排序方式: 共有2条查询结果,搜索用时 0 毫秒
1
1.
Litsis Olena O. Shatrava Iuliia O. Amirkhanov Oleksiy V. Ovchynnikov Vladimir A. Sliva Tatiana Yu. Shishkina Svetlana V. Dyakonenko Viktoriya V. Shishkin Oleg V. Amirkhanov Vladimir M. 《Structural chemistry》2016,27(1):341-355
Structural Chemistry - The new carbacylamidophosphate derivative HL1 (1) with general formula Cl3CC(O)N(H)P(O)(CH2C5H4N)2 named... 相似文献
2.
Iu. Shatrava V. Ovchynnikov K. Gubina S. Shishkina O. Shishkin V. Amirkhanov 《Structural chemistry》2016,27(5):1413-1425
A series of new 3d metal complexes based on dimethyl pyridin-2-ylcarbamoylphosphoramidate (HL) was synthesized. The compounds with general formula M(HL)2Cl2·nH2O and M(L)2·nH2O (M=Co2+, Cu2+, Ni2+) were characterized by means of single-crystal X-ray analysis and IR spectroscopy. The organic ligands in all complexes are coordinated via oxygen atom of the carbonyl group and nitrogen atom of the heterocycle. The coordination environment of the central atoms is a distorted octahedron. The axial positions in the Co(II) and Ni(II) complexes with deprotonated ligands are occupied by water molecules. The Co(II) and Cu(II) complexes with phosphoryl ligands in a neutral form have different ligands in the axial positions: in the Co(II) complex, the positions are occupied by two water molecules, whereas in the Cu(II) complex, the positions are occupied by two chlorine anions. The structure of HL was experimentally and theoretically obtained by utilizing single-crystal X-ray analysis and DFT calculations. The computationally optimized geometric parameters for HL show a good agreement with the experimental results. 相似文献
1