水雾化制备Fe74Al4Sn2P10C2B4Si4非晶合金粉末及其磁粉芯性能研究

采用水雾化方法制备Fe7Al4Sn2P10C2B4Si4合金粉末,研究发现该合金具有强的非晶形成能力和高热稳定性,在粉末粒度小于400目时可以形成非晶态合金.采用该非晶粉末制备的磁粉芯在高频下品质因数显著高于MPP粉芯,说明该磁粉芯高频损耗较低.分析表明,非晶合金磁粉芯高频下损耗低的主要原因是电阻率较高.     

Observation of macroscopic quantum tunneling in a single Bi2Sr2CaCu2O8+delta surface intrinsic Josephson junction

We report on the first unambiguous observation of macroscopic quantum tunneling (MQT) in a single submicron Bi(2)Sr(2)CaCu(2)O(8+delta) surface intrinsic Josephson junction (IJJ) by measuring its temperature-dependent switching current distribution. All relevant junction parameters were determined in situ in the classical regime and were used to predict the behavior of the IJJ in the quantum regime via MQT theory. Experimental results agree quantitatively with the theoretical predictions, thus confirming the MQT picture. Furthermore, the data also indicate that the surface IJJ, where the current flows along the c axis of the crystal, has the conventional sinphi current-phase relationship.     

Effect of carbon nanotubes addition on electrochemical performance and thermal stability of Li4Ti5O12 anode in commercial LiMn2O4/Li4Ti5O12 full-cell

Li₄Ti₅O₁₂ (LTO)/carbon nanotubes (CNTs) composite material is synthesized based on a solid-state method by sand-milling, spray-drying and calcining at 850 ℃ under N₂ flow. The LTO/CNTs samples with 1 wt% and 3 wt% weight ratio of CNTs addition and the pristine LTO sample are prepared. The rate performance and the thermal stability of these samples are investigated based on LiMn₂O₄ (LMO)/LTO full-cell. The results show that theweight ratio of CNTs addition has distinct effect on LTO performances. The composite materials of LTO composited CNTs have better performance at high-rate due to the intercalation enhancement by conductive network of CNTs. At second, the overcharging temperature response of the cell's surface with 1 wt% CNTs addition is the lowest. The particle size distribution is measured and the most uniform particles are obtained with 1 wt% CNTs addition. This trend could explain that the mediumquantity of CNTs is optimal to improve the heat and mass transfer and prevent the problems of crystallite growing interference and aggregation during the calcination process.     

铁基-铁镍基复合非晶态合金的磁性

用双喷嘴坩埚制备了非晶态合金Fe₇₈Si₉B₁₃和(FeNiCr)₇₈(SiB)₂₂的单层带材和复合带,并测量了两种合金的叠绕铁蕊和复合带铁蕊的热磁曲线和磁滞回线.对于两种合金的叠绕铁蕊,其磁滞回线呈峰腰型,类似于两种合金各自磁滞架线的平均值,但并不完全相同.对于复合带铁芯,其热磁曲线与两种合金热磁曲线的平均值基本重合,而磁滞回线不仅不再是蜂腰型,且非常扁平.叠绕铁芯和复合带铁芯磁滞回线的这种变化源于叠绕铁芯和复合带铁芯中的内应力.这种内应力产生的根本原因是两种材料热膨胀系数和磁致伸缩系数的差别. 关键词：     

Influence of reaction parameters on synthesis of high-quality single-layer graphene on Cu using chemical vapor deposition

Large-area monolayer graphene samples grown on polycrystalline copper foil by thermal chemical vapor deposition with differing CH4 flux and growth time are investigated by Raman spectra, scanning electron microscopy, atomic force microscopy, and scanning tunneling microscopy. The defects, number of layers, and quality of graphene are shown to be controllable through tuning the reaction conditions: ideally to 2–3 sccm CH4 for 30 minutes.     

A Series of Collaborations between Various Pharmaceutical Companies and Regulatory Authorities Concerning the Analysis of Biomolecules Using Capillary Electrophoresis: Additional Instruments/Buffer

An international project team (including members from US, Canada and UK) was formed from a number of interested biopharmaceutical companies and regulatory authorities to conduct a cross-organisation collaboration exercise. The results of the first comparison with eight different organisations that used instruments of the same equipment model, the same reagents, and the same methodology has been reported previously [1]. This report represents the addition of other instruments using a different run buffer. The relative migration times were different, as expected, prohibiting a direct comparison between companies. The within-organisation variability was low for both relative migration time (<0.34% RSD% for all companies save one) and the peak area (<5% RSD% for all companies save one) when measuring the purity of a representative IgG sample. The apparent molecular weight of bovine serum albumin was measured with good precision (less than 10% RSD% across all companies) to the theoretical value when all data is utilized (67.5 kDa compared to 66.4 kDa). For a representative IgG sample, the three main components, IgG Light Chain, IgG Non-glycosylated Heavy Chain, and IgG Heavy Chain, could not be separated, specifically the IgG Non-glycosylated Heavy Chain and IgG Heavy Chain. When the IgG Non-glycosylated Heavy Chain and IgG Heavy Chain were combined for all organisations, the fractional peak area for the IgG Light Chain and IgG Non-glycosylated Heavy Chain + IgG Heavy Chain peak also showed excellent agreement, with less than 7.5 and 3.5% RSD%, respectively. The value of this exercise is in demonstrating the reliability of CE for the determination of apparent size of biopharmaceutical proteins. This underpins the appropriate use of such CE data in support of regulatory submissions.     

Enantioselective conjugate addition of both aromatic ketones and acetone to nitroolefins catalyzed by chiral primary amines bearing multiple hydrogen-bonding donors

A new class of chiral primary amine catalysts bearing multiple hydrogen-bonding donors have been designed and synthesized. The newly developed bifunctional organocatalysts efficiently catalyzed not only enantioselective conjugate addition of aromatic ketones to nitroolefins in good yields (up to 87%) with excellent enantioselectivities (97→99% ee) but also enantioselective conjugate addition of acetone to nitroolefins in excellent yields (90-96%) with high enantioselectivities (up to 97% ee).     

磁性纳米四氧化三铁选择性富集-电感耦合等离子体原子发射光谱测定砷

基于磁性纳米Fe3O4对砷的选择性富集作用,建立了电感耦合等离子体原子发射光谱(ICP-OES)测定水溶液中砷的方法.考察了溶液酸度、吸附时间、吸附剂用量、试液体积和共存离子等因素对不同形态砷分离富集效率的影响.结果表明,在pH 2～10范围内,选用6.0 mg纳米Fe3O4定量富集,振荡2 min后,三价砷、五价砷、一甲基砷以及二甲基砷等均可被磁性纳米Fe3O4定量富集.线性范围为0.063～20 mg/L; 检出限(3σ)为0.0189 mg/L; 对砷标准溶液测定的相对标准偏差为1.27%(n=6).用本方法对自来水中加入的砷标准溶液进行了测定,回收率为100.3%～104.8%.本方法简便快速,可用于复杂基体中低含量砷的富集分离和测定.     

Quantitative study of macroscopic quantum tunneling in a dc SQUID: a system with two degrees of freedom

To test whether the theory of macroscopic quantum tunneling (MQT) is applicable to systems with 2 degrees of freedom, we experimentally investigated the switching current distribution of a dc SQUID. Using sample parameters determined from measurements at T=4.2 K, we are able to make quantitative comparison to the theories from 8 mK to 4.2 K. The excellent agreement between the data and the MQT theory demonstrates that tunneling from the zero-voltage state of the dc SQUID is well described by the quantum mechanics.     

纳米结构SmCo/FeCo多层薄膜的磁性

研究了用磁控溅射方法制备的纳米结构Sm₂₂Co₇₈单层膜、Sm₂₂Co₇₈/Fe₆₅Co₃₅双层膜及Sm₂₂Co₇₈/Fe₆₅Co₃₅/Sm₂₂Co₇₈三层膜的磁性,特别是双层膜及三层膜系统中的Fe₆₅Co₃₅软磁层厚度d对薄膜剩磁比(M_r/M_s)和矫顽力(H_c)的影响.所有样品的磁滞回线测量表明,该系列薄膜的易磁化轴在膜面内.磁滞回线的单一硬磁相特征,说明SmCo硬磁层与FeCo软磁层之间的交换相互作用使两相很好地复合在一起.在双层膜和三层膜中,M_r/M_s随软磁层厚度d的增加单调上升,而矫顽力随d的变化出现一峰值.通过研究ΔM随磁场H的变化,发现随着软、硬磁相界面数的增加,ΔM曲线的正峰数量逐渐减少;负峰数量逐渐增强,负峰的半高宽逐渐减少. 关键词：