己内酰胺的聚合——Ⅳ.一元羧酸对聚合过程所发生的作用

己内酰胺在苯甲酸和6-氨基己酸存在下的聚合反应,实验结果表明苯甲酸具有引发 单体聚合、酸解大分子链和酰化大分子的氨基的作用。反应的开始为催化引发单体生成大分子链而不是苯甲酸与单体的加成。随着大分子的增多,酸解和酰化也同时发生。在反应半小时后酸解的影响逐渐显著,到3—4小时以后,酸解影响超过缩聚使聚合物分子量下降羧基含量增加。到反应7—8小时后,聚合物生成量及分子量已达恒定而酰化仍继续进行。到反应达到平衡时,仍然有游离的苯甲酸,聚合物中仍有游离的氨基和羧基,说明酸解、酰化与缩聚都是可逆反应。 在不用苯甲酸的己内酰胺与水的聚合实验中,聚合物虽在常压通氮的情况下在250°,270°或300°加热6小时分子量仍能稳定在一定数值而不升高,即加热15小时(250°)变化也很小。氨基与羧基不再进行缩聚,可能系由于反应系统粘稠,水分子不易扩散除去,大分子不易移动接触,功能基又受本身分子链的空间阻碍,使反应不易继续进行,维持在一定平衡状态。     

CO2激光外差接收的实时强度成像

利用国内的元器件建立了声光调制CO_2激光外差接收系统,并进行了实验室内静止目标的实时强度成像,成像距离3m,成像视场7°× 5°,像素128×98,4个颜色梯度显示像强度.     

用正电子寿命谱研究GeSe_x硫系玻璃的自由体积

采用正电子寿命谱和拉曼散射研究了不同组分配比的Ge Sex(x=6,7,8,9)硫系玻璃的微结构.正电子寿命结果显示在x=8时,其平均正电子寿命具有最小值.拉曼光谱结果研究表明,这种硫系玻璃样品主要由[Ge Se4]四面体和Seμ链的结构单元构成.以上的实验结果用级配理论得到了合理的解释,这两种结构单元配比关系的变化导致硫系玻璃样品中的自由体积变化,从而导致正电子平均寿命减小.研究发现Ge Se8具有最小的自由体积,即具有最稳定的结构.     

基于变权重正交变换的腈纶/棉运动纤维面料近红外光谱识别和信息增强机制

为全面阐释近红外光谱技术在纺织服装行业质量控制中的应用难题,本论文以腈纶/棉混纺纤维运动面料为对象,针对纤维面料的重叠信息精准选择和预处理技术直观化筛选应用进行研究。同时,以混纺纤维中的棉含量为指标,对纺织面料近红外定量模型建立中的分子信息识别和应用机制、建模样品及常规光谱处理对构建模型的影响进行了系统解释。最后,通过变权重正交变换算法计算从分子层面解析了纤维面料谱峰信息差异化贡献及纤维面料散射对定量模型构建和预测稳定性的影响。以期为我国纺织行业及纤维制品的精准化控制和质量表征特异化设备开发提供技术指导和参考。     

工科物理实验教学改革的实践与探索

介绍了近年来华中科技大学物理实验中心教学改革的历程及构建物理实验创新基地的思路和体会．     

Compton ɢ�����ƫ��������۵��������е��Ʋ��ȶ��Ե�Ӱ��

By using the model of multi-photon nonlinear Compton scattering, the nonlinear dispersion relation and Karpman’s model, the influences of the modulation instability on Compton scattering to the linear polarized light in relativistic plasma were studied, the revised equations on the nonlinear dispersion, the control and the growth rate of the modulation instability were given out, and these equations are simulated. The results show that under the same perturbation wave numbers, the even big rate of the modulation instability near the plasma surface are taken place by Compton scattering along with the decreasing of the numbers of the no gauge frequency than before Compton scattering, and the even marked growth rate of the modulation instability near the plasma surface are taken place near the plasma surface than other places. Because the plasma nonlinear is increased by the scattering, the self-focusing and self-turned fine silk are formed.     

限制性核酸内切酶PstⅠ星号活力的研究

研究了温度、酶浓度、反应时间、几种有机溶剂等因素对PstⅠ星号活力的影响,并在有利于星号活力的反应条件下测定了星号活力及原活力的Km 分别为1.46×10- 7 m ol/L和1.02×10- 8 m ol/L,Vm ax 分别为2.86×10- 16 m ol/s和3.06×10- 15 m ol/s.     

THE QUANTUM CORRECTIONS ON THE THEORY OF TRANSITION RADIATION

A Scheme of quantum treatment for transition radiation is proposed. The Fresnel coefficients are adopted to describe the stationary states of electromagnetic fields near the interface between two mediums before a canonical field quantization procedure can be performed. Then an usual perturbation approach in field theory leads to the general expressions of radiation intensity in two different polarizations. The second order quantum corrections are ascribed to the existence of electron spin. Some concrete formulas for the cases of electron or monopole acrossing a metal surface are presented as well.

     

Magnetic and Electrical Transport Properties of Sr1-xLaxRuO3 (0≤x≤0.10)

We investigate the lightly doped polycrystalline Sr1-χLaχRuO3 （χ = 0, 0.02, 0.08 and 0.10）. With La doping, the ferromagnetism in the system has been suppressed. The transition temperature is T＇c at which the long-range ferromagnetism establishes and the magnetization under 3 T at 5 K decreases with increasing χ. In contrast to Sr1-χCaχRuO3, the samples remain with the PM-FM transition at 162K, which might be attributed to the valency change of Ru.     

生长温度和结构参数对InGaAs／GaAs量子阱光学特性的影响

研究了不同生长温度下制备的In0.15Ga0.85As/GaAs应变量子阱的PL谱,结果表明,生长温度越高,In偏析和In-Ga互混越严重,同时,导致更多的In脱附,PL谱发光峰蓝移。对不同In含量的和不同InGaAs厚度的InGaAs/GaAs量子阱进行PL谱测试,分析表明In含量<0.2,生长温度低于560℃时,In含量和InGaAs层量子阱的厚度对In偏析、脱附和In-Ga互混基本没有影响。