Reaction of iminoxyl radicals with triphenylmethylcarbonium salts

Russian Chemical Bulletin -     

Free azoxy radicals from benzoquinolines

Conclusions The 5,6- and 7,8-benzo derivatives of 4-methyl-2-spirocyclohexyl-3,4 3,2-tetrahydrofurano-1,2,3,4-tetrahydroquinoline and their paramagnetic N-oxides were synthesized. A study was made of the paramagnetic absorption spectra of the free radicals, which are bezoquinoline derivatives.     

The magnetic spin-reorientation transitions in the RGa (R=rare earth) intermetallic compounds studied by measurements of the hyperfine interactions of the Sn probe atoms

The magnetic and electric hyperfine interactions of the probe nucleus ¹¹⁹Sn on the Ga site of the ferromagnetic rare-earth (R) gallium compounds RGa (R=Pr–Er) have been investigated by Mössbauer spectroscopy technique. For all of the compounds, the directions of the magnetic moments of the R³⁺ ions have been determined as a function of temperature in the range from 5 K to T_C. For NdGa, SmGa, HoGa, and ErGa compounds, the magnetic reorientation transitions due to the competition between the exchange interaction and the interaction with crystal field have been investigated. At high temperatures, when the electric interaction dominates, the orientation of the magnetic moments is unambiguously determined by the sign of the quadrupole moment of 4f shell of the R³⁺ ion. With decreasing temperature, the magnetic moments rotate gradually from the bc-plane toward the crystallographic a-axis. In the temperature range 5 K?T<100 K, the ferromagnetic structure of the GdGa compound is noncollinear. At 5 K the magnetic moments of the Gd³⁺ ions point in two distinct directions with respect to the crystallographic a  -axis (_θ1≈30°${\theta }_1\approx 30°$ and _θ2≈60°${\theta }_2\approx 60°$).     

New spin labels and probes for biological studies

Conclusions A series of new and highly stable iminoxyl mono- and biradicals was obtained.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1327–1329, June, 1973.