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排序方式: 共有536条查询结果,搜索用时 15 毫秒
1.
Goudarzy Forough Zolgharnein Javad Alizadeh Vahid 《Journal of Analytical Chemistry》2022,77(6):711-716
Journal of Analytical Chemistry - In this article, a new spectrofluorometric method was developed for the determination of methamphetamine based on a turn-on luminescence response of captopril... 相似文献
2.
A sensitive and efficient method for trace analysis of some phenolic compounds using simultaneous derivatization and air‐assisted liquid–liquid microextraction from human urine and plasma samples followed by gas chromatography–nitrogen phosphorous detection
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Mir Ali Farajzadeh Mohammad Reza Afshar Mogaddam Ali Akbar Alizadeh Nabil 《Biomedical chromatography : BMC》2015,29(12):1921-1931
In present study, a simultaneous derivatization and air‐assisted liquid–liquid microextraction method combined with gas chromatography–nitrogen phosphorous detection has been developed for the determination of some phenolic compounds in biological samples. The analytes are derivatized and extracted simultaneously by a fast reaction with 1‐flouro‐2,4‐dinitrobenzene under mild conditions. Under optimal conditions low limits of detection in the range of 0.05–0.34 ng mL?1 are achievable. The obtained extraction recoveries are between 84 and 97% and the relative standard deviations are less than 7.2% for intraday (n = 6) and interday (n = 4) precisions. The proposed method was demonstrated to be a simple and efficient method for the analysis of phenols in biological samples. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
3.
4.
Mohammad H. Alizadeh Toktam Kermani Reza Tayebee 《Monatshefte für Chemie / Chemical Monthly》2007,138(2):165-170
Summary. Esterifications of acetic acid with some linear, secondary, tertiary, and benzylic alcohols mediated by catalytic amounts
of Keggin, Wells–Dawson, and Preyssler type heteropolyacids were carried out under reflux at mild reaction conditions with good to excellent yields. Among the examined
catalysts, H3PW12O40 and H14NaP5W30O110 revealed better results than other heteropolyacids. This work was performed with the aim of simplifying the esterification
process by omitting any solvents and mineral acid catalysts. Easy work-up, low cost, and acidic waste reduction, which are
all important features from the environmental and economical points of view, are distinct aspects of this protocol. Heteropolyacid
catalysts could be separated after a simple work-up and reused for several times. 相似文献
5.
Summary. A highly efficient, selective, fast, and cheap protocol is developed for oxidation of aromatic amines and alcohols utilizing
34% hydrogen peroxide in water catalyzed by some W- and Mo-based heteropolyoxometalates. Findings showed that dodecatungstophosphoric
acid, H3PW12O40, was the most efficient catalyst in the examined oxidation reactions. This methodology may prove to be a valuable alternative
for eco-friendly green oxidation. Inherent simplicity, easy work up, and using regenerable catalysts were other key aspects
of this oxidation protocol. 相似文献
6.
Hindered internal rotation about the C‐N single bonds joining the thiuram disulfide was studied by 1H NMR complete line‐shaped analysis in different dimethyl sulfoxide‐chloroform (DMSO‐CDCl3) mixtures. From the temperature dependence of methyls proton spectra, activation parameters (Ea, ΔH≠, ΔS≠, and ΔG≠) were obtained. The Arrhenius plots showed a distinct isokinetic temperature at about 35 °C at which the exchange rate is more or less independent of the solvent composition. The resulting ΔH≠ against TΔS≠ plot showed a firmly good linear correlation, indicating the existence of an enthalpy‐entropy composition in an exchange process. 相似文献
7.
Proton NMR was used to study the complexation reaction between silver ion and hexathia-18-crown-6 in a number of binary mixed solvents of dimethyl sulfoxide with acetonitrile and methanol. Formation constants for the resulting 1:1 complexes in different solvent mixtures were determined by computer fitting of the chemical shift-mole ratio data. The influence of solvent composition on the stability of the resulting complex is discussed. The exchange kinetics of Ag+-hexathia-18-crown-6 in 70-30 wt.% dimethyl sulfoxide-acetonitrile and 75-25 wt.% dimethyl sulfoxide-methanol were studied by proton NMR line-shape analysis. In both solvent mixtures, the exchange of thiacrown ether between the free and complexed sites was found to proceed via a dissociative pathway. The exchange rates and the activation parameters E
a, H
, S, and G for the ligand exchange were determined and the influence of solvent properties on these parameters discussed. 相似文献
8.
Abolghasem Moghimi Robabeh Alizadeh Hossein Aghabozorg Abbas Shockravi M. Carla Aragoni Francesco Demartin Francesco Isaia Vito Lippolis Andrew Harrison A. Shokrollahi Mojtaba Shamsipur 《Journal of Molecular Structure》2005,750(1-3):166-173
The one-pot reaction between the novel proton transfer compound (pydaH2)2+(phendc)2−, LH2, and Cu(II) afforded the compounds (pydaH)2[Cu(phendc)2]·10H2O, 1, and (pydaH)2[Cu(phendc)(phendcH)]2·5H2O, 2, where pyda=2,6-diaminopyridine, and phendcH2=1,10-phenanthroline-2,9-dicarboxylic acid. The single crystal X-ray diffraction analysis of 1 and 2 revealed that these are two novel self-assembled 3D Cu(II) complex-organo-networks, in which (pydaH)+ ions and [Cu(phendc)2]2− or complex units are held together by ion pairing, H-bonding, and π–π interactions. Magnetic measurements over the temperature range 1.8–310 K revealed no significant magnetic coupling between Cu(II) centers in 1 or 2. 相似文献
9.
Ritu Karwasra Shaban Ahmad Nagmi Bano Sahar Qazi Khalid Raza Surender Singh Saurabh Varma 《Molecules (Basel, Switzerland)》2022,27(18)
Punicalagin is the most bioactive pomegranate polyphenol with high antioxidant and free-radical scavenging activity and can potentially cure different ailments related to the cardiovascular system. The current research work was envisioned to predict the targeting efficiency of punicalagin (PG) nanoparticles to the macrophages, more specifically to bone marrow macrophages. For this, we selected mannose-decorated PLGA-punicalagin nanoparticles (Mn-PLGA-PG), and before formulating this nanocarrier in laboratory settings, we predicted the targeting efficiency of this nanocarrier by in silico analysis. The analysis proceeded with macrophage mannose receptors to be acquainted with the binding affinity and punicalagin-based nanocarrier interactions with this receptor. In silico docking studies of macrophage mannose receptors and punicalagin showed binding interactions on its surface. PG interacted with hydrogen bonds to the charged residue ASP668 and GLY666 and polar residue GLN760 of the Mn receptor. Mannose with a docking score of −5.811 Kcal/mol interacted with four hydrogen bonds and the mannose receptor of macrophage, and in PLGA, it showed a −4.334 Kcal/mol docking score. Further, the analysis proceeded with density functional theory analysis (DFT) and HOMO–LUMO analysis, followed by an extensive 100 ns molecular dynamics simulation to analyse the trajectories showing the slightest deviation and fluctuation. While analysing the ligand and protein interaction, a wonderful interaction was found among the atoms of the ligand and protein residues. This computational study confirms that this nanocarrier could be a promising lead molecule to regulate the incidence of drug-induced neutropenia. Furthermore, experimental validation is required before this can be stated with complete confidence or before human use. 相似文献
10.
Chien Hsu Chih-Yuan Lin Amer Alizadeh Hirofumi Daiguji Wei-Lun Hsu 《Electrophoresis》2021,42(21-22):2206-2214
Resistive pulse sensing using solid-state nanopores provides a unique platform for detecting the structure and concentration of molecules of different types of analytes in an electrolyte solution. The capture of an entity into a nanopore is subject not only to the electrostatic force but also the effect of electroosmotic flow originating from the charged nanopore surface. In this study, we theoretically analyze spherical particle electrophoretic behavior near the entrance of a charged nanopore. By investigating the effects of pore size, particle–pore distance, and salt concentration on particle velocity, we summarize dominant mechanisms governing particle behavior for a range of conditions. In the literature, the Helmholtz–Smoluchowski equation is often adopted to evaluate particle translocation by considering the zeta potential difference between the particle and nanopore surfaces. We point out that, due to the difference of the electric field inside and outside the nanopore and the influence from the existence of the particle itself, the zeta potential of the particle, however, needs to be at least 30% higher than that of the nanopore to allow the particle to enter into the nanopore when its velocity is close to zero. Accordingly, we summarize the effective salt concentrations that enable successful particle capture and detection for different pore sizes, offering direct guidance for nanopore applications. 相似文献