Role of non-conventional hydrogen bonding in controlling regioselectivity for nucleophilic aromatic substitution of 4,6-dinitroisoindoline-1,3-dione with 1,2,3-triazole isomers: a computational studies

Structural Chemistry - The nucleophilic aromatic substitution reactions of 4,6-dinitroisoindoline-1,3-dione with 1,2,3-triazole isomers, i.e., 1H-1,2,3-triazole and 2H-1,2,3-triazole, have been...     

Incorporation of azo group at axial position of silatranes: synthesis,characterization and antimicrobial activity

4‐Aminoazobenzene‐derived silatranes bearing urea and aminosuccinimide as linker groups at the axial position are reported. The urea functionality is introduced in a silane ( 2 ) by the rearrangement reaction between 3‐isocyanatopropyltriethoxysilane and 4‐aminoazobenzene. N‐(3‐silatranylpropyl)‐N′‐[(p‐phenyldiazenyl)phenyl]urea and N‐[3‐(3,7,10‐trimethylsilatranyl)propyl]‐N′‐[(p‐phenyldiazene)phenyl]urea were prepared by transesterification reaction of 2 with triethanolamine and trisisopropanolamine, respectively. An efficient method for C? N bond formation is described for the synthesis of 3‐(silatranylpropyl)amino‐N‐[(p‐phenyldiazene)phenyl]pyrrolidine‐2,5‐dione and 3‐[(3,7,10‐trimethylsilatranyl)propyl]amino‐N‐[(p‐phenyldiazene)phenyl]pyrrolidine‐2,5‐dione via aza‐Michael addition reaction of aminopropylsilatranes with 4‐(N‐maleimido)azobenzene under mild conditions. All the compounds were well characterized using elemental analysis, spectroscopic techniques, thermogravimetric analysis and X‐ray diffraction. UV–visible spectroscopy indicates that the 4‐aminoazobenzene‐derived silatranes are capable acetate receptors. The synthesized compounds were screened for possible antimicrobial properties with the results showing a modest activity. Copyright © 2015 John Wiley & Sons, Ltd.     

Selectivity analysis of 99Tc determination by LSC in the field of nuclear decommissioning

Journal of Radioanalytical and Nuclear Chemistry - In this work, two Tc radiochemical isolation methods—a conventional method by Triskem TEVA® resin and a rapid method by Empore?...     

Heat transfer in a second-order fluid for flow around a circular cylinder

The temperature distribution within the thermal boundary layer region due to the flow of an incompressible second-order fluid around a heated circular cylinder, maintained at a constant temperature higher than that of the fluid at infinity, has been obtained near the forward stagnation point by series expansion. The graph of the Nusselt number Nu for the Prandtl number P = 25 and the Eckert number E = 0.1 indicates that the non-Newtonian effect is to increase the heat flux from the cylinder to the liquid in the region 0° ? θ ? 15.7° and to decrease it in the region 15.7° < θ ? 0₀ where θ is the angular distance on the cylinder measured from the forward stagnation point. The critical point θ₀ at which Nu = 0, that is, where the effect of the frictional heating balances the effect of the temperature difference and there is no heat flux either from the cylinder or from the liquid, shifts towards the forward stagnation point with the increase of non-Newtonian effects.