Study of the reactione + e −→K + K − in the energy range1350 \leqq \sqrt s \leqq 2400 MeV

Thee ⁺ e ^?→K ⁺ K ^? cross section has been measured from about 750 events in the energy interval \(1350 \leqq \sqrt s \leqq 2400 MeV\) with the DM2 detector at DCI. TheK ^± form factor |F _F ^±| cannot be explained by the ρ, ω, ? and ρ′(1600). An additional resonant amplitude at 1650 MeV has to be added as suggested by a previous experiment.     

Rollover‐Assisted C(sp2)C(sp3) Bond Formation

Rollover cyclometalation involves bidentate heterocyclic donors, unusually acting as cyclometalated ligands. The resulting products, possessing a free donor atom, react differently from the classical cyclometalated complexes. Taking advantage of a “rollover”/“retro‐rollover” reaction sequence, a succession of oxidative addition and reductive elimination in a series of platinum(II) complexes [Pt(N,C)(Me)(PR₃)] resulted in a rare C(sp²)?C(sp³) bond formation to give the bidentate nitrogen ligands 3‐methyl‐2,2′‐bipyridine, 3,6‐dimethyl‐2,2′‐bipyridine, and 3‐methyl‐2‐(2′‐pyridyl)‐quinoline, which were isolated and characterized. The nature of the phosphane PR₃ is essential to the outcome of the reaction. This route constitutes a new method for the activation and functionalization of C?H bond in the C(3) position of bidentate heterocyclic compounds, a position usually difficult to functionalize.     

Sulfur‐Functionalized Graphene Oxide by Epoxide Ring‐Opening

The treatment of graphene oxide (GO) with potassium thioacetate followed by an aqueous work‐up yields a new material via the ring‐opening of the epoxide groups. The new material is a thiol‐functionalized GO (GO‐SH) which is able to undergo further functionalization. Reaction with butyl bromide gives another new material, GO‐SBu, which shows significantly enhanced thermal stability compared to both GO and GO‐SH. The thiol‐functionalized GO material showed a high affinity for gold, as demonstrated by the selective deposition of a high density of gold nanoparticles.     

Specific interaction of desthiobiotin lipids and water-soluble biotin compounds with streptavidin

As shown for biotin lipids (Ref. 1), the formation of perfect 2-D crystalline streptavidin domains can also be observed in the plane of desthiobiotin lipid monolayers. The binding constant of streptavidin with desthiobiotin (K_a = 5·10¹³ mol⁻¹) is lower than that with biotin (K_a = 10¹⁵ mol⁻¹) (Ref. 2). By adding free biotin into the subphase a competitive replacement and a detaching of the streptavidin domains from the desthiobiotin lipid monolayer takes place. Streptavidin domains built at receptor lipid monolayers are still functional. As could be shown, there are two biotin binding sites at each protein molecule that are fully accessible to biotin (Ref. 1). This can be proven by the interaction with biotinylated ferritin and fluoresceinated biotin. Further coupling of an anti-FITC-antibody can proceed and a second protein layer can be formed. Using a bifunctional biotin linker a second crystalline streptavidin layer underneath the first one can be obtained.     

Spectroscopic evidence for multiple order parameter components in the heavy fermion superconductor CeCoIn5

Point-contact spectroscopy was performed on single crystals of the heavy-fermion superconductor CeCoIn(5) between 150 mK and 2.5 K. A pulsed measurement technique ensured minimal Joule heating over a wide voltage range. The spectra show Andreev-reflection characteristics with multiple structures which depend on junction impedance. Spectral analysis using the generalized Blonder-Tinkham-Klapwijk formalism for d-wave pairing revealed two coexisting order parameter components with amplitudes Delta(1) = 0.95 +/- 0.15 meV and Delta(2) = 2.4 +/- 0.3 meV, which evolve differently with temperature. Our observations indicate a highly unconventional pairing mechanism, possibly involving multiple bands.     

Two-level systems with relaxation

A method is presented for the coherent control of two-level systems when T2 relaxation is significant. The Bloch equations are rewritten as an equation of motion of the stereographic projection, Gamma, of the spin vector. This allows a Schur-type iteration used for the design of shaped pulses in magnetic resonance and coherent optics to be extended to include the effect of T2. In general, the effect of T2 on Gamma cannot be completely compensated for, although in practice it can be to a high degree. An example is presented of a driving field that produces a coherent superposition (no on-diagonal elements of the density matrix) over a chosen band of frequencies, in the presence of relaxation.     

Exact linearization of the radiation-damped spin system

Nonlinear evolution of the Landau-Lifshitz type can be exactly linearized. Special cases include the radiation-damped spin system and the superradiant system in the semiclassical regime, in the presence of time-varying driving fields. For these, the resultant linear system is simply that of a spin 1 / 2 particle, with the radiation damping rate, or superradiant characteristic time, manifested as an imaginary addition to the spin's resonance frequency. Consequently, methods from inverse scattering theory can be used to design driving fields. The behavior of these systems under stochastic excitation can be determined exactly.     

Radiative decay ofJ/ψ into γ π+ π−

The radiative decayJ/ψ → γ π⁺ π^? has been studied using the 8.6 millionJ/ψ produced in the DM2 experiment at the DCIe ⁺e^? storage rings at Orsay. The π⁺ π^? mass spectrum shows a cleanf ₂ (1270) signal, and the possible presence of two other states at thef ₂ (1720) andf ₄ (2030) masses. For thef ₂ (1270), the branching ratio BR(J/ψ →γf)xBR(f→π⁺ π^?) is measured to be (7.50±0.30±1.12)×10^?4, and the spin analysis prefers theJ=2 assignment, with helicity parametersx=0.83±0.06 andy=0.01±0.06. The existence of higher mass states is discussed.     

GaN nanowire functionalized with atomic layer deposition techniques for enhanced immobilization of biomolecules

We report the use of atomic layer deposition (ALD) coating as a nanobiosensor functionalization strategy for enhanced surface immobilization that may enable higher detection sensitivity. Three kinds of ALD coating films, Al(2)O(3), TiO(2), and SiO(2), were grown on the gallium nitride nanowire (GaN NW) surfaces and characterized with high-resolution transmission electron microscopy (HRTEM) and vacuum Fourier transform infrared spectroscopy (FTIR). Results from HRTEM showed that the thicknesses of ALD-Al(2)O(3), ALD-TiO(2) and ALD-SiO(2) coatings were 4-5 nm, 5-6 nm, and 12-14 nm, respectively. Results from FTIR showed that the OH contents of these coatings were, respectively, ～6.9, ～7.4, and ～9.3 times that of piranha-treated GaN NW. Furthermore, to compare protein attachments on the different surfaces, poly(ethylene glycol) (PEG)-biotin was grafted on the OH-functionalized GaN NW surfaces through active Si-Cl functional groups. Streptavidin protein molecules were then attached to the biotin ends via specific binding. The immobilized streptavidin molecules were examined with scanning electron microscopy, HRTEM, and fluorescent imaging. Results from HRTEM and energy-dispersive X-ray revealed that the nitrogen concentrations on the three ALD coatings were significantly higher than that on the piranha-treated surface. Results from fluorescent imaging further showed that the protein attachments on the Al(2)O(3), TiO(2), and SiO(2) ALD coatings were, respectively, 6.4, 7.8, and 9.8 times that of piranha-treated surface. This study demonstrates that ALD coating can be used as a functionalization strategy for nanobiosensors because it is capable of creating functional groups with much higher density compared to widely used acid modifications, and among the three ALD coatings, ALD-SiO(2) yielded the most promising results in OH content and protein attachment.