排序方式: 共有24条查询结果,搜索用时 15 毫秒
1.
Abusaidi R Akerib DS Barnes PD Bauer DA Bolozdynya A Brink PL Bunker R Cabrera B Caldwell DO Castle JP Clarke RM Colling P Crisler MB Cummings A Da Silva A Davies AK Dixon R Dougherty BL Driscoll D Eichblatt S Emes J Gaitskell RJ Golwala SR Hale D Haller EE Hellmig J Huber ME Irwin KD Jochum J Lipschultz FP Lu A Mandic V Martinis JM Nam SW Nelson H Neuhauser B Penn MJ Perera TA Perillo Isaac MC Pritychenko B Ross RR Saab T Sadoulet B Schnee RW Seitz DN Shestople P Shutt T Smith A Smith GW 《Physical review letters》2000,84(25):5699-5703
The Cryogenic Dark Matter Search (CDMS) employs Ge and Si detectors to search for weakly interacting massive particles (WIMPs) via their elastic-scattering interactions with nuclei while discriminating against interactions of background particles. CDMS data, accounting for the neutron background, give limits on the spin-independent WIMP-nucleon elastic-scattering cross section that exclude unexplored parameter space above 10 GeV/c2 WIMP mass and, at >75% C.L., the entire 3sigma allowed region for the WIMP signal reported by the DAMA experiment. 相似文献
2.
A phosphonium surfactant is introduced as a pseudostationary phase for MEKC and its performance and selectivity are compared to that of an analogous ammonium surfactant. The linear solvation energy relationship model has been applied to the two cationic surfactants, allowing the contributions of five chemical factors to the interactions between solutes and the micelles to be evaluated. Differences in the pseudophases cohesivity and acid/base interactions were observed. Despite the significant differences observed in the solvation parameter results the two phases have remarkably similar electrophoretic properties, with the anodic EOF produced by the dynamic coating and the electrophoretic mobility of the two surfactants being statistically equal. 相似文献
3.
Walter Schnee 《Mathematische Annalen》1909,67(1):110-125
Ohne Zusammenfassung 相似文献
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Alexandreas DE Allen GE Berley D Biller S Burman RL Cavalli-Sforza M Chang CY Chen ML Chumney P Coyne D Dion C Dion GM Dorfan D Ellsworth RW Goodman JA Haines TJ Harmon M Hoffman CM Kelley L Klein S Nagle DE Schmidt DM Schnee R Sinnis C Shoup A Stark MJ Weeks DD Williams DA Wu JP Yang T Yodh GB Zhang WP 《Physical review letters》1993,71(16):2524-2527
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Dr. Palraj Kasinathan Dr. Charlotte Lang Dr. Sambhu Radhakrishnan Dr. Josefine Schnee Cécile D'Haese Dr. Eric Breynaert Prof. Johan A. Martens Prof. Eric M. Gaigneaux Prof. Alain M. Jonas Dr. Antony E. Fernandes 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(27):6753-6762
Solid acid catalysts are central in our chemical industry and are major players in the valorization of bioresources. However, there is still a need to develop solid acid catalysts with enhanced acid strength and improved, or tunable, physicochemical profile to enhance the efficiency and sustainability of chemical processes. Here, a modular approach to tune the acid strength and surface polarity of silica-supported sulfonic acid catalysts, based on a versatile copper-catalyzed azide–alkyne cycloaddition (CuAAC)-based anchoring scheme, is presented. The CuAAC-formed triazole link was used to enhance the activity of the grafted sulfonic acids and to pair the acid sites with secondary hydrophobic functions. The beneficial effects of both the triazolium link and the paired hydrophobic site, as well as the optimal positioning of the sulfonic moiety on the triazole ring, are discussed in model esterification reactions. 相似文献
7.
Ahmed Z Akerib DS Arrenberg S Bailey CN Balakishiyeva D Baudis L Bauer DA Brink PL Bruch T Bunker R Cabrera B Caldwell DO Cooley J do Couto e Silva E Cushman P Daal M DeJongh F Di Stefano P Dragowsky MR Duong L Fallows S Figueroa-Feliciano E Filippini J Fox J Fritts M Golwala SR Hall J Hennings-Yeomans R Hertel SA Holmgren D Hsu L Huber ME Kamaev O Kiveni M Kos M Leman SW Liu S Mahapatra R Mandic V McCarthy KA Mirabolfathi N Moore D Nelson H Ogburn RW Phipps A Pyle M Qiu X Ramberg E Rau W 《Physical review letters》2011,106(13):131302
We report results from a reanalysis of data from the Cryogenic Dark Matter Search (CDMS II) experiment at the Soudan Underground Laboratory. Data taken between October 2006 and September 2008 using eight germanium detectors are reanalyzed with a lowered, 2 keV recoil-energy threshold, to give increased sensitivity to interactions from weakly interacting massive particles (WIMPs) with masses below ~10 GeV/c(2). This analysis provides stronger constraints than previous CDMS II results for WIMP masses below 9 GeV/c(2) and excludes parameter space associated with possible low-mass WIMP signals from the DAMA/LIBRA and CoGeNT experiments. 相似文献
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Walter Schnee 《Mathematische Zeitschrift》1928,27(1):456-462
Ohne Zusammenfassung 相似文献
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We present a mathematically rigorous analysis of the ground state of a dilute, interacting Bose gas in a three-dimensional trap that is strongly confining in one direction so that the system becomes effectively two-dimensional. The parameters involved are the particle number, , the two-dimensional extension, , of the gas cloud in the trap, the thickness, of the trap, and the scattering length a of the interaction potential. Our analysis starts from the full many-body Hamiltonian with an interaction potential that is assumed to be repulsive, radially symmetric and of short range, but otherwise arbitrary. In particular, hard cores are allowed. Under the premises that the confining energy, ~ 1/h
2, is much larger than the internal energy per particle, and a/h→ 0, we prove that the system can be treated as a gas of two-dimensional bosons with scattering length a
2D = hexp(−(const.)h/a). In the parameter region where , with the mean density, the system is described by a two-dimensional Gross-Pitaevskii density functional with coupling parameter ~ Na/h. If the coupling parameter is and thus independent of a. In both cases Bose-Einstein condensation in the ground state holds, provided the coupling parameter stays bounded. 相似文献
10.
Normal‐to‐Abnormal NHC Rearrangement of AlIII,GaIII, and InIII Trialkyl Complexes: Scope,Mechanism, Reactivity Studies,and H2 Activation
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Dr. Gilles Schnee Prof. Olalla Nieto Faza Dr. David Specklin Dr. Béatrice Jacques Dr. Lydia Karmazin Prof. Richard Welter Prof. Carlos Silva López Dr. Samuel Dagorne 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(49):17959-17972
The present contribution reports experimental and theoretical mechanistic investigations on a normal‐to‐abnormal (C2‐to‐C4‐bonded) NHC rearrangement processes occurring with bulky group 13 metal NHC adducts, including the scope of such a reactivity for Al compounds. The sterically congested adducts (nItBu)MMe3 (nItBu=1,3‐di‐tert‐butylimidazol‐2‐ylidene; M=Al, Ga, In; 1 a – c ) readily rearrange to quantitatively afford the corresponding C4‐bonded complexes (aItBu)MMe3 ( 4 a – c ), a reaction that may be promoted by THF. Thorough experimental data and DFT calculations were performed on the nNHC‐to‐aNHC process converting the Al‐nNHC ( 1 a ) to its aNHC analogue 4 a . A nItBu/aItBu isomerization is proposed to account for the formation of the thermodynamic product 4 a through reaction of transient aItBu with THF–AlMe3. The reaction of benzophenone with (nItBu)AlMe3 afforded the zwitterionic species (aItBu)(CPh2‐O‐AlMe3) ( 6 ), reflecting the unusual reactivity that such bulky adducts may display. Interestingly, the nItBu/Al(iBu)3 Lewis pair behaves like a frustrated Lewis pair (FLP) since it readily reacts with H2 under mild conditions. This may open the way to future reactivity developments involving commonly used trialkylaluminum precursors. 相似文献