全文获取类型
收费全文 | 545篇 |
免费 | 4篇 |
国内免费 | 1篇 |
专业分类
化学 | 340篇 |
晶体学 | 12篇 |
力学 | 8篇 |
数学 | 56篇 |
物理学 | 134篇 |
出版年
2018年 | 5篇 |
2016年 | 9篇 |
2014年 | 10篇 |
2013年 | 33篇 |
2012年 | 13篇 |
2011年 | 31篇 |
2010年 | 9篇 |
2009年 | 11篇 |
2008年 | 19篇 |
2007年 | 24篇 |
2006年 | 20篇 |
2005年 | 23篇 |
2004年 | 31篇 |
2003年 | 20篇 |
2002年 | 19篇 |
2001年 | 8篇 |
2000年 | 12篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 14篇 |
1996年 | 22篇 |
1995年 | 10篇 |
1994年 | 10篇 |
1993年 | 11篇 |
1992年 | 13篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 10篇 |
1988年 | 11篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 11篇 |
1983年 | 7篇 |
1982年 | 8篇 |
1981年 | 12篇 |
1980年 | 8篇 |
1979年 | 9篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 5篇 |
1973年 | 5篇 |
1966年 | 2篇 |
1964年 | 2篇 |
1963年 | 2篇 |
1961年 | 2篇 |
1960年 | 4篇 |
1956年 | 2篇 |
1948年 | 3篇 |
1942年 | 2篇 |
1935年 | 2篇 |
排序方式: 共有550条查询结果,搜索用时 9 毫秒
1.
2.
S. Kalavathi J. Janaki Awadhesh Mani V. Sankara Sastry 《Solid State Communications》2006,139(7):334-338
Some new members of a ruthenocuprate(2212) series have been synthesized by Mn substitution for Ru in Gd1.4Ce0.6Sr2RuCu2O10. Characterization by x-ray diffraction (XRD) phase analysis has been carried out. Changes in structural features on substitution, including a significant change in lattice parameter for a very low substitution level, have been observed. Four-probe resistivity studies indicate the coexistence of superconductivity and magnetism for the pristine compound and a semiconductor-like upturn in resistivity and the absence of superconductivity even for very low levels of Mn substitution. AC susceptibility measurements show a progressive suppression of the magnetic transition temperature as well as a smearing of the magnetic transition as a function of Mn substitution. Possible reasons for the absence of superconductivity have been discussed. 相似文献
3.
The present paper describes various classification techniques like cluster analysis, principal component (PC)/factor analysis to classify different types of base stocks. The API classification of base oils (Group I-III) has been compared to a more detailed NMR derived chemical compositional and molecular structural parameters based classification in order to point out the similarities of the base oils in the same group and the differences between the oils placed in different groups. The detailed compositional parameters have been generated using and nuclear magnetic resonance (NMR) spectroscopic methods. Further, oxidation stability, measured in terms of rotating bomb oxidation test (RBOT) life, of non-conventional base stocks and their blends with conventional base stocks, has been quantitatively correlated with their NMR and elemental (sulphur and nitrogen) data with the help of multiple linear regression (MLR) and artificial neural networks (ANN) techniques. The MLR based model developed using NMR and elemental data showed a high correlation between the ‘measured’ and ‘estimated’ RBOT values for both training (R=0.859) and validation (R=0.880) data sets. The ANN based model, developed using fewer number of input variables (only NMR data) also showed high correlation between the ‘measured’ and ‘estimated’ RBOT values for training (R=0.881), validation (R=0.860) and test (R=0.955) data sets. 相似文献
4.
Three simple and sensitive spectrophotometric methods for the determination of tamoxifen citrate have been developed. They are based on the formation of an ion-association complex between the drug and a dye, Erioglaucine A, which is extractable into chloroform and has an absorption maximum at 625 nm (method A), oxidation with excess potassium permanganate and the determination of unconsumed permanganate using Fast Green FCF (method B), or by the formation of a coloured cobalt thiocyante coordination complex which is extracted into benzene and measured at 635 nm (method C). Beer's law limits for methods A, B, and C are 0.5-3.0 mug ml(-1), 1.0-6.0 mug ml(-1) and 100-500 mug ml(-1), respectively. No interference was observed from tableting additives and the applicability of the methods was examined by analysing tablets containing tamoxifen. The quantities determined were 99.0-100.03% of the exptected values. 相似文献
5.
B3LYP/6-31G* calculations indicate that sequential annelation of benzene rings to the rim of corannulene gradually flattens the skeleton. Pentabenzocorannulene is predicted to exhibit nearly barrierless flipping motion at room temperature. A mixed quartic-quadratic potential successfully explains the inversion barrier and curvature (given by the pi-orbital axis vector angle) relationship. 相似文献
6.
Chirag Patel Vishwanada Sastry Datta Madamwar 《Applied biochemistry and biotechnology》1996,56(1):89-94
To obtain enriched methane content and improve the anaerobic digestion of a mixture of cattle dung, poultry waste, and cheese
whey, the effect of various doses of Tegoprens: T-3012, T-3022, T-5842, T-5843, T-5851, T-5852 has been studied, in bench-scale
digesters. Among them, Tegoprens 3022 showed more than a 45% increase in gas production with higher methane content. 相似文献
7.
Sidhaye DS Kashyap S Sastry M Hotha S Prasad BL 《Langmuir : the ACS journal of surfaces and colloids》2005,21(17):7979-7984
Photoresponsive gold nanoparticle networks were prepared by functionalizing them with azobenzene derivatives. A network can be formed when a linker molecule constituting the azobenzene moiety suitably derivatized on either side with gold surface sensitive groups such as thiols and amines is added to the nanoparticle solution. It is shown that the interparticle spacing in the networks could be controlled by the reversible trans-cis isomerization of the azobenzene moiety induced by UV and visible light, respectively. The photoinduced variation in the interparticle spacings is inferred by the changes in the optical spectra of the gold nanoparticles which display a red or blue shift in the surface plasmon resonance peak depending on a decrease or increase in the interparticle spacing, respectively. Transmission electron microscopy images are in consonance with the evidence from the optical spectra. 相似文献
8.
Application of sodium metaperiodate for the determination of ribavirin in pharmaceutical formulations 总被引:1,自引:0,他引:1
Three simple and sensitive visible spectrophotometric methods (A-C) have been described for the assay of ribavirin either in pure form or in pharmaceutical formulations. They are based on the oxidation of ribavirin with excess sodium metaperiodate and estimating either the products formed (dialdehyde with MBTH, method A; iodate with metol-sulphanilamide, in the presence of Mo(VI) and iodide, method B) or the amount of periodate consumed (celestine blue in the presence of telurium (IV), method C). All of the variables have been optimized and the reaction mechanisms presented. The concentration measurements are reproducible within a R.S.D. of 1.0%. Recoveries are 99.2-101.2%. 相似文献
9.
Spectrophotometric methods for the determination of labetalol hydrochloride in pure and dosage forms
Simple and sensitive Spectrophotometric methods for the determination of labetalol hydrochloride are described. The first two are based on the oxidative coupling reaction of labetalol hydrochloride withp-N,N-dimethyl-phenylenediamine dihydrochloride (method A, max 685 nm) and 3-methyl-2-benzothiazolinone hydrazone hydrochloride (method B, max 545 nm) in the presence of sodium hypochlorite and eerie ammonium sulphate as oxidants, respectively. The third depends on the formation of an ion-association complex of labetalol hydrochloride with suprachen violet 3B at pH 1.3, which is extracted into chloroform (method C, max 565 nm). The methods obey Beer's law and the precision and accuracy of the methods were checked against the B.P. reference method and the relative standard deviations were in the range 0.35–0.52%. These methods are applied to the determination of labetalol in dosage forms. 相似文献
10.
EPR studies have been carried out on solutions of the complexes [Cu(trien)NCS](NO3), [Cu(trien)I]I, [Cu(Me6trien)NCS]B?4 and [Cu(Me6trien)](ClO4)2, (trien = 1,4,7,10-tetraazadecane; Me6trien = hexamethyl trien) in different solvents to investigate the solute-solvent interactions. From calculations of the 4s contribution in the ground state and bond parameters it is found that the axial bond in [Cu(trien)NCS](NO3) dissolved in pyridine is weaker than that in the other complexes dissolved in different solvents. For the two methylated complexes, in spite of the +I effect of the methyl group, the in-plane copper-nitrogen bonds are found to be weak, which is probably due to the changes in structure caused by methylation. 相似文献