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Saule Troitskaya 《Studies in Applied Mathematics》2017,139(3):434-456
We consider the problem of small oscillations of a rotating inviscid incompressible fluid. From a mathematical point of view, new exact solutions to the two‐dimensional Poincaré–Sobolev equation in a class of domains including trapezoid are found in an explicit form and their main properties are described. These solutions correspond to the absolutely continuous spectrum of a linear operator that is associated with this system of equations. For specialists in Astrophysics and Geophysics, the existence of these solutions signifies the existence of some previously unknown type of inertial waves corresponding to the continuous spectrum of inertial oscillations. A fundamental distinction between monochromatic inertial waves and waves of the new type is shown: usual characteristics (frequency, amplitude, wave vector, dispersion relation, direction of energy propagation, and so on) are not applicable to the last. Main properties of these waves are described. In particular, it is proved that they are progressive. Main features of their energy transfer are described. 相似文献
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Smooth anodic TiO2 nanotubes 总被引:6,自引:0,他引:6
Macak JM Tsuchiya H Taveira L Aldabergerova S Schmuki P 《Angewandte Chemie (International ed. in English)》2005,44(45):7463-7465
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Stabilization of emulsions by mixed polyelectrolyte/surfactant systems is a prominent example for the application in modern technologies. The formation of complexes between the polymers and the surfactants depends on the type of surfactant (ionic, non-ionic) and the mixing ratio. The surface activity (hydrophilic–lipophilic balance) of the resulting complexes is an important quantity for its efficiency in stabilizing emulsions. The interfacial adsorption properties observed at liquid/oil interfaces are more or less equivalent to those observed at the aqueous solution/air interface, however, the corresponding interfacial dilational and shear rheology parameters differ quite significantly. The interfacial properties are directly linked to bulk properties, which support the picture for the complex formation of polyelectrolyte/surfactant mixtures, which is the result of electrostatic and hydrophobic interactions. For long alkyl chain surfactants the interfacial behavior is strongly influenced by hydrophobic interactions while the complex formation with short chain surfactants is mainly governed by electrostatic interactions. 相似文献
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Gulmira
zek Igor A. Schepetkin Moldir Yermagambetova Temel
zek Liliya N. Kirpotina Shyryn S. Almerekova Saule I. Abugalieva Andrei I. Khlebnikov Mark T. Quinn 《Molecules (Basel, Switzerland)》2021,26(24)
Little is known about the immunomodulatory activity of essential oils isolated from Juniperus species. Thus, we isolated essential oils from the cones and leaves of eight juniper species found in Montana and in Kazakhstan, including J. horizontalis, J. scopolorum, J. communis, J. seravschanica, J. sabina, J. pseudosabina, J. pseudosabina subsp. turkestanica, and J. sibirica. We report here the chemical composition and innate immunomodulatory activity of these essential oils. Compositional analysis of the 16 samples of Juniper essential oils revealed similarities and differences between our analyses and those previously reported for essential oils from this species. Our studies represent the first analysis of essential oils isolated from the cones of four of these Juniper species. Several essential oil samples contained high levels of cedrol, which was fairly unique to three Juniper species from Kazakhstan. We found that these essential oils and pure (+)-cedrol induced intracellular Ca2+ mobilization in human neutrophils. Furthermore, pretreatment of human neutrophils and N-formyl peptide receptor 1 and 2 (FPR1 and FPR2) transfected HL60 cells with these essential oils or (+)-cedrol inhibited agonist-induced Ca2+ mobilization, suggesting these responses were desensitized by this pretreatment. In support of this conclusion, pretreatment with essential oils from J. seravschanica cones (containing 16.8% cedrol) or pure (+)-cedrol inhibited human neutrophil chemotaxis to N-formyl peptide. Finally, reverse pharmacophore mapping predicted several potential kinase targets for cedrol. Thus, our studies have identified cedrol as a novel neutrophil agonist that can desensitize cells to subsequent stimulation by N-formyl peptide. 相似文献
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Daniel Taton Myriam Saule Jennifer Logan Randolph Duran Sijian Hou Elliot L. Chaikof Yves Gnanou 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1669-1676
Eight‐arm poly(ethylene oxide) (PEO) stars were prepared by the core‐first method with a newly designed octahydroxylated precursor. This compound was readily obtained in two steps from commercially available tert‐butylcalix[8]arene. The choice of the proper solvent of polymerization proved crucial to obtain PEO star materials with a narrow distribution of molar masses. For instance, the use of dimethyl sulfoxide (DMSO) resulted in PEO samples of rather large polydispersities (PDI: 1.3–1.5). In this solvent, the calixarene‐based precursor was only sparingly soluble, and an attempt to metalate its eight hydroxyl groups produced insoluble alkoxides. In addition, the presence of a side population of low‐molar‐mass species attributable to linear chains was detected because of the chain transfer of propagating alkoxides to DMSO. Polymerization experiments carried out in tetrahydrofuran (THF) as solvent afforded better control over the molar masses and PDIs. This was related to the better solubility of the octafunctional calixarene‐based precursor in THF and to the small tendency of the alkoxides formed to aggregate in that solvent. Under such conditions, all eight hydroxyl functions efficiently initiated the polymerization of ethylene oxide. In this way, well‐defined PEO stars (PDI < 1.2) of tunable molar masses incorporating a calixarene‐based core could be obtained, as it was supported by the characterization of the samples by size exclusion chromatography, NMR, and viscometry. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1669–1676, 2003 相似文献