全文获取类型
收费全文 | 115篇 |
免费 | 5篇 |
国内免费 | 4篇 |
专业分类
化学 | 50篇 |
晶体学 | 5篇 |
力学 | 3篇 |
数学 | 37篇 |
物理学 | 29篇 |
出版年
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 3篇 |
2014年 | 5篇 |
2013年 | 5篇 |
2012年 | 1篇 |
2011年 | 9篇 |
2010年 | 3篇 |
2009年 | 3篇 |
2008年 | 6篇 |
2007年 | 9篇 |
2006年 | 8篇 |
2005年 | 4篇 |
2004年 | 4篇 |
2003年 | 2篇 |
2002年 | 4篇 |
2001年 | 2篇 |
2000年 | 10篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1981年 | 1篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1965年 | 1篇 |
1961年 | 1篇 |
1958年 | 2篇 |
排序方式: 共有124条查询结果,搜索用时 734 毫秒
1.
D. Indumathi 《Pramana》1995,45(1):155-171
This talk discusses the current understanding in some aspects of polarised lepton-nucleon deep inelastic scattering. The first section focuses on the non-singlet part of available spin dependent structure function data. The results, though consistent with theoretical predictions in this sector, are extremely sensitive to extrapolation of the data to thex→1 region and seem to indicate that the quarksdo carry a very small fraction of the nucleon spin. We then review the formalism of DIS processes with emphasis on the gluon sector. 相似文献
2.
D. Indumathi M. V. N. Murthy V. Ravindran 《Zeitschrift fur Physik C Particles and Fields》1992,56(3):427-436
Following recent interest in the subject of polarisation phenomena, we discuss the cross-sections and polarisation asymmetry in 2-jet production in polarised proton-polarised proton (
) scattering. We set up a complete set of parametrisations for the proton spin-dependent parton densities and use them to demonstrate that this cross-section is dominated by gluonic terms. Hence, a measurement of the asymmetry in such processes will provide information on the gluon spin-dependent density. We further show that a factorisation of the hadronic cross-section a la Combridge and Maxwell's work in unpolarised 2-jet production also applies to the spin-dependent case. Hence, the cross-section can be written in terms of a genericpolarised parton density, which can then be measured in the process. 相似文献
3.
4.
A new method was adopted for the synthesis of benzo[b]carbazoles by Claisen condensation followed by Fischer indole cyclization. Newly synthesized benzo[b]carbazoles were treated with ethanol amine in the presence of polyphosphoric acid which leads to the formation of pyrazino carbazoles. All the synthesized compounds were characterized by all spectral means. 相似文献
5.
Development of Biosensor for Catechol Using Electrosynthesized Poly(3‐methylthiophene) and Incorporation of LAC Simultaneously
下载免费PDF全文
![点击此处可从《Electroanalysis》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Simultaneous electropolymerization of 3‐methylthiophene and incorporation of Laccase (LAC) was carried out in the presence of propylene carbonate as a medium by amperometric method. This enzyme modified electrode was used for the sensing of polyphenol. Catechol is taken as a model compound for the study. UV‐Vis spectral studies suggest no denaturation of LAC in presence of propylene carbonate. The SEM studies reveal the surface morphology and incorporation of LAC in P3MT with agglomerated flaky masses are observed in with and without enzyme micrographs. The cyclic voltammograms were recorded for 0.01 mM catechol on plain glassy carbon, polymer and enzyme incorporated electrodes at pH 6.0 and scan rate 50 mV s?1. The fabricated electrochemical biosensor was used for the determination of catechol in aqueous solution by Differential Pulse Voltammetry (DPV) technique. The concentration linear range of 8×10?8 to 1.4×10?5 M a value of Michealis? Menten constant Km=7.67 µmol dm?3 and activation energy is 32.75 kJ mol?1. It retains 83 % of the original activity after 60 days which is much higher than that of other biosensors. The developed biosensor was used to quantify catechol in the determination in real samples. 相似文献
6.
Twelve ruthenium(III) complexes bearing amine-bis(phenolate) tripodal ligands of general formula [Ru(L1–L3)(X)(EPh3)2] (where L1–L3 are dianionic tridentate chelator) have been synthesized by the reaction of ruthenium(III) precursors [RuX3(EPh3)3] (where E = P, X = Cl; E = As, X = Cl or Br) and [RuBr3(PPh3)2(CH3OH)] with the tripodal tridentate ligands H2L1, H2L2 and H2L3 in benzene in 1:1 molar ratio. The newly synthesized complexes have been characterized by analytical (elemental and magnetic susceptibility) and spectral methods. The complexes are one electron paramagnetic (low-spin, d5) in nature. The EPR spectra of the powdered samples at RT and the liquid samples at LNT shows the presence of three different ‘g’ values (gx ≠ gy ≠ gz) indicate a rhombic distortion around the ruthenium ion. The redox potentials indicate that all the complexes undergo one electron transfer process. The catalytic activity of one of the complexes [Ru(pcr-chx)Br(AsPh3)2] was examined in the transfer hydrogenation of ketones and was found to be efficient with conversion up to 99% in the presence of isopropanol/KOH. 相似文献
7.
V. Indumathi 《Proceedings Mathematical Sciences》2001,111(2):229-239
We give a necessary and sufficient condition for proximinality of a closed subspace of finite codimension in c0-direct sum of Banach spaces. 相似文献
8.
V.A. Sethuraman M.J. Chon M. Shimshak N. Van Winkle P.R. Guduru 《Electrochemistry communications》2010,12(11):1614-1617
We report in situ measurement of biaxial moduli of a Si thin-film electrode as a function of its lithium concentration. During lithiation, biaxial compressive stress is induced in the Si film and it undergoes plastic flow. At any state-of-charge (SOC), a relatively small delithiation–relithiation sequence unloads and reloads the film elastically. From the stress and strain changes during a delithiation–relithiation cycle, the biaxial modulus of the film is calculated. Stress change is obtained by measuring the change in substrate curvature using a Multi-beam Optical Sensor; the elastic strain change is obtained from the change in SOC. By repeating these measurements at several different values of SOC, the biaxial modulus was seen to decrease from ca. 70 GPa for Li0.32Si to ca. 35 GPa for Li3.0Si. Such a significant reduction in elastic modulus has important implications for modeling stress evolution and mechanical degradation in Si-based anodes. 相似文献
9.
Chon MJ Sethuraman VA McCormick A Srinivasan V Guduru PR 《Physical review letters》2011,107(4):045503
Crystalline to amorphous phase transformation during initial lithiation in (100) Si wafers is studied in an electrochemical cell with Li metal as the counter and reference electrode. During initial lithiation, a moving phase boundary advances into the wafer starting from the surface facing the lithium electrode, transforming crystalline Si into amorphous Li(x)Si. The resulting biaxial compressive stress in the amorphous layer is measured in situ, and it was observed to be ca. 0.5 GPa. High-resolution TEM images reveal a very sharp crystalline-amorphous phase boundary, with a thickness of ~1 nm. Upon delithiation, the stress rapidly reverses and becomes tensile, and the amorphous layer begins to deform plastically at around 0.5 GPa. With continued delithiation, the yield stress increases in magnitude, culminating in a sudden fracture of the amorphous layer into microfragments, and the cracks extend into the underlying crystalline Si. 相似文献
10.
We discuss thex-dependence of the spin dependent structure function data currently available for proton, neutron and deuteron targets, with emphasis on the non-singlet sector. We pinpoint the sources of deviation of the data fromtheoretical expectations based, in particular, on the Bjorken sum rule. We conclude that apparent discrepancies can be reconciled so that the data are consistent with theoryprovided the large-x limit is properly defined. 相似文献