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1.
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Results of an experimental observation of the voltage oscillations associated with a discrete tunneling of holes in porous silicon at room temperature are presented. The noise characteristics of diode structures with a porous silicon interlayer formed on heavily boron-doped silicon single crystals are studied. Peaks of excessive noise are observed at frequencies of ~1 MHz, at which single-electron oscillations should be expected. The peak noise power is found to increase with current according to the ~2.5 power law and, at a current density of 0.15 A/cm2, to exceed the noise power of the receiver by three to four orders of magnitude. The complex shape of the noise spectrum and its extension to the higher frequency region with increasing current are explained by the three-dimensionality of the system of nanometer-sized silicon grains embedded in insulating silicon dioxide of porous silicon. 相似文献
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B. A. Belyaev N. A. Drokin V. F. Shabanov V. A. Baranova 《Physics of the Solid State》2004,46(3):574-578
This paper reports on the results of investigations into the influence of variations in the chemical composition of the aromatic core of cyano-containing molecules of liquid crystals on their dielectric properties in the frequency range 1–2000 MHz. It is shown that the dispersion of the longitudinal permittivity is adequately described by the sum of two Debye processes with different weighting factors and relaxation times. The frequency dependence of the transverse permittivity is well approximated by the Debye process with a continuous distribution of relaxation times in a specified range. It is established that the replacement of one benzene ring in the biphenyl core of the 5CB liquid-crystal molecule by a cyclohexane (or bicyclooctane) fragment leads to a considerable decrease in both relaxation times for the longitudinal permittivity, a change in the low-frequency limit of the relaxation time range for the transverse permittivity, and the evolution of the frequency dependence of the dielectric anisotropy. 相似文献
5.
An expression is obtained for the reflection coefficient of circularly polarized light normally incident on the film of a cholesteric liquid crystal with a variable helix pitch. It is shown that, in the case of a single defect (local change in the helix pitch), the spectrum of light reflection from a cholesteric acquires a dip corresponding to the defect mode. New qualitative features appear in the reflection spectrum of a cholesteric with two defects as the distance between them varies. 相似文献
6.
Based on polarization measurements of the low-frequency Raman spectra of p-bromochlorobenzene and calculations of the frequency spectra of lattice vibrations by the Dean method it is shown that the
structure may contain vacancies. Their presence affects the appearance of additional lines in the low-frequency spectrum,
particularly in the vicinity of 70 cm−1, and their positions depend weakly on the orientational disorder of the molecules with respect to the para substituents. The activation energies for diffusion in a randomly disordered p-bromochlorobenzene crystal with vacancies in the structure is calculated from atom-atom potentials. It is shown that the
value of the activation energy varies along a selected direction and depends on the arrangement of the p-bromochlorobenzene molecules with respect to the para substituents, in contrast to the results for ordered p-dibromobenzene and p-dichlorobenzene.
Fiz. Tverd. Tela (St. Petersburg) 40, 1835–1838 (October 1998) 相似文献
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A. Khandar A. L. Shabanov R. Medzhidi G. G. Asadov Ch. I. Mamedov 《Journal of Analytical Chemistry》2003,58(2):183-185
The electrochemical properties of membranes based on dibenzo-crown ethers bearing hydroxyl and chloromethyl groups in polyether rings were studied. These substances were tested as membrane ionophores for ion-selective electrodes (ISEs) reversible to potassium ion. The developed ISEs were used for determining potassium in blood plasma samples. The generalized results of determining potassium in the blood of different patients with cardiovascular diseases revealed quantitative regularities that allowed the diseases to be diagnosed early. 相似文献
9.
Shabanov A. L. Gasanova M. M. Mamedov Ch. I. 《Russian Journal of Organic Chemistry》2002,38(7):1060-1063
Stereochemistry of [2+2]- and [1+1]-macrocylization of cis-4-cyclohexene-1,2-dicarboxylic acid with 1,2-dibromoethane, 1,3-dichloro-2-propanol, and 1,5-dichloro-3-oxapentane was studied. The reaction of cis-4-cyclohexene-1,2-dicarboxylic acid with 1,2-dibromoethane according to the [2+2]-cyclization scheme gave a mixture of stereoisomeric macroheterocycles with cis,syn,cis- and cis,anti,cis-junction of the polyether and cyclohexene rings. In the reaction of cis-4-cyclohexene-1,2-dicarboxylic acid with 1,5-dichloro-3-oxapentane, a mixture of crown compounds with cis,anti,cis- and cis-junction of the polyether and cyclohexene rings was obtained. The structure of the products was established on the basis of their chemical transformations and spectral data. 相似文献
10.
Conclusions The stereochemistry of the bromination of 3-methyl-4-cyclohexene-cis-1,2-dicarboxylic acid and its anhydride was studied, and the configurations of the products were proved. The observed features of the bromination were explained on the basis of the ionic mechanism of these reactions.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 127–132, January, 1967. 相似文献