正交各向异性材料切口尖端热弹奇性特征分析

研究正交各向异性平面V形切口,计算其热弹奇性特征.通过引入切口尖端物理场的渐近级数展开式,将应力和热流平衡方程转化为关于奇性指数的特征常微分方程组,采用插值矩阵法求解,获取切口尖端的热流、应力奇性指数和对应的特征角函数.算例表明,该法精度高适应性强.     

Phase diagrams,mechanisms and unique characteristics of alternating-structured polymer self-assembly via simulations

Alternating-structured polymers(ASPs), like alternating copolymers, regular multiblock copolymers and polycondensates, are very important polymer structures with broad applications in photoelectric materials. However, their self-assembly behaviors,especially the self-assembly of alternating copolymers, have not been clearly studied up to now. Meanwhile, the unique characteristics therein have not been systematically disclosed yet by both experiments and theories. Herein, we have performed a systematic simulation study on the self-assembly of ASPs with two coil alternating segments in solution through dissipative particle dynamics(DPD) simulations. Several morphological phase diagrams were constructed as functions of different impact parameters. Diverse self-assemblies were observed, including spherical micelles, micelle networks, worm-like micelles, disklike micelles, multimicelle aggregates, bicontinuous micelles, vesicles, nanotubes and channelized micelles. Furthermore, a morphological evolutionary roadmap for all these self-assemblies was constructed, along with which the detailed molecular packing models and self-assembly mechanisms for each aggregate were disclosed. The ASPs were found to adopt a folded-chain mechanism in the self-assemblies. Finally, the unique characteristics for the self-assembly of alternating copolymers were revealed especially, including(1) ultra-fine and uniform feature sizes of the aggregates;(2) independence of self-assembled structures from molecular weight and molecular weight distribution;(3) ultra-small unimolecular aggregates. We believe the current work is beneficial for understanding the self-assembly of alternating structured polymers in solution and can serve as a guide for the further experiments.     

Emulsion‐Assisted Polymerization‐Induced Hierarchical Self‐Assembly of Giant Sea Urchin‐like Aggregates on a Large Scale

Hierarchical solution self‐assembly has become an important biomimetic method to prepare highly complex and multifunctional supramolecular structures. However, despite great progress, it is still highly challenging to prepare hierarchical self‐assemblies on a large scale because the self‐assembly processes are generally performed at high dilution. Now, an emulsion‐assisted polymerization‐induced self‐assembly (EAPISA) method with the advantages of in situ self‐assembly, scalable preparation, and facile functionalization was used to prepare hierarchical multiscale sea urchin‐like aggregates (SUAs). The obtained SUAs from amphiphilic alternating copolymers have a micrometer‐sized rattan ball‐like capsule (RBC) acting as the hollow core body and radiating nanotubes tens of micrometers in length as the hollow spines. They can capture model proteins effectively at an ultra‐low concentration (ca. 10 nm ) after functionalization with amino groups through click copolymerization.     

Efficient frequency doubling of a telecom 1560 nm laser in a waveguide and frequency stabilization to Rb D_2 line

We experimentally demonstrate efficient frequency doubling of a telecom 1560 nm distributed feedback diode laser with a 3 cm long MgO：PPLN waveguide with a conversion coefficient of 114%/W. We investigate optical inhomogeneities by measuring the quasi-phase-matching temperature curve. The -2.7 mW of second-harmonic power at 780 nm is sufficient to detect the Rb D2 features using modulation transfer spectroscopy. The laser frequency is locked to a hyperfine transition of Rb D2 line and typical residual frequency fluctuation of ＋86 kHz （rms） is achieved within 30 min. Our experimental scheme can be used for realizing robust, compact, and highly accurate Rb stabilized 1560 nm laser systems for fiber-optic communication applications.     

1560nm激光经PPLN和PPKTP晶体准相位匹配倍频研究

将1560nm光栅反馈复合腔半导体激光器产生的连续激光注入掺铒光纤放大器,放大至约5 W,分别采用周期极化铌酸锂(PPLN)和周期极化磷酸氧钛钾(PPKTP)晶体单次穿过进行准相位匹配倍频,对应获得约336mW和210mW的780nm激光输出,倍频效率约为7%和4.4%。通过监视倍频光纵模,显示其具有良好的单频输出特性。此外,还扫描测得了Rb原子D2线的吸收光谱,表明780nm激光的频率调谐范围大于10GHz。采用无调制偏振光谱技术将1560nm半导体激光器频率锁定至87 Rb 5S1/2(Fg=2)-5P3/2(Fe=3)超精细跃迁线上。相对于自由运转450s内1560nm激光频率起伏约4MHz,锁定后可将残余频率起伏压低至1.5MHz左右。     

MembrFactory: A Force Field and composition Double Independent Universal Tool for Constructing Polyamide Reverse Osmosis Membranes

The topmost polyamide (PA) layer of the thin-film-composite reverse osmosis (RO) membrane is the most important part in the membrane-based RO technology. With the aid of molecular dynamics simulations, many PA layer-related features in the RO process can be revealed. With many novel types of PA RO membranes out of trimesoyl chloride/m-phenylenediamine monomers developed in the laboratory, a convenient model building tool for these PA layer systems is urgently needed to conduct the theoretical analysis. Here, we develop a new universal toolkit for constructing PA RO membranes, named as MembrFactory, which combines flexibility of force fields and membrane compositions. A key characteristic of our approach is the use of monomers as the starting state, and the final membrane model was obtained automatically by stepwise reaction between the functional groups on the monomers. The reliability of MembrFactory has been validated by constructing several common PA RO membranes. © 2019 Wiley Periodicals, Inc.     

Copper doped ceria porous nanostructures towards a highly efficient bifunctional catalyst for carbon monoxide and nitric oxide elimination

Copper doped ceria porous nanostructures with a tunable BET surface area were prepared using an efficient and general metal–organic-framework-driven, self-template route. The XRD, SEM and TEM results indicate that Cu²⁺ was successfully substituted into the CeO₂ lattice and well dispersed in the CeO₂:Cu²⁺ nanocrystals. The CeO₂:Cu²⁺ nanocrystals exhibit a superior bifunctional catalytic performance for CO oxidation and selective catalytic reduction of NO. Interestingly, CO oxidation reactivity over the CeO₂:Cu²⁺ nanocrystals was found to be dependent on the Cu²⁺ dopants and BET surface area. By tuning the content of Cu²⁺ and BET surface area through choosing different organic ligands, the 100% conversion temperature of CO over CeO₂:Cu²⁺ nanocrystals obtained from thermolysis of CeCu–BPDC nanocrystals can be decreased to 110 °C. The porous nanomaterials show a high CO conversion rate without any loss in activity even after five cycles. Furthermore, the activity of the catalysts for NO reduction increased with the increase of BET surface, which is in accordance with the results of CO oxidation.     

Efficient generation of a continuous-wave,tunable 780 nm laser via an optimized cavity-enhanced frequency doubling of 1.56 µm at low pump powers

We present the strict design parameters of the experiment for the 780 nm tunable continuous-wave second harmonic (SH) generation by the nonlinear resonator containing a MgO doped periodically poled LiNbO₃ (MgO:PPLN) crystal. Optimization of such critical parameters, including focusing and impedance matching, more than 84% SH conversion efficiency and 3.1 W available output power at 780 nm were obtained from the fundamental wave at 1560 nm with two different input couplers. The thermal saturated behavior of the SH output power has been observed in the experiment. The beam quality factor M² of the generated SH wave is 1.04 (1.03), and the RMS power stability is 1.29% in 3 h. The SH wave was further used to detect the D ₂ transitions of Rb atom, exhibiting a fine tunable characteristic. Such laser source can be a suitable candidate in the atomic physics and quantum optics.     

Multilayer onion-like vesicles self-assembled from amphiphilic hyperbranched multiarm copolymers via simulation

Multilayer onion-like vesicles are valuable in cell mimics and biomedicine fields. However, as an excellent self-assembly precursor, the formation of multilayer onion-like vesicles by the self-assembly of hyperbranched multiarm copolymers (HMCs) were not reported due to the complex self-assembly dynamics. In this article, the self-assembly behavior of multilayer onion-like vesicles from HMCs was systematically investigated using dissipative particle dynamics simulation. The formation conditions for different kinds of vesicles were disclosed through the construction of the morphological phase diagram. Moreover, the formation mechanisms of the onion-like vesicles with different layers were revealed. We observed that it is the fusion mechanism in low concentrations and the molecular rearrangement mechanism in high concentrations. For low concentration, the law between the number of the membrane layers and the morphology of the aggregates in the fusion process was disclosed. Meanwhile, the membrane of the onion-like vesicles self-assembled from HMCs is monolayer structure and the thickness of each layer is decreased in sequence from inside to outside. The current observations have important guiding significance for its application in drug delivery systems.     

Self-assembly of Amphiphilic Alternating Copolymers

Polymer self-assembly has been a hot research topic for several decades. Different types of polymers with various architectures, like block copolymers, brush polymers, hyperbranched polymers and dendrimers, etc., are currently being investigated. Alternating copolymers (ACPs) are regular copolymers with an alternating monomeric unit structure in the polymer backbones. However, despite the great progress in the synthesis of ACPs, their self-assembly is still in an infant stage. Very recently, our group reported a new type of amphiphilic ACPs through click copolymerization and obtained spheres, vesicles, nanotubes, and even hierarchical sea urchin-like aggregates through the self-assembly process. In addition, we have found some intriguing features in the self-assembly of amphiphilic ACPs when compared with other copolymers, including their facile syntheses, readily functionalization, novel self-assembly structures, new folding-chain mechanisms, and uniform but ultrathin feature length. In this Concept article, we present the self-assembly of amphiphilic ACPs together with their unique features by reviewing our latest results and related studies. Moreover, the future perspective on the self-assembly of amphiphilic ACPs is also proposed. Our aim is to capture the attention and interest of chemists in this new area of polymerization.