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Bodrikov I. V. Sazhin A. A. Shebelova I. Yu. Subbotin A. Yu. Rybalova T. V. Gatilov Yu. V. Barkhash V. A. 《Russian Journal of Organic Chemistry》2002,38(8):1105-1112
In reaction of unsaturated compounds with sulfur dichloride in the presence of dimethyl sulfide radically new induced directions are realized: the reagent is involved as dimer or trimer (formation of di- and trisulfides). Alongside this process a conjugate chlorination occurred with participation of external nucleophiles, dimethyl sulfide and acetonitrile, furnishing sulfonium chlorides and N-substituted acetamides respectively. The relative importance of these alternative reactions depends on solvent, alkene structure, and order of reagents addition. 相似文献
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