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Separation of 23 dansylated amino acids by micellar electrokinetic chromatography at low temperature
Summary The baseline separation of 23 dansylated amino acids (including 3 didansylated species) is reported. Lowering of the analysis
temperature and fine control of the surfactant concentration were essential in obtaining this result. Calibration graphs with
good linearity were obtained. 相似文献
4.
Minimal, rigid foliations by curves on ℂℙ
n 总被引:1,自引:0,他引:1
We prove the existence of minimal and rigid singular holomorphic foliations by curves on the projective space ℂℙ
n
for every dimension n≥2 and every degree d≥2. Precisely, we construct a foliation ℱ which is induced by a homogeneous vector field of degree d, has a finite singular set and all the regular leaves are dense in the whole of ℂℙ
n
. Moreover, ℱ satisfies many additional properties expected from chaotic dynamics and is rigid in the following sense: if
ℱ is conjugate to another holomorphic foliation by a homeomorphism sufficiently close to the identity, then these foliations
are also conjugate by a projective transformation. Finally, all these properties are persistent for small perturbations of
ℱ.?This is done by considering pseudo-groups generated on the unit ball 𝔹
n
⊆ℂ
n
by small perturbations of elements in Diff(ℂ
n
,0). Under open conditions on the generators, we prove the existence of many pseudo-flows in their closure (for the C
0-topology) acting transitively on the ball. Dynamical features as minimality, ergodicity, positive entropy and rigidity may
easily be derived from this approach. Finally, some of these pseudo-groups are realized in the transverse dynamics of polynomial
vector fields in ℂℙ
n
.
Received March 7, 2002 / final version received November 26, 2002?Published online February 7, 2003
Most of this work has been carried out during a visit of the first author to IMPA/RJ and a visit of the second author to the
University of Lille 1. We would like to thank these institutes for hospitality and express our gratitude to CNPq-Brazil and
CNRS-France for the financial support which made these visits possible. We are also indebted to Paulo Sad, Marcel Nicolau
and the referee whose comments helped us to improve on the preliminary version. Finally, the second author has partially conducted
this research for the Clay Mathematics Institute. 相似文献
5.
Mary E. Neubert DAVID G. ABDALLAH Jr Sandra S. Keast Julie M. Kim Soonnam Lee Ryan M. Stayshich Margaret E. Walsh Rolfe G. Petschek Shin-Tson Wu 《Liquid crystals》2003,30(6):711-731
New diphenyldiacetylenes of the type with A, B = H and/or F; m = 0, 1; n = 1-4; and X = C n H 2n + 1 , F, CF 3 or CN were synthesized and their mesomorphic properties determined by hot stage polarizing microscopy and DSC. When m = 0, all of these compounds showed only a nematic phase except when X = CF 3 when both nematic and smectic A phases were seen. Both clearing and melting temperatures were higher than those reported for substitution with the corresponding alkyl chains but the much larger increase in clearing temperatures produced considerably wider nematic phases. Eutectic mixtures of a few of these olefins yielded nematic materials also having much wider temperature ranges and higher clearing temperatures than the eutectic mixtures of the alkyl compounds, while retaining their high birefringence and low viscosities. Such materials are of interest for beam-steering devices.
Four of the diacetylenes with m = 1 ( A, B = H) were also prepared ( X = C 6 H 13 , F, n = 2, 3). When X was C 6 H 13 ( n = 2), the nematic range was smaller in the 2- than in the 1-olefin but wider than in the alkyl series. When X = F, either no nematic phase or a monotropic one was observed, whereas the 1-olefins gave a much wider nematic phase. Both transition temperatures were lower than those for the corresponding 1-olefin and alkyl analogues. The compound with X = C 6 H 13 and n = 2 had a melting temperature below room temperature. 相似文献
Four of the diacetylenes with m = 1 ( A, B = H) were also prepared ( X = C 6 H 13 , F, n = 2, 3). When X was C 6 H 13 ( n = 2), the nematic range was smaller in the 2- than in the 1-olefin but wider than in the alkyl series. When X = F, either no nematic phase or a monotropic one was observed, whereas the 1-olefins gave a much wider nematic phase. Both transition temperatures were lower than those for the corresponding 1-olefin and alkyl analogues. The compound with X = C 6 H 13 and n = 2 had a melting temperature below room temperature. 相似文献
6.
Zero-schemes on smooth complex projective varieties, forcing all elements of ample and free linear systems to be reducible, are studied. Relationships among the minimal length of such zero-schemes, the positivity of the line bundle associated with the linear system, and the dimension of the variety are established. Bad linear spaces are also investigated. 相似文献
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K. Jaques W. Buda L. Dumortier J. Van der Eycken Arnold Venema Pat Sandra 《Journal of separation science》1994,17(2):72-73
Capillary GC on permethyl α-, β-, and γ-cyclodextrins has been applied to separate and quantify the enantiomers of some 2,3-iso-propylidene-1,2,3-cyclohexanetriol derivatives. Quantitative CGC data are compared to those obtained with chiral shift 1H NMR. 相似文献
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