排序方式: 共有27条查询结果,搜索用时 15 毫秒
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Leena V. Bora Manan Rathod Kush Kapadia Sonal Thakkar R.N. Reddy Sandesh S. Chougule Nisha V. Bora 《印度化学会志》2022,99(7):100560
In this study, we report a waste material-ground granulated blast furnace slag (GGBFS) as a low cost geopolymer, hybridised with ZnO to form a novel and efficient photocatalyst capable of discolouring textile wastewater. GGBFS is a waste material in an iron industry. Methylene blue was used as the probe dye and natural sunlight was used for activation of the photocatalyst. It was observed that under the experimental conditions, ZnGP-40 exhibited twice the discoloration efficiency than conventionally used ZnO or TiO2. This enhanced performance is majorly attributed to increased surface area of ZnO when strewn in the GGBFS matrix. The photocatalysts were characterized by SEM, TEM, PSA, TGA, BET and UV–Vis/NIR. The effect of photocatalyst loading, speed of agitation and solar insolation has also been studied. Since this study has been performed in direct sunlight, it exhibits a realizable application of solar energy in the treatment of wastewater. 相似文献
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Anchoring Mechanism of ZnO Nanoparticles on Graphitic Carbon Nanofiber Surfaces through a Modified Co‐Precipitation Method to Improve Interfacial Contact and Photocatalytic Performance 下载免费PDF全文
Dr. Gowra Raghupathy Dillip Dr. Arghya Narayan Banerjee Dr. Veettikunnu Chandran Anitha Dr. Sang Woo Joo Dr. Bong Ki Min Dr. Sandesh Y. Sawant Dr. Moo Hwan Cho 《Chemphyschem》2015,16(15):3214-3232
A facile three‐step co‐precipitation method is developed to synthesize graphitic carbon nanofibers (CNFs) decorated with ZnO nanoparticles (NPs). By interchanging intermediate steps of the reaction processes, two kinds of nanohybrids are fabricated with stark morphological and physicochemical differences. The morphologies differ because of the different chemical environments of the NP/nanocluster formation. The hybrid with larger and non‐uniform ZnO nanocluster size is formed in liquid phase and resulted in considerable interfacial defects that deteriorate the charge‐transfer properties. The hybrid with smaller and uniform ZnO NPs was formed in a dry solid phase and produced near‐defect‐free interfaces, leading to efficient charge transfer for superior photocatalytic performance. The results broaden the understanding of the anchoring/bonding mechanism in ZnO/CNF hybrid formation and may facilitate further development of more effective exfoliation strategies for the preparation of high‐performance composites/hybrids. 相似文献
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Kundan Tayade Amanpreet Kaur Sandesh Tetgure G. Krishana Chaitanya Narinder Singh Anil Kuwar 《Analytica chimica acta》2014
The (13E,19E)-N1′,N3′-bis[4-(diethylamino)-2-hydroxybenzylidene]malonohydrazide (L) has been developed for the detection of Th4+ ions using dual channel signalling system. The UV–vis absorbance and fluorescence spectroscopic data revealed the formation of L–Th4+ complex in 1:1 equilibrium. The density functional theory (DFT) also confirms the optimum binding cavity for the recognition of metal ion. The binding constant computed from different mathematical models for an assembly of L–Th4+. The detection limit of L for Th4+ recognition is to a concentration down to 0.1 μM (0.023 μg g−1). The present sensing system is also successfully applied for the detection of Th4+ ion present in soil near nuclear atomic plants. 相似文献
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Doiphode Vidya Vairale Priti Sharma Vidhika Waghmare Ashish Punde Ashvini Shinde Pratibha Shah Shruti Pandharkar Subhash Hase Yogesh Aher Rahul Nair Shruthi Jadkar Vijaya Bade Bharat Prasad Mohit Rondiya Sachin Jadkar Sandesh 《Journal of Solid State Electrochemistry》2021,25(6):1835-1846
Journal of Solid State Electrochemistry - Herein, we report the synthesis of ZnO nanorod films onto FTO (fluorine-doped tin oxide) substrates using the solution-processed electrodeposition method.... 相似文献
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This study reports the comparison of heat transfer and friction factor characteristics of helical screw inserts in Al2O3–water and carbon nano-tube–water nano-fluids through a straight pipe in transition regime with constant heat flux boundary condition. Experiments were carried out by using 0.15% volume concentration of Al2O3–water and carbon nano-tube–water nano-fluid with helical tape inserts of twist ratio, TR = 1.5, 2.5, and 3. The thermal performance of helical screw tape inserts with the carbon nano-tube–water nano-fluid is found -to be higher when compared to the Al2O3–water nano-fluid. In addition, the maximum enhancement in heat transfer was obtained for the carbon nano-tube–water nano-fluid with helical tape inserts of twist ratio 1.5. The increase in pressure drop of the Al2O3–water nano-fluid with helical screw tape inserts is found to be higher compared to the carbon nano-tube–water nano-fluid helical screw tape inserts at lower value of twist ratio. 相似文献
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Dr. Sachin Thawarkar Dr. Sachin R. Rondiya Dr. Nelson Y. Dzade Dr. Nageshwar Khupse Dr. Sandesh Jadkar 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(26):7408-7417
Lead-free double perovskites have emerged as stable and non-toxic alternatives to Pb-halide perovskites. Herein, the synthesis of Fe-doped Cs2AgBiCl6 lead-free double perovskites are reported that display blue emission using an antisolvent method. The crystal structure, morphology, optical properties, band structure, and stability of the Fe-doped double perovskites were investigated systematically. Formation of the Fe-doped Cs2AgBiCl6 double perovskite is confirmed by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis. XRD and thermo-gravimetric analysis (TGA) shows that the Cs2AgBiCl6 double perovskite has high structural and thermal stability, respectively. Field emission scanning electron microscopy (FE-SEM) analysis revealed the formation of dipyramidal shape Cs2AgBiCl6 crystals. Furthermore, energy-dispersive X-ray spectroscopy (EDS) mapping shows the overlapping of Cs, Bi, Ag, Fe, and Cl elements and homogenous incorporation of Fe in Cs2AgBiCl6 double perovskite. The Fe-doped Cs2AgBiCl6 double perovskite shows a strong absorption at 380 nm. It extends up to 700 nm, suggesting that sub-band gap states transition may originate from the surface defect of the doped perovskite material. The radiative kinetics of the crystals was studied using the time-correlated single-photon counting (TCSPC) technique. Lattice parameters and band gap value of the Fe-doped Cs2AgBiCl6 double perovskites predicted by the density functional theory (DFT) calculations are confirmed by XRD and UV/Visible spectroscopy analysis. Time-dependent photo-response characteristics of the Fe-doped Cs2AgBiCl6 double perovskite show fast response and recovery time of charge carriers. We believe that the successful incorporation of Fe in lead-free, environmentally friendly Cs2AgBiCl6 double perovskite can open a new class of doped double perovskites with significant potential optoelectronics devices fabrication and photocatalytic applications. 相似文献
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Surendra D. Barewar Sandesh S. Chougule J. Jadhav S. Biswas 《Journal of Thermal Analysis and Calorimetry》2018,134(3):1493-1504
The comparative study on the thermo-physical properties of water-based ZnO nanofluids and Ag/ZnO hybrid nanofluids is reported in the present study. The outer surface of ZnO nanoparticles was modified with a thin coating of Ag nanoparticles by a wet chemical method for improved stability and heat transfer properties. The ZnO and Ag/ZnO nanofluids were prepared with varying volume concentration (??=?0.02–0.1%). The synthesized nanoparticles and nanofluids were characterized with different characterization methods viz., scanning electron microscopy, X-ray diffraction, dynamic light scattering, thermal conductivity measurement, and viscosity measurement. Results show that thermal conductivity of Ag/ZnO hybrid nanofluids is found to be significantly higher compared to ZnO nanofluids. The maximum thermal conductivity an enhancement for Ag/ZnO nanofluid (??=?0.1%) is found to 20% and 28% when it compared with ZnO nanofluid (??=?0.1%) and water, respectively. 相似文献