Erratum to: Effect of High-Temperature Gas-Chemical Modification on the Structural and Functional Properties of Carbon Black Particles

Russian Journal of Applied Chemistry - Figure 6 in the page 1980 should be replaced     

Synthesis and Study of Nanodispersed Carbon in the Combustion of Acetylene in a Flow Detonation Tube

Nanodispersed carbon was obtained via high-temperature combustion of acetylene–oxygen mixtures in a flow-through tubular chamber in cyclic detonation waves (“pulsed detonation”) at a constant propagation velocity (D_det ≈ 2150 m s^–1). It was found that the position of a plateau in the curve describing how the detonation velocity depends on the content of oxygen in the starting detonation mixture in the range 15–30% coincides with the range of descending branches of the dependences of the specific adsorption surface area and adsorption of dibutyl phthalate by aggregated particles. Various physicochemical methods of analysis (X-ray diffraction analysis, Raman spectroscopy, high-resolution transmission electron microscopy, etc.) were used to comparatively examine the properties of nanodispersed carbon and of the known industrially produced domestic and foreign brands of technical-grade carbon. The conditions were found in which detonation nanocarbon particles are obtained in a certain range of parameters of micro- and macrostructures with improved morphology and basic electrical properties.

     

Effect of High-Temperature Gas-Chemical Modification on the Structural and Functional Properties of Carbon Black Particles

The structure and electrochemical properties (specific capacitance and electrical resistance) of various grades of carbon black before and after high-temperature gas-chemical treatment were studied. The textural and structural parameters were determined by the methods of low-temperature nitrogen adsorption, dibutyl phthalate absorption, X-ray diffraction analysis, and Raman spectroscopy. The results are compared to the characteristics of Printex XE2-B extra-conductive carbon black.