全文获取类型
收费全文 | 179篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 160篇 |
力学 | 2篇 |
数学 | 2篇 |
物理学 | 18篇 |
出版年
2012年 | 2篇 |
2011年 | 3篇 |
2008年 | 1篇 |
2007年 | 1篇 |
2005年 | 1篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2002年 | 10篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 14篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 9篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1982年 | 4篇 |
1981年 | 10篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1972年 | 6篇 |
1971年 | 6篇 |
1970年 | 1篇 |
1969年 | 6篇 |
1967年 | 2篇 |
1966年 | 2篇 |
1965年 | 1篇 |
1963年 | 1篇 |
1962年 | 1篇 |
1961年 | 2篇 |
1957年 | 1篇 |
1956年 | 1篇 |
1955年 | 1篇 |
1954年 | 2篇 |
排序方式: 共有182条查询结果,搜索用时 312 毫秒
1.
2.
O. V. Gusev V. V. Krivykh P. V. Petrovskii M. I. Rybinskaya 《Russian Chemical Bulletin》1987,36(7):1532-1534
Conclusions The allyl ligand in neutral molybdenum and cobalt complexes is readily exchanged by dienes in the presence of a strong protic acid with the formation of cationic complexes. This exchange is facilitated by an increase in the basicity of the starting compounds.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1655–1657, July, 1987. 相似文献
3.
4.
A.N. Nesmeyanov V.V. Krivykh P.V. Petrovskii V.S. Kaganovich M.I. Rybinskaya 《Journal of organometallic chemistry》1978,162(3):323-342
Irradiation of alkenylarene tricarbonyl-chromium, -molybdenum, and -tungsten compounds in which the double bond is separated from the arene moiety by a two- or three-atom bridge results in intramolecular cyclization to give stable chelate alkenylarenedicarbonylmetal complexes. Chelate complexes containing four-atom bridges have low stabilities, and those with monoatomic bridges were not formed at all. Irradiation of styrenetricarbonyl-chromium and -molybdenum leads to dinuclear tricarbonylmetal—dicarbonylmetal complexes. The chelate complexes obtained have been studied by IR, proton NMR, and 13C NMR spectroscopy. The electron density distributions and the stereochemistry of the complexes are discussed. With nonsymmetric arenes, diastereoisomers are formed; the predominant isomers have been isolated in the pure form. According to the proton NMR data the double bond in alkenylarenechromium chelates is parallel of nearly parallel to the arene ring plane. 相似文献
5.
V. S. Kaganovich Z. A. Kerzina M. I. Rybinskaya E. Kolehmainen 《Russian Chemical Bulletin》1995,44(6):1131-1132
The reaction of cluster Ru6C(CO)17 (1) with nickelocene is studied. Five CO ligands rather than a metal-ligand crown are substituted for two cyclopentadienyl groups to give a new complex Ru6C(5-Cp)2(CO)12 (2). The reaction of cluster1 with entamethylcyclopentadiene leads to new complex Ru6C(-15-CH2C5Me4)(CO)14 (3) containing the cr-bond CH2-Ru, along with an 5-coordinated cyclopentadienyl ring.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1171–1172, June, 1995. 相似文献
6.
7.
Conclusions An F atom and PhO group on a coordinated P atom in chromium arene phosphite dicarbonyl chelate complexes undergo nucleophilic substitution when treated with PhLi without ring opening to give the corresponding arene diphenylphosphinite chelates.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1900–1902, August, 1981. 相似文献
8.
A. R. Kudinov D. A. Loginov P. V. Petrovskii M. I. Rybinskaya 《Russian Chemical Bulletin》1998,47(8):1583-1584
Thirty-electron triple-decker complexes with a central pentaphospholyl ligand [(η-C5Me5)Fe(μ-η:η-P5)M(η-C5R5)]BF4 (M=Fe, R=Me or M=Ru, R=H, Me) were synthesized by a stacking reaction of cationic 12-electron fragments [(η-C5R5)M]+ with (η-C5Me5)Fe(η-P5).
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1625–1626, August, 1998. 相似文献
9.
A. R. Kudinov L. S. Shul'pina P. V. Petrovskii M. I. Rybinskaya 《Russian Chemical Bulletin》1992,41(3):549-554
Interaction of [Ru(-C
6
H
6
)Cl
2
]
2
with indenyl- or fluorenyllithium in THF gives, together with cationic benzene complexes [Ru(
5
-C
9
H
7
)(-C
6
H
6
)]+ and [Ru(
5
-C
13
H
9
)(-C
6
H
6
)]+, the neutral cyclohexadienyl derivatives Ru(
5
-C
9
H
6
-C
9
H
7
) and Ru(
5
-C
13
H
9
)(
5
-C
6
H
6
-C
13
H
9
), respectively. Interaction of the cyclohexadienyl complexes with Al
2
O
3
, Ph
3
C+, and CF
3
CO
2
H has been studied. Reaction of Ru(
5
-C
13
H
9
)(
5
-C
6
H
7
) with CF
3
CO
2
H in the presence of an arene yields cationic cyclohexadienylarene complexes: [Ru(
5
-C
13
H
9
)(
6
-arene)]+ (arene=C
6
H
6
or 1,3,5-Me
3
C
6
H
3
).A. N. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, 117813 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 699–706, March, 1992. 相似文献
10.
Conclusions A simple method was developed for the synthesis of cyclopentadienyliron aquadicarbonyl tetraphenylborate by oxidizing the dimer of cyclopentadienyliron dicarbonyl with Fe(III) sulfate.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 225–226, January, 1983. 相似文献