全文获取类型
收费全文 | 929篇 |
免费 | 52篇 |
国内免费 | 9篇 |
专业分类
化学 | 670篇 |
晶体学 | 11篇 |
力学 | 12篇 |
数学 | 87篇 |
物理学 | 210篇 |
出版年
2023年 | 7篇 |
2022年 | 13篇 |
2021年 | 18篇 |
2020年 | 17篇 |
2019年 | 27篇 |
2018年 | 22篇 |
2017年 | 11篇 |
2016年 | 32篇 |
2015年 | 21篇 |
2014年 | 30篇 |
2013年 | 42篇 |
2012年 | 54篇 |
2011年 | 64篇 |
2010年 | 54篇 |
2009年 | 48篇 |
2008年 | 48篇 |
2007年 | 58篇 |
2006年 | 57篇 |
2005年 | 46篇 |
2004年 | 37篇 |
2003年 | 33篇 |
2002年 | 30篇 |
2001年 | 19篇 |
2000年 | 23篇 |
1999年 | 8篇 |
1998年 | 10篇 |
1997年 | 4篇 |
1996年 | 8篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 7篇 |
1991年 | 10篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 9篇 |
1985年 | 12篇 |
1984年 | 4篇 |
1983年 | 7篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1978年 | 4篇 |
1976年 | 11篇 |
1975年 | 7篇 |
1973年 | 4篇 |
1970年 | 5篇 |
1969年 | 3篇 |
1967年 | 3篇 |
1966年 | 3篇 |
排序方式: 共有990条查询结果,搜索用时 62 毫秒
1.
2.
We study the nonrelativistic limit of the Cauchy problem for the nonlinear Klein-Gordon equation and prove that any finite
energy solution converges to the corresponding solution of the nonlinear Schr?dinger equation in the energy space, after the
infinite oscillation in time is removed. We also derive the optimal rate of convergence in .
Received: 13 July 2000 / Published online: 1 February 2002 相似文献
3.
Joji Ohshita Ryosuke Taketsugu Yuki Nakahara Atsutaka Kunai 《Journal of organometallic chemistry》2004,689(20):3258-3264
Selective dehydrogenative coupling of di- and trihydrosilanes with alcohols catalyzed by PdCl2 or NiCl2 afforded alkoxyhydro- and dialkoxyhydrosilanes in good yield. Further treatment of the resulting alkoxyhydrosilanes with carbon tetrachloride or allyl bromide in the presence of the same catalyst led to the formation of alkoxychloro- and alkoxybromosilanes, respectively. Similar reactions of dialkoxyhydrosilanes with carbon tetrachloride afforded dialkoxychlorosilanes in good yield, although contamination of small amounts of trialkoxysilanes and alkoxydichlorosilanes was detected in the products. Selective substitution of the alkoxyhalosilanes with nucleophiles is also reported. 相似文献
4.
5.
It is an important challenge to analyze a three-dimensional thermal flow field in engineering, science, and agriculture. For such an analysis, it is essential to measure physical quantities such as temperature and velocity over the entire thermal flow field. This paper presents a measurement system based on color image processing for temperature and velocity vector distributions in a three-dimensional thermal flow field. Flow visualization is accomplished by the use of thermo-sensitive liquid crystal tracers. An algorithm for the color-to-temperature transformation using a multi-layer feed-forward neural network is applied to three-dimensional natural convection in a rotating cylindrical cell. Two-dimensional temperature distributions in a slit plane are obtained by using the algorithm. A three-dimensional temperature distribution is consequently constructed by interpolating the two-dimensional distributions using the B-spline function. In addition, the Spatio-Temporal correlation method is applied to the natural convection to obtain a three-dimensional velocity vector distribution. 相似文献
6.
Ryosuke Sakai Issei Otsuka Toshifumi Satoh Ryohei Kakuchi Harumi Kaga Toyoji Kakuchi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):325-334
The asymmetric polymerization of 4′‐isocyanatobenzo‐18‐crown‐6 with the lithium amide of (S)‐(2‐methoxymethyl)pyrrolidine successfully proceeded to afford end‐functionalized poly(4′‐isocyanatobenzo‐18‐crown‐6) with (S)‐(2‐methoxymethyl)pyrrolidine (polymer 2 ). In the circular dichroism (CD) spectrum of 2 , a clear positive Cotton effect was observed in the range of 240–350 nm corresponding to the absorption of the polymer backbone, indicating that 2 partially formed a one‐handed helical structure, which was preserved by the chirality of (S)‐(2‐methoxymethyl)pyrrolidine bonding to the terminal end in 2 . In the titration experiments for the CD intensity of 2 in the presence of D ‐ and L ‐Phe·HClO4 (where Phe is phenylalanine), a small but remarkable difference was observed in the amount of the chiral guest needed for saturation of the CD intensity and in the saturated CD intensity, indicating that the extremely stable, one‐handed helical part should exist in the main chain of 2 , which was not inverted even when the unfavorable chiral guest for the predominant helical sense, L ‐Phe·HClO4, was added. In addition, helical polymer 2 exhibited a chiral discrimination ability toward racemic guests; that is, the guests were extracted from the aqueous phase into the organic phase with enantiomeric excess. The driving force of the chiral discrimination ability of 2 should certainly be attributed to the one‐handed helical structure in 2 . © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 325–334, 2006 相似文献
7.
Takahiro Gunji Ryosuke Shimano Koji Arimitsu Yoshimoto Abe 《Journal of polymer science. Part A, Polymer chemistry》2006,44(8):2542-2550
Tetraethoxysilane (TEOS) and polyethoxysiloxanes (PEOSs; prepared by the acid‐catalyzed hydrolytic polycondensation of TEOS) were subjected to the sol–gel process in the presence of cetyltrimethylammonium bromide (CTAB), respectively. The PEOSs with Mw 700–26,000, as prepared by sol–gel coating of TEOS and PEOS under various conditions, were used. Uniform and crack‐free thin films of thickness 276–613 nm were prepared by spin‐coating of a PEOS solution containing CTAB. When the coating films were sintered at 400 °C, the combustion of ethoxy groups and CTAB took place to provide porous silica thin films. The structure of the thin films was found to be dependent on the molecular weight of PEOS and the molar ratio of CTAB/Si: lamellar or hexagonal phase was observed for Mw less than 15,000 and for CTAB/Si molar ratios greater than 0.10. Honeycomb structures were observed for Mw less than 5000 and for CTAB/Si molar ratios of 0.15. The honeycomb structure was also observed by atomic force microscopy and transmission electron microscope. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2542–2550, 2006 相似文献
8.
Weighted Strichartz estimates with homogeneous weights with critical exponents are proved for the wave equation without a support restriction on the forcing term. The method of proof is based on expansion by spherical harmonics and on the Sobolev space over the unit sphere, by which the required estimates are reduced to the radial case. As an application of the weighted Strichartz estimates, the existence and uniqueness of self‐similar solutions to nonlinear wave equations are proved on up to five space dimensions. © 2006 Wiley Periodicals, Inc. 相似文献
9.