English)》2015,54(19):5596-5602
Biology‐oriented synthesis employs the structural information encoded in complex natural products to guide the synthesis of compound collections enriched in bioactivity. The trans‐hydrindane dehydro‐δ‐lactone motif defines the characteristic scaffold of the steroid‐like withanolides, a plant‐derived natural product class with a diverse pattern of bioactivity. A withanolide‐inspired compound collection was synthesized by making use of three key intermediates that contain this characteristic framework derivatized with different reactive functional groups. Biological evaluation of the compound collection in cell‐based assays that monitored biological signal‐transduction processes revealed a novel class of Hedgehog signaling inhibitors that target the protein Smoothened. 相似文献
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The Michael-type addition of dimedone and dihydroresorcinol to β,β-dinitrostyrenes occurs easily without a catalyst. The adducts
cyclize into 3-aryl-2-nitro-2,3,4,5,6-hexahydrobenzofuran-4-ones under the action of triethylamine. 相似文献