全文获取类型
收费全文 | 3303篇 |
免费 | 269篇 |
国内免费 | 18篇 |
专业分类
化学 | 2372篇 |
晶体学 | 13篇 |
力学 | 73篇 |
数学 | 517篇 |
物理学 | 615篇 |
出版年
2023年 | 55篇 |
2022年 | 68篇 |
2021年 | 120篇 |
2020年 | 169篇 |
2019年 | 191篇 |
2018年 | 88篇 |
2017年 | 73篇 |
2016年 | 204篇 |
2015年 | 158篇 |
2014年 | 165篇 |
2013年 | 212篇 |
2012年 | 288篇 |
2011年 | 294篇 |
2010年 | 167篇 |
2009年 | 133篇 |
2008年 | 211篇 |
2007年 | 177篇 |
2006年 | 160篇 |
2005年 | 116篇 |
2004年 | 79篇 |
2003年 | 44篇 |
2002年 | 49篇 |
2001年 | 35篇 |
2000年 | 34篇 |
1999年 | 16篇 |
1998年 | 16篇 |
1997年 | 13篇 |
1996年 | 15篇 |
1995年 | 16篇 |
1994年 | 10篇 |
1993年 | 9篇 |
1992年 | 15篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1988年 | 6篇 |
1987年 | 11篇 |
1986年 | 12篇 |
1985年 | 9篇 |
1984年 | 11篇 |
1983年 | 6篇 |
1982年 | 9篇 |
1981年 | 10篇 |
1979年 | 13篇 |
1978年 | 9篇 |
1976年 | 6篇 |
1975年 | 7篇 |
1974年 | 7篇 |
1973年 | 8篇 |
1972年 | 5篇 |
1970年 | 5篇 |
排序方式: 共有3590条查询结果,搜索用时 15 毫秒
1.
Cover Picture: Coordination Chemistry of N‐Heterocyclic Nitrenium‐Based Ligands (Chem. Eur. J. 19/2015) 下载免费PDF全文
2.
Dr. Sebastian Lars Müller Xinglong Zhou Dr. Peter Leonard Oxana Korzhenko Dr. Constantin Daniliuc Prof. Dr. Frank Seela 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(12):3077-3090
Silver-mediated α-dC–Ag+–β-dC hybrid base pairs decorated with 5-iodo- or 5-octadiynyl residues are well accommodated in duplex DNA. A strong Tm increase and favorable thermodynamic data for duplex DNA were observed after addition of silver ions. The phenomenon is particularly obvious when both nucleobases of the base pairs are functionalized. Neither the position of the base pair, nor the type of 5-substituent had a negative influence. On the contrary, functionalization of conventional silver-mediated β-dC–Ag+–β-dC homo base pairs showed a negative impact induced by the bulky substituents. To this end, cytosine modified 12-mer oligodeoxynucleotides were prepared by solid-phase synthesis employing new α-anomeric 2′-deoxycytidine phosphoramidites. A multigram scale synthesis was developed for 5-iodo-α-d -2′-deoxycytidine ( 1 ) employing the direct glycosylation of cytosine with Hoffer's α-d -halogenose followed by separation of anomeric DMT nucleosides. Regarding base-pair stability and functionalization silver-mediated α/β-dC hybrid base pairs were found to be superior to β/β-dC homo pairs. According to their extraordinary properties, they might find applications in DNA diagnostics, material science, or nanotechnology. 相似文献
3.
Natalia L. Calvo Sebastian O. SimonettiRubén M. Maggio Teodoro S. Kaufman 《Analytica chimica acta》2015
Exposure of cimetidine (CIM) to dry heat (160–180 °C) afforded, upon cooling, a glassy solid containing new and hitherto unknown products. The kinetics of this process was studied by a second order chemometrics-assisted multi-spectroscopic approach. Proton and carbon-13 nuclear magnetic resonance (NMR), as well as ultraviolet and infrared spectroscopic data were jointly used, whereas multivariate curve resolution with alternating least squares (MCR-ALS) was employed as the chemometrics method to extract process information. It was established that drug degradation follows a first order kinetics. 相似文献
4.
We prove the existence of global smooth solutions near a given steady state of the hydrodynamic model of the semiconductors
in a bounded domain with physical boundary conditions. The steady state and the doping profile are permitted to be of large
variation but the initial velocity must be small. Two cases are considered. In the first one the problem is three-dimensional,
the boundary conditions are insulating and the steady state velocity vanishes. In the second one, the problem is one-dimensional,
the boundary is of contact type and the steady state velocity does not vanish. 相似文献
5.
Sebastian Kuntze 《ZDM》2006,38(6):456-463
So-called “bottom-up” strategies for implementation based on mathematics teachers' own developmental activities are considered to be a powerful approach when encouraging teachers to introduce alternative instructional practices. For evaluational research of in-service teacher training programs using “bottom-up” implementation strategies, the way how teachers implement contents of the teacher training is at the centre of interest. As the teachers' active role in the implementation process is necessary, their individual beliefs on the contents of the teacher training and their expectancies might influence the teachers' implementational activities. These beliefs can be considered as components of professional knowledge and pedagogical contents knowledge (Shulman, 1986) in particular. For this reason, the study focuses on the development of beliefs on contents of a teacher training program throughout the training on the one hand and relationships with characteristics of implementation on the other hand. We consider the example of introducing a student-centred learning environment, the so-called topic study method, in the teachers' classrooms. The results indicate that there are interdependencies between beliefs on the teacher training contents and characteristics of implementation. 相似文献
6.
The Cauchy Problem for the relativistic Vlasov-Maxwell equations is studied in three space dimensions. It is assumed that the initial data satisfy the required constraints and have compact support. If in addition the data have sufficiently smallC
2 norm, then a uniqueC
1 solution to this system is shown to exist on all of spacetime.Research supported in part by NSF DMS 85-20662 and NSF DMS 84-20957 相似文献
7.
8.
On a Definitizable Analog of the Trigonometric Moment Problem Generating an Indefinite Toeplitz Form
We prove the existence of an integro-polynomial representation for a sequence of numbers such that there exists a difference operator mapping this sequence to a sequence that generates the solvable trigonometric moment problem. A similar result related to the power moment problem was given in [12]. 相似文献
9.
Zhijian Zhao William H. LeisterKimberly A. Strauss David D. WisnoskiCraig W. Lindsley 《Tetrahedron letters》2003,44(6):1123-1127
By the application of microwave technology, a general protocol has been developed for the rapid synthesis of diverse 3,5,6-trisubstituted 1,2,4-triazines in excellent yield and purity, including many previously unknown 3-heterocyclic-1,2,4-triazines. 相似文献
10.
Tunable microlens arrays using polymer network liquid crystal 总被引:1,自引:0,他引:1
A tunable-focus microlens array based on polymer network liquid crystal (PNLC) is demonstrated. The PNLC was prepared using an ultraviolet (UV) light exposure through a patterned photomask. The photocurable monomer in each of the UV exposed spot forms an inhomogeneous centro-symmetrical polymer network which acts as a lens when a homogeneous electric field is applied to the cell. The focal length of the microlens arrays is tunable with the applied voltage. 相似文献