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1.
We construct non-tight frames in finite-dimensional spaces consisting of periodic functions. In order for these frames to
be useful in practice one needs to calculate a dual frame; while the canonical dual frame might be cumbersome to work with,
the setup presented here enables us to obtain explicit constructions of some particularly convenient oblique duals. We also
provide explicit oblique duals belonging to prescribed spaces different from the space where we obtain the expansion. In particular
this leads to oblique duals that are trigonometric polynomials. 相似文献
2.
We address the problem of correlating the observed FID and T1ρ components in wideline 1H relaxation measurements of motionally heterogeneous polymers, and show that different methods of data treatment can highlight different aspects of the correlations present. For a sample of polypropylene we find that the T1ρ relaxation behaviour is driven by relaxation associated with the intermediate FID component, which strongly suggests a motionally inhomogeneous amorphous region in the sample. 相似文献
3.
Jamie YuLing Han Timothy Thatt Yang Tan Joachim Say Chye Loo 《Journal of nanoparticle research》2011,13(8):3441-3454
The aim of this study was to investigate the feasibility of the inverse micelles (IM) technique in producing protein-loaded
calcium phosphate nanoparticles (CaP NPs), and to compare this technique with the conventional co-precipitation (co-ppt) technique.
In this study, bovine serum albumin and lysozyme were used as model proteins. The results show that CaP NPs produced by IM
were shown to be spherical and homogenous in size of ~50 nm. Protein loading efficiency of the IM technique was shown to be
much higher than CaP NPs synthesized through co-ppt technique. X-ray photoelectron spectroscopy shows that proteins were not adsorbed onto the surface of IM-synthesized CaP NPs, which suggested
that the proteins were entrapped within the particle matrix. Release studies show that protein release was more rapid at lower
pH conditions (pH 5 and 6) than at physiological pH of 7.4. A burst release was observed for co-ppt CaP NPs, while a continuous
release of protein was observed for IM-produced CaP NPs. This study shows the superiority of the IM technique in preparing
pH responsive CaP NPs as nano-carriers. 相似文献
4.
Li-ion rechargeable batteries based on polymer electrolytes are of great interest for solid state electrochemical devices
nowadays. Many studies have been carried out to improve the ionic conductivity of polymer electrolytes, which include polymer
blending, incorporating plasticizers and filler additives in the electrolyte systems. This paper describes the effects of
incorporating nano-sized MnO2 filler on the ionic conductivity enhancement of a plasticized polymer blend PMMA–PEO–LiClO4–EC electrolyte system. The maximum conductivity achieved is within the range of 10−3 S cm−1 by optimizing the composition of the polymers, salts, plasticizer, and filler. The temperature dependence of the polymer
conductivity obeys the VTF relationship. DSC and XRD studies are carried out to clarify the complex formation between the
polymers, salts, and plasticizer. 相似文献
5.
Yaoyu Feng Say‐Leong Ong Jiangyong Hu Wun‐Jern Ng 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):m34-m35
Reaction of 1,10‐phenanthroline (phen) with iron trichloride in the presence of sodium nitrilotriacetate (NTA) resulted in the formation of red crystals of the title complex, [Fe(C6H6NO6)(C12H8N2)(H2O)]·H2O. The Fe atom has a distorted capped trigonal prismatic coordination comprised of one tetradentate NTA, one bidentate phen molecule and a water molecule. Intermolecular O—H?O hydrogen bonds link the molecules into infinite chains. The chains are crosslinked by hydrogen bonds involving the solvent water molecule, leading to an infinite ladder packing mode. 相似文献
6.
Xu QC Ng YH Zhang Y Loo JS Amal R Tan TT 《Chemical communications (Cambridge, England)》2011,47(30):8641-8643
We demonstrate a general strategy to prepare Bi(2)WO(6)/Ag/N-TiO(2) film with double visible-light-active components bridged by Ag nanoparticles as an electron shuttle, which exhibits enhanced photocatalytic activity and photoelectrochemical performance under visible light. 相似文献
7.
Morón V Gamallo P Martin-Gondre L Crespos C Larregaray P Sayós R 《Physical chemistry chemical physics : PCCP》2011,13(39):17494-17504
A microkinetic model is developed to study the reactivity of an O/O(2) gas mixture over a β-cristobalite (001) surface. The thermal rate constants for the relevant elementary processes are either inferred from quasiclassical trajectory calculations or using some statistical approaches, resting on a recently developed interpolated multidimensional potential energy surface based on density functional theory. The kinetic model predicts a large molecular coverage at temperatures lower than 1000 K, in contrary to a large atomic coverage at higher temperatures. The computed atomic oxygen recombination coefficient, mainly involving atomic adsorption and Eley-Rideal recombination, is small and increases with temperature in the 700-1700 K range (0.01 < γ(O) < 0.02) in good agreement with experiments. In the same temperature range, the estimated chemical energy accommodation coefficient, the main contribution to which is the atomic adsorption process is almost constant and differs from unity (0.75 < β(O) < 0.80). 相似文献
8.
Ayta? Gültekin Arzu Ers?z Nalan Y?lmaz Sar??zlü Adil Denizli R?dvan Say 《Journal of nanoparticle research》2010,12(6):2069-2079
Molecular imprinted polymers (MIPs) as a recognition element for sensors are increasingly of interest and MIP nanoclusters have started to appear in the literature. In this study, we have proposed a novel thiol ligand-capping method with polymerizable methacryloylamido-cysteine (MAC) attached to gold–silver nanoclusters, reminiscent of a self-assembled monolayer and have reconstructed surface shell by synthetic host polymers based on molecular imprinting method for recognition. In this method, methacryloylamidoantipyrine–terbium ((MAAP)2–Tb(III)) has been used as a new metal-chelating monomer via metal coordination–chelation interactions and dipicolinic acid (DPA) which is main participant of Bacillus cereus spores used as a model. Nanoshell sensors with templates give a cavity that is selective for DPA. The DPA can simultaneously chelate to Tb(III) metal ion and fit into the shape-selective cavity. Thus, the interaction between Tb(III) ion and free coordination spheres has an effect on the binding ability of the gold–silver nanoclusters nanosensor. The binding affinity of the DPA imprinted nanoclusters has been investigated by using the Langmuir and Scatchard methods, and the respective affinity constants (K affinity) determined were found to be 1.43 × 104 and 9.1 × 106 mol L?1. 相似文献
9.
Extending band-limited constructions of orthonormal refinable functions, a special class of periodic functions is used to generate a family of band-limited refinable functions. Characterizations of Riesz bases and frames formed by integer shifts of these refinable functions are obtained. Such families of refinable functions are employed to construct band-limited biorthogonal wavelet bases and biframes with desirable time-frequency localization. 相似文献
10.