排序方式: 共有28条查询结果,搜索用时 93 毫秒
1.
Sung Woo Moon Gun-Dae Lee Seong Soo Park Seong-Soo Hong 《Reaction Kinetics and Catalysis Letters》2004,82(2):303-310
Catalytic combustion of chlorobenzene over supported vanadium oxides has been investigated. TiO2 was prepared by the sol-gel method from titanium isopropoxide. The supported vanadium oxide catalysts have been prepared
by precipitation-deposition and impregnation method and characterized by XRD, FT-Raman and TPR. In the VOx/TiO2catalysts prepared using the impregnation method, when vanadium loading reaches 3 wt.%, the activity shows a maximum. However,
in the VOx/TiO2catalysts prepared by precipitation-deposition, when vanadium loading reaches 7 wt.%, the activity shows a maximum. This result
suggests that the precipitation-deposition can yield a higher metal loading on the support and a high dispersion compared
to the impregnation method.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
2.
Won Young Jung Seung Hee Baek Seong Soo Park Gun-Dae Lee Euh Duck Jeong Hyun Gyu Kim Seong-Soo Hong 《Reaction Kinetics and Catalysis Letters》2007,91(2):233-240
The nanosized titania and TiO2/SiO2 particles were prepared by the microwave-hydrothermal method. The effect of physical properties TTIP/TEOS ratio and calcination
temperature has been investigated. The major phase of the pure TiO2 particle is of the anatase structure, and a rutile peak was observed above 800°C. In TiO2/SiO2 particles, however, no significant rutile phase was observed, although the calcination temperature was 900°C. No peaks for
the silica crystal phase were observed at either silica/titania ratio. The crystallite size of TiO2/SiO2 particles decreases as compared to pure TiO2 at high calcination temperatures. The TiO2/SiO2 particles show higher activity on the photocatalytic decomposition of orange II as compared to pure TiO2 particles. 相似文献
3.
Won Young Jung Byung Ho Noh Seung Hee Baek Gun-Dae Lee Seong Soo Park Seong-Soo Hong 《Reaction Kinetics and Catalysis Letters》2007,91(2):223-231
SBA-15 mesoporous material was prepared by microwave-hydrothermal method and was used as support in TiO2-loaded SBA-15 photocatalysts. The physical properties of these particles were investigated. We also examined the activity
of these samples as photocatalysts for the decomposition of orange II. Titania loaded on a silica matrix decreases the surface
area of the support as expected for TiO2 incorporation. For TiO2-loaded SBA-15 photocatalysts, the IR absorption at ∼960 cm−1 commonly accepted as the characteristic vibration of the Ti-O-Si bond. The photocatalytic activity increases with an increase
of the TiO2 loading. 相似文献
4.
The electro-catalytic oxidation of ethanol in a direct-type polymer electrolyte membrane fuel cell is known to be more complex than that of methanol. We used both solution and solid-state nuclear magnetic resonance (NMR) methods for the first time to successfully identify and quantify the reaction intermediates and the fuel itself which were distributed differently over fuel pathways and the polymer membrane (PEM) in the direct ethanol fuel cell (DEFC). The diverse chemical species present in the exhaust were identified by high-resolution solution NMR, while the nature and amounts of the species in the PEM of the DEFC were analyzed by solid-state NMR. The relative amount of reaction intermediates of ethanol detected in the PEM was an order of magnitude higher than that observed in the exhaust, which might be of critical importance in understanding and developing DEFC systems. 相似文献
5.
A Cu/Cr2O3 catalyst was prepared by co-precipitation method, studied in methanol dehydrocoupling to methyl formate in different gas
streams and characterized by BET, XRD, TPR, TPD of NH3 and CO2, etc. The results demonstrate that the catalyst can catalyze the dehydrocoupling of methanol to methyl formate in high efficiency,e. g. 99% selectivity to methyl formate at 48% conversion of methanol. The results further indicate that metallic copper might
be the active species for the formation of methyl formate 相似文献
6.
Kee Sung Han Seong-Soo Kim Ki Hyeok Kang Byoung Jean Mean Heon Hwa Choi Oc Hee Han Moohee Lee 《Electrochemistry communications》2009,11(2):466-468
195Pt nuclear magnetic resonance (NMR) was employed to study the influence of Nafion ionomers (NIs), a common ingredient used as a proton conducting mediator and binder in a membrane-electrode-assembly (MEA) for proton exchange membrane fuel cells, on the local density of states at the Fermi surface (EF-LDOS) of Pt/C catalysts. NIs were observed to increase the surface EF-LDOS of Pt particles, thereby altering of the catalytic properties of metal particles. This correlates well with the reduction of fuel oxidation rates. Thus, ionomers decreasing the surface EF-LDOS of Pt particles would be desirable. In addition, a new concept to interpret the surface EF-LDOS was introduced and validated. 相似文献
7.
Andreas Wilk Seong-Soo Kim Boris Mizaikoff 《Analytical and bioanalytical chemistry》2009,395(6):1661-1671
Optical simulations enable to model an entire chemical gas sensing platform based on hollow waveguides (HWGs) operating in
the mid-infrared spectral regime using a three-dimensional representation of the sensor components and taking the spectral
response to virtual analytes into account. Furthermore, a strategy for including the spectral response of dielectrically coated
HWGs is demonstrated. Utilizing experimentally obtained spectroscopic data recorded at well-defined conditions, the complex
refractive indices of selected target analytes (i.e., methane, butane, and isobutylene) have been derived based on a refined
harmonic oscillator model. In turn, these parameters have enabled to directly assign the dielectric functions of these analytes
to virtual objects representing the analyte within the modeled sensor setup. In a next step, spectroscopic sensor response
functions have been simulated as absorbance spectra across selected wavelength regimes utilizing spectrally resolved ray-tracing
techniques and have been compared to experimental data. 相似文献
8.
The main objective of this study is the development of a correlation model in dynamic Bayesian belief networks (DBBNs) followed by an inverse economic analysis. This is based on a quadratic hierarchical Bayesian inference prediction method using Markov chain Monte Carlo simulations. The developed model is implemented to predict the future degradation and maintenance budget for a suspension bridge system. Bayesian inference is applied to find the posterior probability density function of the source parameters (damage indices and serviceability), given 10 years maintenance data. The simulated risk prediction under decreased serviceability conditions gives posterior distributions based on a prior distribution and likelihood data updated from annual maintenance tasks. Compared with a conventional linear prediction model, the proposed quadratic model provides highly improved convergence and closeness to the measured data. Finally, the developed inverse DBBN analysis method allows forecasts of future performance and the financial management of complex infrastructures by providing the sensitivity of serviceability and risky factors to the maintenance budgets of structural components and the overall system. 相似文献
9.
Tamanna Sultana Jae Mok Jung Seong-Soo Hong Won-Ki Lee Yeong-Soon Gal Hyun Gyu Kim Kwon Taek Lim 《Journal of inclusion phenomena and macrocyclic chemistry》2012,72(1-2):207-212
Inclusion properties of the drug omeprazole (OMP) with peracetylated-beta-cyclodextrin (PAc-β-CD) prepared by green method, following supercritical carbon-dioxide (scCO2), were characterized through thermal (TGA and DSC), crystalline (XRD), NMR spectroscopic and dissolution studies. Comparison amongst PAc-β-CD, OMP, physical binary mixture (equimolar ratio of OMP: PAc-β-CD) and the solid inclusion complex (OMP/PAc-β-CD) revealed scCO2 as a successful technique for inclusion complex formation as well, identified characteristics performances of PAc-β-CD/OMP interactions. For instance, absence of characteristic DSC or XRD peaks of either chemical in the complex was quite noticeable with the shift of proton peaks in 1H NMR spectra. The formed inclusion complex also showed an important dissolution performance of OMP for controlled release applications partly due to the hydrophobic nature of PAc-β-CD. 相似文献
10.
Charged terminal groups or polar side chains of amino acids create spatially nonuniform electrostatic potential around intramolecular peptide bonds and induce amide I mode frequency shifts in polypeptides. By carrying out a series of quantum chemistry calculation studies of various ionic di- and tripeptides as well as dipeptides of 20 different amino acids, these internal field effects on vibrational properties are theoretically investigated. The amide I local and normal mode frequencies and dipole and rotational strengths determining IR and vibrational circular dichroism intensities, respectively, are found to depend on the polar nature of side chains, whereas the vibrational coupling strength weakly does so. The empirical correction and fragment analysis methods were used to theoretically calculate the amide I local mode frequencies and dipole and rotational strengths. These values were directly compared with ab initio and density functional theory calculation results, and the agreements were found to be quantitative. 相似文献