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排序方式: 共有2705条查询结果,搜索用时 15 毫秒
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Shaobo Cheng Vidushi Sharma Altug S. Poyraz Lijun Wu Xing Li Amy C. Marschilok Esther S. Takeuchi Kenneth J. Takeuchi Marivi Fernndez-Serra Yimei Zhu 《Chemical science》2020,11(19):4991
Tunneled metal oxides such as α-Mn8O16 (hollandite) have proven to be compelling candidates for charge-storage materials in high-density batteries. In particular, the tunnels can support one-dimensional chains of K+ ions (which act as structure-stabilizing dopants) and H2O molecules, as these chains are favored by strong H-bonds and electrostatic interactions. In this work, we examine the role of water molecules in enhancing the stability of K+-doped α-Mn8O16 (cryptomelane). The combined experimental and theoretical analyses show that for high enough concentrations of water and tunnel-ions, H2O displaces K+ ions from their natural binding sites. This displacement becomes energetically favorable due to the formation of K2+ dimers, thereby modifying the stoichiometric charge of the system. These findings have potentially significant technological implications for the consideration of cryptomelane as a Li+/Na+ battery electrode. Our work establishes the functional role of water in altering the energetics and structural properties of cryptomelane, an observation that has frequently been overlooked in previous studies.Water displaces potassium ions and initiates the formation of a homonuclear dimer ion (K2+) in the tunnels of hollandite. 相似文献
3.
An experimental method for determining the real-time depth of laser-drilled holes is presented. The proposed method involves
detecting the laser-induced optoacoustic waves generated during the interaction of the laser beam with the material. Our optodynamic
study involved measuring the propagation times of these waves as they traveled through the material and analyzing their temporal
behavior during the drilling process. The experimental observations revealed an exponential relationship between the propagation
time of the longitudinal stress wave and the number of consecutive laser pulses.
Received: 25 October 2001 / Accepted: 27 October 2001 / Published online: 20 December 2001 相似文献
4.
一类具有非局部反应扩散方程的奇摄动问题 总被引:7,自引:0,他引:7
本文讨论一类具非局部反应扩散方程的奇摄动初始边值问题,利用迭代法及微分不等式,研究了初始边值问题的存在唯一及其渐近性态。 相似文献
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具有非局部边界条件的奇摄动反应扩散问题 总被引:2,自引:0,他引:2
本文研究了一类具有非局部边界条件的奇摄动反应扩散初始边值问题.在适当的条件下,利用比较定理讨论了问题解的渐近性态. 相似文献
8.
针对高功率二极管重复率抽运的V型非稳腔Yb3+∶YAG激光头,提出了利用金刚石窗口冷却和直接水冷相结合的复合冷却设计.在YAG片的抽运面进行直接水冷,同时在激光提取面利用金刚石窗口冷却介质.金刚石优异的导热性能不仅能够有效地冷却激光介质,还能消除横向的温度梯度,解决了高功率激光器冷却和高功率抽运的矛盾.模拟结果表明对掺杂10 at %厚度为1.6 mm的Yb3+∶YAG片在抽运功率密度为20 kW/cm2,重复频率为10 Hz的条件下,要将最高温度控制在可接受的范围内(比如320 K),周围冷却水的对流换热系数约为4000 W/m2K. 相似文献
9.
This paper discusses a kind of optimization problem with linear complementarity constraints, and presents a sequential quadratic
programming (SQP) algorithm for solving a stationary point of the problem. The algorithm is a modification of the SQP algorithm
proposed by Fukushima et al. [Computational Optimization and Applications, 10 (1998),
5-34], and is based on a reformulation of complementarity condition as a system of linear equations. At each iteration,
one quadratic programming and one system of equations needs to be solved, and a curve search is used to yield the step size.
Under some appropriate assumptions, including the lower-level strict complementarity, but without the upper-level strict
complementarity for the inequality constraints, the algorithm is proved to possess strong convergence and superlinear convergence.
Some preliminary numerical results are reported. 相似文献
10.
THE ASYMPTOTIC SOLUTION FOR A CLASS OF SINGULARLY PERTURBED PROBLEM FOR SEMILINEAR SINGULAR EQUATION
The singularly perturbed boundary value problem for a class of semilinearsingular equation is considered. Using a simple and special method the asym-ptotic behavior of solution is studied. 相似文献