Beryllium (boron) clustering quest in relativistic multifragmentation (BECQUEREL Project)

A physical program of irradiation of emulsions in beams of relativistic nuclei named the BECQUEREL Project is reviewed. It is destined to study in detail the processes of relativistic fragmentation of light radioactive and stable nuclei. The expected results would make it possible to answer some topical questions concerning the cluster structure of light nuclei. Owing to the best spatial resolution, the nuclear emulsions would enable one to obtain unique and evident results. The most important irradiations will be performed in the secondary beams of He, Be, B, C, and N radioactive nuclei formed on the basis of JINR Nuclotron beams of stable nuclei. We present results on the charged state topology of relativistic fragmentation of the ¹⁰B nucleus at low energy-momentum transfers as the first step of the research.     

Investigation of clustering in light nuclei by means of relativistic-multifragmentation processes

New results concerning the topology of the fragmentation of relativistic nuclei ⁷Li and ¹⁰B are presented. A program is proposed for studying the cluster structure of stable and radioactive nuclei. The use of emulsions in the investigation of nuclear clustering in the fragmentation of light nuclei at energies are in excess of 1 GeV per nucleon is discussed.     

New pecJ-n (n = 1, 2) Basis Sets for High-Quality Calculations of Indirect Nuclear Spin–Spin Coupling Constants Involving 31P and 29Si: The Advanced PEC Method

In this paper, we presented new J-oriented basis sets, pecJ-n (n = 1, 2), for phosphorus and silicon, purposed for the high-quality correlated calculations of the NMR spin–spin coupling constants involving these nuclei. The pecJ-n basis sets were generated using the modified version of the property-energy consistent (PEC) method, which was introduced in our earlier paper. The modifications applied to the original PEC procedure increased the overall accuracy and robustness of the generated basis sets in relation to the diversity of electronic systems. Our new basis sets were successfully tested on a great number of spin–spin coupling constants, involving phosphorus or/and silicon, calculated within the SOPPA(CCSD) method. In general, it was found that our new pecJ-1 and pecJ-2 basis sets are very efficient, providing the overall accuracy that can be characterized by MAEs of about 3.80 and 1.98 Hz, respectively, against the benchmark data obtained with a large dyall.aae4z⁺ basis set of quadruple-ζ quality.     

Reactions of heteroaromatic chromophores with lanthanide complexes of p-sulfonatothiacalix[4]arene

The conditions for the formation of heteroleptic complexes of a lanthanide(iii) ion (Ln = La, Gd, and Tb) with p-sulfonatothiacalix[4]arene and a heteroaromatic chromophore in water were found using X-ray diffraction analysis, pH-metry, ¹H NMR and UV—Vis spectroscopy, and nuclear magnetic relaxation. In the resulting complexes, the heteroaromatic chromophore is in the calix[4]arene cavity and the lanthanide ion is coordinated by the electron-donating groups of the upper or lower calix[4]arene rim. Emission spectroscopic studies revealed changed emission properties of Tb^III ions in the terbium(iii)—p-sulfonatothiacalix[4]arene—bipy complex. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1871–1878, September, 2008.     

Algebraic-diagrammatic construction polarization propagator approach to indirect nuclear spin-spin coupling constants

A new polarization propagator approach to indirect nuclear spin-spin coupling constantans is formulated within the framework of the algebraic-diagrammatic construction (ADC) approximation and implemented at the level of the strict second-order approximation scheme, ADC(2). The ADC approach possesses transparent computational procedure operating with Hermitian matrix quantities defined with respect to physical excitations. It is size-consistent and easily extendable to higher orders via the hierarchy of available ADC approximation schemes. The ADC(2) method is tested in the first applications to HF, N(2), CO, H(2)O, HCN, NH(3), CH(4), C(2)H(2), PH(3), SiH(4), CH(3)F, and C(2)H(4). The calculated indirect nuclear spin-spin coupling constants are in good agreement with the experimental data and results of the second-order polarization propagator approximation method. The computational effort of the ADC(2) scheme scales as n(5) with respect to the number of molecular orbitals n, which makes this method promising for applications to larger molecules.     

Effect of electron irradiation on the structure and mechanical properties of 36% Ni, 12% Cr, 3% Ti, 1% Al age-hardened austenitic steel subjected to various modes of thermomechanical treatment

The effect of electron irradiation on the structure and mechanical properties of 36% Ni, 12% Cr, 3% Ti, 1% Al age-hardened austenitic steel after different modes of thermomechanical treatment, including quenching, rolling with a 99% degree of compression, and aging, is studied experimentally in the constant current mode with a fluence of 10¹⁹ freq cm^?2. Regularities of the changes in the structural phase composition and mechanical properties of the investigated alloy are established as a result of electron irradiation. Scientifically grounded recommendations are given for selecting modes of thermomechanical treatment, supplemented by irradiation and ensuring the optimum combination of strength and ductility in 36% Ni, 12% Cr, 3% Ti, 1% Al age-hardened austenitic steel.     

New Luminescent Lanthanide Tetrakis-Complexes NEt4[LnL4] Based on Dimethyl-N-Benzoylamidophosphate

New lanthanide dimethyl-N-benzoylamidophosphate (HL) based tetrakis-complexes NEt₄[LnL₄] (Ln³⁺=La, Nd, Sm, Eu, Gd, Tb, Dy) are reported. The complexes are characterized by means of NMR, IR, absorption, and luminescent spectroscopy as well as by elemental, X-Ray, and thermal gravimetric analyses. The phenyl groups of the four ligands of the complex anion are directed towards one side, while the methoxy groups are directed in the opposite side, which makes the complexes under consideration structurally similar to calixarenes. The effect of changing the alkali metal counterion to the organic cation NEt₄⁺ on the structure and properties of the tetrakis-complex [LnL4]^- is analyzed. The complexes exhibit bright characteristic for respective lanthanides luminescence. Rather high intensity of the band of ⁵D₀→⁷F₄ transition, observed in the luminescence spectrum of NEt₄[EuL₄], is discussed based on theoretical calculations.     

Charge topology of the coherent dissociation of relativistic <Superscript>11</Superscript>C and <Superscript>12</Superscript>N nuclei

The charge topology of coherent-dissociation events is presented for ¹¹С and ¹²N nuclei of energy 1.2 GeV per nucleon bombarding nuclear track emulsions. This topology is compared with respective data for ⁷Be, ^8,10B, ^9,10C, and ¹⁴N nuclei.     

Electromagnetic dissociation of relativistic 8B nuclei in nuclear track emulsion

Experimental data on fragmentation channels in peripheral interactions of ⁸B nuclei in nuclear track emulsions are presented. A detailed analysis made it possible to justify selections of events of the electromagnetic-dissociation process ⁸B → ⁷Be + p and to estimate its cross section. Events of ¹⁰C peripheral dissociation that were observed in the same exposure are described.     

Peripheral fragmentation of 8B nuclei in nuclear emulsion at an energy of 1.2 GeV per nucleon

The results obtained by studying the charge topology of fragments produced in the peripheral dissociation of relativistic ⁸B nuclei in emulsion are presented. Fifty-five events of the peripheral dissociation of a ⁸B nucleus in events where there was no production of target-nucleus fragments and mesons (“white stars”) were selected. A leading contribution of the ⁸B → ⁷Be + p mode, which has the lowest energy threshold, was revealed on the basis of these events. Information about the branching ratios for dissociation modes characterized by a higher multiplicity was obtained. The dissociation of the ⁷Be core in ⁸B bears resemblance to the dissociation of a free ⁷Be nucleus. The transverse-momentum distributions of fragments originating from the ⁸B → ⁷Be + p dissociation mode were obtained. For these distributions, a small mean value of 〈P*_T〉 = 52 ± 5 MeV/c in the c.m. frame suggests a low binding energy of the outer proton in the ⁸B nucleus. An indication of a strong azimuthal correlation of the fragments ⁷Be and p was found.