Photocatalytic decolorization of methyl orange solution with potassium peroxydisulfate

Increasing environmental pollution caused by toxic dyes due to their hazardous nature is a matter of great concern. It has been generally agreed that methyl orange (MO) can be effectively degraded in aerated K₂S₂O₈ homogeneous reaction system using near-UV irradiation. In this paper photocatalytic degradation of MO solutions with K₂S₂O₈ was investigated, with particular attention on the possible underlying mechanisms. This report has shown decolorization efficiency of MO increases with the increasing of the dosage of the catalyst. There is no optimal amount of catalyst in our case, where special attention was paid on the nature of the photocatalyst itself. The current research revealed that the decolorization reaction is a pseudo first-order reaction when the concentration of MO is below 20 mg L⁻¹ and the decolorization reaction is zero-order reaction when the concentration of MO is above 100 mg L⁻¹, but the Langmuir-Hinshewood kinetic model does not describe this. The influence of IO₄⁻, BrO₃⁻ and H₂O₂ were investigated in detailed. Several observations indicate that the mechanism is not involved in hydroxyl radical attacks in MO degradation with K₂S₂O₈ by UV irradiation. The possible underlying mechanisms are direct oxidation of the MO by S₂O₈²⁻ and hydrogen attraction by SO₄^•−.      

导管架海洋平台自振特性的简化计算方法

本文提出一个方程中考虑剪切、弯曲、转动惯量效应,而其它如塔架形状变化,平台面转动惯量及台面集中质量变化等其它影响因素均以修正系数方法确定,给出平台基本频率的简化算法。     

高效液相色谱法测定硝苯柳胺含量

硝苯柳胺是合成筛选出来的一种新杀螺剂。经实验探索,以３,５－二硝基苯甲酸作内标,采用并建立了高效液相色谱法测定合成物中硝苯柳胺的含量。方法简便、准确,灵敏度高。     

低乙烯基聚丁二烯橡胶的合成和表征

以钴催化体系为催化剂,用两步聚合法合成了1,2-链节含量范围在7—16%的低乙烯基聚了二烯橡胶。对聚合产物的表征结果表明,聚合物中存在着间同1,2-聚丁二烯的微晶,这些微晶起晶种的作用,能促进产物在低温下的结晶;当胶中1,2-链节含量小于10%时,不溶于CS₂的级分较少,加入1,2-聚合催化剂后主要生成顺1,4-间同1,2-丁二烯嵌段共聚物;当1,2-链节含量高于10%时,CS₂不溶物量较多,这时除上述嵌段物外尚可能生成少量间同1,2-聚了二烯均聚物。     

Modification of bonding properties and microstructure of resin-cement interface by coupling agents

To solve the problem of organic-inorganic light conductive composite interface features, transparent resin and cement matrix were used as carriers to further study features of the organic-inorganic interface formed by transparent resin and cement matrix and the interface modification of the coupling agent. The bond strength, micro-hardness, microstructure and surface morphology of a resin light conductive cementitious materials (RLCCM) interface were evaluated by tests of tensile and oblique shear, micro-hardness, environmental scanning electron microscopy, and atomic force microscope. The results show that the silane A-151 and aluminate coupling agent could significantly improve interface bond properties of RLCCM. At 7 d, the interface tensile bond strength of the silane A-151 and aluminate coupling agent increased by 117 and 105%, respectively. At 28 d, strength on average increased by 73%. At 7 d, interface shear strength the silane A-151 and aluminate coupling agent of 45° increased by 43 and 53%, respectively, At 28 d, strength on average increased by 40%. The transparent resin performance weakened region thickness up to 100 μm; the hardness of the transparent resin in the transition region was increased by 19.6 and 39.9%, respectively. Silane coupling agent A-151 and cement hydration products formed flat spherical particles with diameter of approximately 78 nm, and these particles mosaicked and fused in the surface of the hydrate; therefore, the surface became denser and smoother.     

水平井变质量流研究进展

综述了水平井筒沿管壁具有流体流入的变质量流动的最新研究进展.内容包括:考虑油藏流体流入时井筒流动压力及产量的计算,具有不同流入时管壁摩擦系数的经验计算公式,以及流体径向流入井筒后流动阻力损失产生的机理分析等.重点介绍了水平井筒变质量流动阻力系数的计算,同时文中还介绍了井筒两相变质量流动损失产生的机理和数值模拟研究进展.      

τ质量测量方案的Monte Carlo研究

在τ质量实验测量之前对多种测量方案进行了细致的Monte Carlo研究,并进行了比较.确定τ质量测量实验采用最大似然法,并给出可能的测量精度.研究了包括探测效率、束流能散等诸多因素对实验的影响,同时对实验的实现提出要求.