排序方式: 共有62条查询结果,搜索用时 15 毫秒
1.
A new alternative system for the oxidation of secondary alcohols to ketones with DMSO/N2H4.H2O/I2/H2O/CH3CN in hydrated media has been developed. The system also selectively oxidizes the secondary alcoholic groups to the corresponding ketones in the presence of primary alcoholic groups present within the same molecule in moderate to very good yields at reflux temperature. 相似文献
2.
3.
Dimeric chlorobridge complex [Rh(CO)2Cl]2 reacts with two equivalents of a series of unsymmetrical phosphine–phosphine monoselenide ligands, Ph2P(CH2)nP(Se)Ph2 {n = 1( a ), 2( b ), 3( c ), 4( d )}to form chelate complex [Rh(CO)Cl(P∩Se)] ( 1a ) {P∩Se = η2‐(P,Se) coordinated} and non‐chelate complexes [Rh(CO)2Cl(P~Se)] ( 1b–d ) {P~Se = η1‐(P) coordinated}. The complexes 1 undergo oxidative addition reactions with different electrophiles such as CH3I, C2H5I, C6H5CH2Cl and I2 to produce Rh(III) complexes of the type [Rh(COR)ClX(P∩Se)] {where R = ? C2H5 ( 2a ), X = I; R = ? CH2C6H5 ( 3a ), X = Cl}, [Rh(CO)ClI2(P∩Se)] ( 4a ), [Rh(CO)(COCH3)ClI(P~Se)] ( 5b–d ), [Rh(CO)(COH5)ClI‐(P~Se)] ( 6b–d ), [Rh(CO)(COCH2C6H5)Cl2(P~Se)] ( 7b–d ) and [Rh(CO)ClI2(P~Se)] ( 8b–d ). The kinetic study of the oxidative addition (OA) reactions of the complexes 1 with CH3I and C2H5I reveals a single stage kinetics. The rate of OA of the complexes varies with the length of the ligand backbone and follows the order 1a > 1b > 1c > 1d . The CH3I reacts with the different complexes at a rate 10–100 times faster than the C2H5I. The catalytic activity of complexes 1b–d for carbonylation of methanol is evaluated and a higher turnover number (TON) is obtained compared with that of the well‐known commercial species [Rh(CO)2I2]?. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
4.
Molar extinction coefficients of some carbohydrates viz. l-arabinose (C5H10O5), d-glucose (C6H12O6), d-mannose (C6H12O6), d-galactose (C6H12O6), d(-) fructose (C6H12O6) and maltose (C12H24O12) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by gamma ray transmission method in a
narrow beam good geometry set-up. These coefficients have been found to depend upon the photon energy following a 4-parameter
polynomial. These extinction coefficients for different sugars having the same molecular formula have same values varying
within experimental uncertainty. Within concentration ranges studied, Beer-Lambert law is obeyed very well. 相似文献
5.
Sarmah MP Gonnade RG Shashidhar MS Bhadbhade MM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(7):2103-2110
Racemic 2,4-di-O-acyl-myo-inosityl 1,3,5-orthoesters undergo transesterification catalyzed by sodium carbonate with varying ease of reaction in the solid state; reactions in solution and melt do not show such varied differences. An interesting crystal of a 1:1 molecular complex of highly reactive racemic 2,4-di-O-benzoyl-myo-inosityl 1,3,5-orthoformate and its orthoacetate analogue exhibited better reactivity than the latter component alone. Single-crystal X-ray structures of the reactants have been correlated with the observed differences in the acyl-transfer efficiencies in the solid state. Although each of the derivatives helically self-assembles around the crystallographic 2(1) axis linked through O-H...O hydrogen bonding, the pre-organization of the reactive groups (C=O [El] and OH [Nu]), C-H...O and the C-H...pi interactions are significantly more favourable for the reactive derivatives than the less reactive ones. Bond-length distributions also showed differences; the O-C bond of the axial benzoyl group, which gets cleaved during the reaction, is longer (1.345-1.361 A) relative to the chemically equivalent O-C bond of the equatorial benzoyl group (1.316-1.344 A) in the reactive derivatives. These bond-length differences are not significant in the less reactive derivatives. The overall molecular organization is different too; the strikingly discrete helices, which may be viewed as "reaction tunnels" and are held by interhelical interactions, are clearly evident in the reactive derivatives in comparison with the less reactive ones. 相似文献
6.
We present some identities and congruences for the general partition function p r (n). In particular, we deduce some known identities for Ramanujan’s tau function and find simple proofs of Ramanujan’s famous partition congruences for modulo 5 and 7. Our emphasis throughout this paper is to exhibit the use of Ramanujan’s theta functions to generate identities and congruences for general partition function. 相似文献
7.
Kangkan Sarmah Amlan J. Kalita Ankur K. Guha 《International journal of quantum chemistry》2023,123(1):e27006
Attachment of one electron to 1,2-diBeX-benzene and 1,2-diZnX-benzene derivatives leads to the formation of stronger Be Be and Zn Zn interaction compared to the neutral one. This is reflected in the dramatic shortening of the Be Be and Zn Zn distance. The formation of these 2-center-1-electron bonds have also been confirmed by topological survey of electron density using quantum theory of atoms in molecules and electron localization function. The formation of these bonds is expected to render stability to these radical anions. These radical anions are stable toward electron detachment and computed bond dissociation energy values are also significant. 相似文献
8.
Birendra N. Goswami Jiban C. Sarmah Kataky Jogendra N. Baruah 《Journal of heterocyclic chemistry》1984,21(4):1225-1229
A series of 1-(2,4-dichlorobenzoyl)thiosemicarbazides, s-triazoles and their methyl derivatives have been synthesised by condensation of 2,4-dichlorobenzoyl hydrazine with aryl isothiocyanates. Subsequent ring closure of the substituted thiosemicarbazides yielded the s-triazoles, and reaction with methyl iodide resulted methyl derivatives. All the compounds were subjected to in vitro testing against two gram-positive and two gram-negative bacteria. Antibacterial activity was found to be moderate to good in most of the compounds. 相似文献
9.
The purpose of this paper is to show that evolutionary stable market equilibrium is achievable through complete disintermediation of auctioneers if the option of bargaining-based supply chain contracting exists. The paper analyzes the evolutionary dynamics of a market that caters both the scopes of auction-intermediation and supply chain contracting to a set of homogeneous buyers and sellers. The motivation of this work developed from the contradiction between the theoretical framework of Lu and McAfee (1996) that identifies auction to be evolutionary stable over bargaining and the real instance of sustained disintermediation of auctioneers in the world’s largest tea industry in India where supply chain contracting is the other option of trading. 相似文献
10.
We present the generating function for \(c\phi _6(n)\), the number of generalized Frobenius partitions of \(n\) with \(6\) colors, in terms of Ramanujan’s theta functions and exhibit \(2\), and \(3\)-dissections of it that yield the congruences \(c\phi _6(2n+1)\equiv 0~(\text {mod}~4)\), \(c\phi _6(3n+1)\equiv 0~(\text {mod}~3^2)\) and \(c\phi _6(3n+2)\equiv 0~(\text {mod}~3^2)\). 相似文献