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1.
A new microscopic model of anomalous muonium for the elemental semiconductors is proposed. The relevant configuration consisting
of both a diamagrentic molecule Si−Mu and an unpaired orbital e− is contained into a semivacancy of the real lattice. By using the unrestricted Hartree-Fock computational method the principal
properties of the system are established. A dynamical version of the model together with a question on the formation of such
system are discussed. 相似文献
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3.
A. N. Pestryakov R. H. Muhutdinov N. A. Samoylov 《Reaction Kinetics and Catalysis Letters》1994,53(1):211-215
Catalysts on the basis of ultradispersed powders of complex oxides of transition metals have been studied in the process of low temperature deep oxidation of organic compounds. 相似文献
4.
This paper is devoted to the matter effect and its role in Long-Baseline experiments. As examples, the NOvA and DUNE experiments will be discussed. 相似文献
5.
R. Kh. Amirov N. A. Vorona A. V. Gavrikov G. D. Liziakin V. P. Polistchook I. S. Samoylov V. P. Smirnov R. A. Usmanov I. M. Yartsev 《Physics of Atomic Nuclei》2015,78(14):1631-1634
One of the key problems in the development of plasma separation technology is designing a plasma source which uses condensed spent nuclear fuel (SNF) or nuclear wastes as a raw material. This paper covers the experimental study of the evaporation and ionization of model materials (gadolinium, niobium oxide, and titanium oxide). For these purposes, a vacuum arc with a heated cathode on the studied material was initiated and its parameters in different regimes were studied. During the experiment, the cathode temperature, arc current, arc voltage, and plasma radiation spectra were measured, and also probe measurements were carried out. It was found that the increase in the cathode heating power leads to the decrease in the arc voltage (to 3 V). This fact makes it possible to reduce the electron energy and achieve singly ionized plasma with a high degree of ionization to fulfill one of the requirements for plasma separation of SNF. This finding is supported by the analysis of the plasma radiation spectrum and the results of the probe diagnostics. 相似文献
6.
L. Seetha Lakshmi V Sridharan DV Natarajan V Sankara Sastry T S Radhakrishnan 《Pramana》2002,58(5-6):1019-1026
Mn site is substituted with closed shell ions (Al, Ga, Ti, Zr and a certain combination of Zr and Al) and also with Fe and
Ru ions carrying the magnetic moment (S=5/2 and 2 respectively) at a fixed concentration of 5 at %. Substitution did not change either the crystal symmetry or the
oxygen stoichiometry. All substituents were found to suppress both the metal-insulator and ferromagnetic transition temperatures
(T
p(ρ) and T
C, respectively) to varied extents. Two main contributions identified for the suppression are the lattice disorder arising
due to difference in the ionic radii between the substituent (r
M) and the Mn3+ ion (r
Mn
3+) and in the case of the substituents carrying a magnetic moment, the type of magnetic coupling between the substituent and
that of the neighboring Mn ion. 相似文献
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8.
McHedlov-Petrossyan NO Vodolazkaya NA Surov YN Samoylov DV 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(11-12):2747-2760
Stepwise dissociation and tautomerism of 2,4,5,7-tetranitrofluorescein (TNF) were studied by using vis-spectroscopy in dimethylsulfoxide (DMSO), in aqueous acetone, and in cetyl-trimethylammonium chloride (CTAC) micellar solutions at ionic strength of the bulk phase 4.00M KCl. The pK(a) values in DMSO and 90 mass% (CH3)2CO as well as the 'apparent'pK(a)(a) values of the substance in micellar media were determined spectrophotometrically. The neutral (molecular) form H2R is found to be completely converted into the colorless lactone. Moreover, the lactonic structure, yellow due to 'nitrophenolate' absorption band, predominates also in the case of TNF dianion R2-. Contrary to the unsubstituted fluorescein, and like 2,4,5,7-tetrabromofluorescein (eosin), the monoanion HR- of TNF with lambda(max) 522-525 nm and E(max) approximately (60-62)x10(3) dm(3)mol(-1)cm(-1) exists mainly as a deeply and intensively colored structure with non-ionized carboxylic and ionized hydroxylic group; its fluorescence spectra in various media are registered. In 90% acetone, the Stokes shift is 1.17x10(3)cm(-1), fluorescence lifetime equals 2.3 ns. An extremely expressed trend to dianion-lactone formation of R2- ion of TNF is confirmed in the systems studied. For TNF in DMSO, in aqueous acetone, in surfactant micelles, and in trichloromethane extracts of ionic associatiates with N(n-Bu)4+ and N(n-Hept)4+, the deeply colored 'quinon-phenolate' dianion, typical for all hydroxyxanthenes, is not registered at all. The sequence of dissociation of functional groups in solution is confirmed using IR spectroscopy in DMSO. 相似文献
9.
F. A. Emanov A. V. Andrianov K. V. Astrelina V. V. Balakin A. M. Barnyakov O. V. Belikov D. E. Berkaev M. F. Blinov Yu. M. Boimelshtain D. Yu. Bolkhovityanov N. S. Dikansky A. R. Frolov G. V. Karpov A. S. Kasaev A. A. Kondakov I. V. Kuptsov I. A. Koop G. Ya. Kurkin R. M. Lapik N. N. Lebedev A. E. Levichev Yu. I. Maltseva A. A. Murasev D. A. Nikiforov A. V. Pavlenko V. V. Rashchenko S. L. Samoylov S. V. Vasiliev I. M. Zemlyansky Yu. A. Rogovsky S. A. Krutikhin A. Yu. Martinovsky S. V. Motigin A. M. Pilan I. K. Sedliarov A. G. Tribendis 《Physics of Particles and Nuclei Letters》2018,15(7):720-723
10.
V.G. Alpatov Yu.D. Bayukov A.V. Davydov Yu.N. Isaev G.R. Kartashov M.M. Korotkov V.E. Rad'ko A.A. Sadovsky V.M. Samoylov 《Hyperfine Interactions》1997,107(1-4):231-246
The temperature dependence of the 109Ag γ-ray self-absorption was investigated for the horizontal and vertical directions of emission. The source was a single-crystal
silver plate containing atoms of parent radionuclide 109Cd. Gamma-radiation of this γ-source and that of the monitoring γ-source, 57Co, were registered by a pair of Ge(Li)-detectors. As a result of cooling the source from 77 K to ~12 K a relative decrease
was observed of the intensity of the horizontally emitted γ-rays equal to 0.00064±0.00044. For the vertical direction the
corresponding intensity change turned out to be -0.00047±0.00051. Although these data, as one would see, give some evidence
for the possible effect of the gravitation on the resonant γ-ray absorption, future measurements must show if these results
aren’t a consequence of any apparatus effect. The ways for developments in this study are discussed and some hindrances are
considered.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献