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Synthesis and Characterization of New Xanthene Derivatives,and Their Electrochemical Study
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This work investigated the synthesis of biphenyl‐3,3′,4,4′‐tetracarboxylic dianhydride and benzophenone‐3,3′,4,4′‐tetracarboxylic dianhydride derivatives ( 3a – e and 6a – e ) with different substituted phenols via Friedel‐Crafts acylation reaction in the presence of dilute sulfuric acid. Dianhydride derivatives with 3‐N,N′‐dimethylamino phenol ( 3d and 6d ) and resorcinol ( 3e and 6e ) have been found to be highly fluorescent. The structures of all newly synthesized compounds were confirmed by the chromatographic, spectral and elemental data. Electrochemical study was done to determine to band gap energy, LUMO and HOMO levels energy. Band gap and LUMO energy levels were found to be lowest in xanthene derivatives substituted with 3‐N,N′‐dimethylamino group having value 2.24 and 4.85 eV respectively. 相似文献
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Muhammad Waqas Huai-Min Chen Guang-Xiong Peng Abd Al Karim Haj Ismail Muhammad Ajaz Zafar Wazir Ramoona Shehzadi Sabiha Jamal Atef AbdelKader 《Entropy (Basel, Switzerland)》2021,23(10)
We used the blast wave model with the Boltzmann–Gibbs statistics and analyzed the experimental data measured by the NA61/SHINE Collaboration in inelastic (INEL) proton–proton collisions at different rapidity slices at different center-of-mass energies. The particles used in this study were , , , , and . We extracted the kinetic freeze-out temperature, transverse flow velocity, and kinetic freeze-out volume from the transverse momentum spectra of the particles. We observed that the kinetic freeze-out temperature is rapidity and energy dependent, while the transverse flow velocity does not depend on them. Furthermore, we observed that the kinetic freeze-out volume is energy dependent, but it remains constant with changing the rapidity. We also observed that all three parameters are mass dependent. In addition, with the increase of mass, the kinetic freeze-out temperature increases, and the transverse flow velocity, as well as kinetic freeze-out volume decrease. 相似文献
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Chekanov S Derrick M Magill S Musgrave B Nicholass D Repond J Yoshida R Mattingly MC Antonioli P Bari G Bellagamba L Boscherini D Bruni A Bruni G Cindolo F Corradi M Iacobucci G Margotti A Nania R Polini A Antonelli S Basile M Bindi M Cifarelli L Contin A De Pasquale S Sartorelli G Zichichi A Bartsch D Brock I Hartmann H Hilger E Jakob HP Jüngst M Nuncio-Quiroz AE Paul E Samson U Schönberg V Shehzadi R Wlasenko M Brook NH Heath GP Morris JD Capua M Fazio S Mastroberardino A Schioppa M Susinno G 《Physical review letters》2008,101(11):112003
Inclusive K_{S};{0}K_{S};{0} production in ep collisions at the DESY ep collider HERA was studied with the ZEUS detector using an integrated luminosity of 0.5 fb;{-1}. Enhancements in the mass spectrum were observed and are attributed to the production of f_{2}(1270)/a_{2};{0}(1320), f_{2};{'}(1525) and f_{0}(1710). Masses and widths were obtained using a fit which takes into account theoretical predictions based on SU(3) symmetry arguments, and are consistent with the Particle Data Group values. The f_{0}(1710) state, which has a mass consistent with a glueball candidate, was observed with a statistical significance of 5 standard deviations. However, if this state is the same as that seen in gammagamma-->K_{S};{0}K_{S};{0}, it is unlikely to be a pure glueball state. 相似文献
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Channar Pervaiz Ali Arshad Nasima Farooqi Shahid Iqbal Larik Fayaz Ali Saeed Aamer Hökelek Tuncer Shehzadi Syeda Aaliya Abbas Nasir Flörke Ulrich 《Applied biochemistry and biotechnology》2019,189(1):175-192
Applied Biochemistry and Biotechnology - (E)-2-(3-Hydroxy-4-methoxybenzylidene)hydrazinecarbothioamide 3 was synthesized by reacting thiosemicarbazide with 2-hydorxy-3-methoxybenzaldehyde in dry... 相似文献
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Sajida Parveen Nadeem Irfan Bukhari Naureen Shehzadi Shaista Qamar Ejaz Ali Surriya Naheed 《Natural product research》2019,33(6):858-861
Recently, a traditional remedy (Joshanda) has been replaced largely by modern ready-to-use dosage forms, which have not been compared to the original remedy. Therefore, the present study aimed to compare a number of modern dosage forms with traditional remedy. Seven brands, 3 batches each, were compared with a Lab-made formulation with reference to analytical (proximate analyses, spectroscopic and chromatographic metabolomes) and pharmacological profiles (anti-inflammatory and antibacterial activities). Chemical and pharmacological differences were found between Lab-made Joshanda and modern dosage forms. Such variations were also found within the brands and batches of modern formulations (p < 0.05). The Lab-made Joshanda showed significantly higher pharmacological activities as compared to modern brands (p ). The results of the present study indicate that modern dosage forms are unstandardised and less effective than the traditional remedy. Characteristic profiles obtained from Lab-made Joshanda may be used as reference to produce comparable dosage forms. 相似文献
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