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1.
2‐Amino‐4‐ethoxycarbonylpyridine 1 was used as a starting material in the synthesis of some 4‐substituted‐N1‐2‐pyridylsulfanilamide derivatives to evaluate their antimicrobial activity. The obtained compounds were of no particular effect against the tested organisms except for a noticeable inhibition of B. subtilis, which was of varying extents but remained clearly significant. 相似文献
2.
Ethyl- and propylammonium nitrate are novel ionic solvents, liquid at room temperature, suitable for use as selective solvents for the isolation of analytes containing proton donor functional groups (alcohols, amines, phenols, carboxylic acids, etc.) by liquid-liquid distribution. These solvents form immiscible solvent pairs with non-polar aliphatic and aromatic hydrocarbons, ethers and alkyl halide solvents (e.g., methylene chloride, chloroform). Analytes can be recovered from the ionic solvents by back-extraction into ah organic solvent after dilution with water or pH buffer or, preferably, by extractive derivatization when gas chromatography is used for the analyses, avoiding the accumulation of salt on the column that results in poor baseline stability. Alkylation, acylation and particularly silylation are suitable methods for extractive derivatization using standard reaction conditions. Applications are presented for the isolation of polar analytes from an urban dust, shale oil and urine samples and for the determination of low-molecular-weight alcohols in gasahol and glycerol in soap. Liquid-liquid chromatographic systems with the liquid organic salt as stationary phase can be used to predict distribution constants for a particular separation and for the separation of polar solutes, particularly isomeric compounds possessing a proton donor functional group. 相似文献
3.
4.
Metwally Nadia H. Abdelrazek Fathy M. Eldaly Salwa M. 《Research on Chemical Intermediates》2016,42(2):1071-1089
Research on Chemical Intermediates - The starting 3-(3,5-dimethyl-1H-pyrazol-1-yl)-3-oxopropanenitrile (1) reacts with phenyl isothiocyanate and ethyl bromoacetate to give the corresponding... 相似文献
5.
Jamil Salhi James MacLaurin Salwa Toumi 《Stochastics An International Journal of Probability and Stochastic Processes》2018,90(1):49-60
In this paper we obtain a time-uniform propagation estimate for a system of interacting diffusion processes. Using a well defined metric function h , our result guarantees a time-uniform estimate for the convergence of a class of interacting stochastic differential equations towards their mean field limit, under conditions that ensure that the decay associated to the internal dynamics term dominates the interaction and noise terms. Our result should have diverse applications, particularly in neuroscience, and allows for models more elaborate than the one of Wilson and Cowan. In particular, the internal dynamics need not be that of linear decay. 相似文献
6.
The adsorption behavior of Rhodamine B dye from aqueous solutions was investigated onto the cation-exchange resin, Duolite C-20 (hydrogen form). The effects of various experimental factors; sorbent amount, contact time, dye concentration and temperature, were studied by using the batch technique. Lagergren pseudo-first-order equation shows good applicability with high correlation coefficients for all ranges of initial dye concentrations and at different temperatures. This equation was used to describe the kinetics of the dye adsorption process. The adsorption constants were evaluated by using both the Langmuir and Freundlich adsorption isotherm models. Thermodynamic parameters were obtained and it was found that the adsorption of Rhodamine B dye onto Duolite C-20 resin was an endothermic and spontaneous process at the temperatures under investigation. 相似文献
7.
AbstractIn continuing our efforts to develop new potent anticancer candidates, a new series of 9-ethylcarbazoles carrying at position 3 various heterocyclic substituents such as 2-imino-2H-chromenes 5a–e, 2-oxo-2H-chromenes 6a–e, 3-imino-3H-benzo[f]chromene 8, 3-oxo-3H-benzo[f]chromene 9, 2-pyridones 11, 14, pyrazole 19, pyrimidine 23, pyrido[1,2-a]pyrimidine 27, 2H-pyran-2-one 30, and pyrano[2,3-d]pyrimidinetrione 34 were efficiently synthesized, characterized and evaluated for their in vitro antitumor activity. The mechanism for the synthesis of compounds was also discussed. Most of the synthesized compounds were displayed the considerable anticancer activities against three human tumor cells lines, in particular, colon carcinoma (HCT-116), hepatocellular carcinoma (HepG-2) and breast cancer (MCF-7). Compound 6d proves as most active molecule in this study with special effectiveness against the human HCT-116 and HepG-2 as its IC50 values are 1.50, 0.90?μM, respectively, when doxorubicin is compared. Compound 34 was also found to have high activity against HepG-2, HCT-116 and moderate activity against MCF-7. 相似文献
8.
Mohammad Nasser H. EL-Sherbiny Gamal M. Hammad Ali A. Askar Ahmed A. El- Nour Salwa A. Abou 《Cellulose (London, England)》2022,29(3):1791-1805
Cellulose - Antibacterial coatings based on bacterial cellulose (BC) have been widely used in many fields including food packaging and wound dressing. In this study, we aimed to synthesis of... 相似文献
9.
Wee Ching Tan Siti Salwa Alias Ahmad Badri Ismail Ahmad Azmin Mohamad 《Journal of Solid State Electrochemistry》2012,16(6):2103-2112
The effect of a gel polymer electrolyte (GPE) as the redox electrolyte used in dye-sensitized solar cells was studied. A GPE solution consisting of 0.5?M sodium iodide, 0.05?M iodine, and ethylene carbonate/propylene carbonate (1:1 w/w) binary solvents was mixed with increasing amounts of styrene–acrylonitrile (SAN). Bulk conductivity measurements show a decreasing trend from 4.54 to 0.83×10?3?S?cm?1 with increasing SAN content. The GPE exhibits Newtonian-like behavior and its viscosity increases from 0.041 to 1.093?Pa?s with increasing SAN content. A balance between conductivity (1.3?×?10?3?S?cm?1) and viscosity (1.4?Pa?s) is observed at 19?wt.% SAN. Fourier transform infrared spectroscopy detects elevated ring torsion at 706?cm?1 upon the addition of SAN into the liquid electrolyte. This indicates that SAN does not bond with the liquid electrolyte. Finally, the potential stability window of 19?wt.% SAN, which ranges from ?1.68 to 1.38?V, proves its applicability in solar cells. 相似文献
10.
Fifteen tetraalkylammonium salts of the functionalized sulfonic acids N,N-bis(2-hydroxy- ethyl)-2-aminoethanesulfonic acid, 2-(cyclohexylamino)ethanesulfonic acid and 2-hydroxy-4- morpholinopropanesulfonic acid were synthesized and the eight organic salts that were liquid at room temperature were characterized by physical, spectroscopic and chromatographic methods. All liquid salts were viscous at room temperature but after dilution with a suitable cosolvent could be used as mobile phases in liquid chromatography. For this application, the rapid deterioration of silica-based column packings was more of a deterrent than the physical properties of the salts. The tetraalkylammonium sulfonates had wide liquid ranges and were stable as column packings up to 150–180°C, making them suitable for use in gas chromatography. Their solvent properties were characterized by solvatochromic parameters [ET(30), π*, α and β] and by thermodynamic parameters determined by gas chromatography. Good agreement was found between the predictions of the two methods. The liquid salts showed strong orientation and solvent hydrogen bond acceptor capacity with weak hydrogen bond donor capacity in spite of the functionalization of the anions. The most probable reason for the weak hydrogen bond donor capacity of the anions is the unavailability of these functional groups for solute interactions owing to their preferential involvement in the formation of anion association complexes. The chemically defined structure, unique solvent properties and wide usable temperature ranges make the tetraalkylammonium sulfonates useful stationary phases for gas chromatography. 相似文献