全文获取类型
收费全文 | 77篇 |
免费 | 1篇 |
专业分类
化学 | 72篇 |
数学 | 1篇 |
物理学 | 5篇 |
出版年
2022年 | 4篇 |
2021年 | 1篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 4篇 |
2013年 | 6篇 |
2012年 | 6篇 |
2011年 | 4篇 |
2010年 | 5篇 |
2009年 | 5篇 |
2008年 | 5篇 |
2006年 | 2篇 |
2004年 | 1篇 |
2003年 | 4篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1980年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1970年 | 2篇 |
排序方式: 共有78条查询结果,搜索用时 15 毫秒
1.
2.
Working conditions were found for determining the novocaine salt of benzylpenicillin antibiotic as its 4,6-dinitrobenzofuroxan derivative by flow-injection analysis with spectrophotometric detection ( = 510 nm). The best results were obtained for flows of methanol (ethanol) and water with a volume ratio of 30 : 70. The calibration range of the pharmaceutical is 0.28–10 g/mL with a throughput capacity of 30 samples/h. The limit of detection (3, n= 4) is 0.14 g/mL. Amino acids and components of penicillin-containing pharmaceuticals did not interfere with the determination. Procedures for determining benzylpenicillin novocaine salt in medicinal formulations containing benzylpenicillin N,N"-dibenzylethylenediamine, potassium, and sodium salts and some other 相似文献
3.
Two new alkaloids — petine and petine N-oxide — have been isolated from the bulbs of Petilium eduardi. Their structures have been established on the basis of spectral characteristics and chemical transformations.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, FAX (3712) 89-14-75. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 524–528, July–August, 1994. 相似文献
4.
O. G. Shakirova D. Yu. Naumov Yu. G. Shvedenkov N. I. Alferova G. V. Dolgushin L. G. Lavrenova 《Journal of Structural Chemistry》2003,44(4):642-649
A new trinuclear nickel(II) complex with 4-(pyridyl-2)-1,2,4-triazole (pytrz), [Ni3(pytrz)6(H2O)6](NO3)6, has been synthesized, and its crystal structure has been determined. The compound was studied by X-ray phase analysis (XRPA), magnetochemical measurements, and electronic and IR spectroscopy. 相似文献
5.
6.
The new C-nor-D-homosteroidal alkaloid imperiazine was isolated from the bulbous plantPetilium eduardiRgl. (Liliaceae). The structure was established using spectral data. 相似文献
7.
O.?G.?Shakirova L.?G.?LavrenovaEmail author N.?V.?Kuratieva A.?S.?Bogomyakov L.?A.?Sheludyakova A.?P.?Mosalkova Yu.?V.?Grigoriev 《Journal of Structural Chemistry》2017,58(5):919-925
Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]?2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K. 相似文献
8.
Koshevoy IO Shakirova JR Melnikov AS Haukka M Tunik SP Pakkanen TA 《Dalton transactions (Cambridge, England : 2003)》2011,40(31):7927-7933
Coordination of P,N indolyl-phosphine ligands to Au(I), Ag(I) and Cu(I) metal ions under weakly basic conditions results in easy deprotonation of the indolyl N-H function and effective formation of a family of homo- and heterobimetallic complexes MM'(PPh(2)C(9)H(7)N)(2) (M = M' = Au (2), Ag (5); M = Au, M' = Cu (3), Ag (4)). The latter (4) exists as an inseparable mixture of four different complexes, which are in equilibrium driven by slow dynamics. The reaction of silver(I) and copper(I) ions with PPh(2)(C(9)H(8)N) affords a rare tetranuclear Z-shaped cluster Ag(2)Cu(2)(PPh(2)C(9)H(7)N)(4) (6), which exhibits red luminescence in solid state (650 nm) and a weak dual emission in solution with the main component in the near-IR region (746 nm). 相似文献
9.
10.
Bondar A. E. Buzulutskov A. F. Parkhomchuk V. V. Petrozhitskiy A. V. Sokolov A. V. Frolov E. A. Shakirova T. M. 《Physics of Atomic Nuclei》2021,84(1):82-86
Physics of Atomic Nuclei - A new ion identification method for accelerator mass spectrometry on the basis of measuring ion track ranges is proposed. A low pressure time projection chamber (TPC)... 相似文献