排序方式: 共有45条查询结果,搜索用时 31 毫秒
1.
Soumen Ghosh Rupa Mukhopadhyay Madeleine Helliwell Alok K. Mukherjee 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(8):o496-o500
The pyrazine ring in two N‐substituted quinoxaline derivatives, namely (E)‐2‐(2‐methoxybenzylidene)‐1,4‐di‐p‐tosyl‐1,2,3,4‐tetrahydroquinoxaline, C30H28N2S2O5, (II), and (E)‐methyl 2‐[(1,4‐di‐p‐tosyl‐1,2,3,4‐tetrahydroquinoxalin‐2‐ylidene)methyl]benzoate, C31H28N2S2O6, (III), assumes a half‐chair conformation and is shielded by the terminal tosyl groups. In the molecular packing of the compounds, intermolecular C—H...O hydrogen bonds between centrosymmetrically related molecules generate dimeric rings, viz. R22(22) in (II) and R22(26) in (III), which are further connected through C—H...π(arene) hydrogen bonds and π–π stacking interactions into novel supramolecular frameworks. 相似文献
2.
Bin Liu Rupa S. ShettyKristofer K. Moffett Martha J. Kelly 《Tetrahedron letters》2011,52(14):1680-1684
An efficient synthesis of 1,3,5-trisubstituted benzenes via a sequential Pd-mediated carbon-sulfur, carbon-nitrogen, and carbon-carbon bond formation reactions is reported. Selective amidation and sulfonamidation reactions are accomplished via Pd-catalyzed reactions between aryl chlorides and an acetamide or a methanesulfonamide. 相似文献
3.
We prove a uniqueness theorem for two non-constant meromorphic functions sharing three values which improves a recent result of T.C. Alzahary. As a consequence of our main result we also improve a theorem of G. Brosch. 相似文献
4.
Prashant Dubey Devarajan Muthukumaran Subhashis Dash Rupa Mukhopadhyay Sabyasachi Sarkar 《Pramana》2005,65(4):681-697
Carbon nanotubes (CNT) has been synthesized by pyrolysing mustard oil using an oil lamp. It was made water-soluble (wsCNT)
through oxidative treatment by dilute nitric acid and was characterized by SEM, AFM, XRD, Raman and FTIR spectroscopy. The
synthesized wsCNT showed the presence of several junctions and defects in it. The presence of curved graphene structure (sp2) with frequent sp3 hybridized carbon is found to be responsible for the observed defects. These defects along with the presence of di- and tri-podal
junctions showed interesting magnetic properties of carbon radicals formed by spin frustration. This trapped carbon radical
showed ESR signal in aqueous solution and was very stable even under drastic treatment by strong oxidizing or reducing agents.
Oxidative acid treatment of CNT introduced several carboxylic acid group functionalities in wsCNT along with the nicking of
the CNT at different lengths with varied molecular weight. To evaluate molecular weights of these wsCNTs, an innovative method
like gel electrophoresis using high molecular weight DNA as marker was introduced. 相似文献
5.
A regioselective synthesis of 2,4,6-trisubstituted pyridine is described starting from 2,6-dibromo-4-nitropyridine. All three different regioisomers of the 2,4,6-triamino substituted pyridine have been synthesized in four to five steps. The method described is a general route to unsymmetrical 2,4,6-trisubstituted amino pyridines. 相似文献
6.
Dipak Ghosh Argha Deb Swarnapratim Bhattacharyya Jayita Ghosh Rupa Das 《Acta Physica Hungarica A》2003,17(1):161-166
This paper reports an investigation on the two-particle long-range angular correlation among the target fragments produced in 28Si–AgBr interactions at 14.5 AGeV, 16O–AgBr interactions at 60 AGeV and 32S–AgBr interactions at 200 AGeV. The experimental data have been compared with Monte Carlo simulated events to extract dynamical correlation. The data exhibit two-particle long-range correlation in emission angle space at all energies. 相似文献
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8.
We predict the transverse momentum (p(T)) dependence of elliptic flow of thermal photons for Au + Au collisions at the BNL Relativistic Heavy Ion Collider. We model the system hydrodynamically, with a thermalized quark-gluon plasma at early times followed by hadronization and decoupling. Photons are emitted throughout the expansion history. Contrary to hadron elliptic flow, which increases monotonically with p(T), the elliptic flow nu2(p(T)) of thermal photons is predicted to first rise and then fall again. Photon elliptic flow at high p(T) reflects the quark momentum anisotropy at early times when it is small, while at low p(T) it mirrors the large pion momentum anisotropy during the late hadronic emission stage. An interesting structure is predicted at intermediate p(T) approximately 0.4 GeV/c, where photon elliptic flow reflects the momenta and the (compared to pions) reduced nu2 of heavy vector mesons in the late hadronic phase. 相似文献
9.
We report the use of solution-processed thin-film organic photodiodes for microscale chemiluminescence. The active layer of the photodiodes comprised a 1 : 1 blend by weight of the conjugated polymer poly(3-hexylthiophene) [P3HT] and [6,6]-phenyl-C(61)-butyric acid-methylester [PCBM]--a soluble derivative of C(60). The devices had an active area of 1 mm x 1 mm, and a broad-band response from 350 to 700 nm, with an external quantum efficiency of more than 50% between 450 and 550 nm. The photodiodes have a simple layered structure that permits facile integration with planar chip-based systems. To evaluate the suitability of the organic devices as integrated detectors for microscale chemiluminescence, a peroxyoxalate based chemiluminescence reaction (PO-CL) was monitored within a poly(dimethyl-siloxane) (PDMS) microfluidic device. Quantitation of hydrogen peroxide indicated excellent linearity and yielded a detection limit of 10 microM, comparable with previously reported results using micromachined silicon microfluidic chips with integrated silicon photodiodes. The combination of organic photodiodes with PDMS microfluidic chips offers a means of creating compact, sensitive and potentially low-cost microscale CL devices with wide-ranging applications in chemical and biological analysis and clinical diagnostics. 相似文献
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