全文获取类型
收费全文 | 301篇 |
免费 | 8篇 |
专业分类
化学 | 269篇 |
晶体学 | 2篇 |
力学 | 1篇 |
数学 | 7篇 |
物理学 | 30篇 |
出版年
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 3篇 |
2016年 | 6篇 |
2015年 | 8篇 |
2014年 | 6篇 |
2013年 | 14篇 |
2012年 | 6篇 |
2011年 | 15篇 |
2010年 | 6篇 |
2009年 | 12篇 |
2008年 | 19篇 |
2007年 | 13篇 |
2006年 | 14篇 |
2005年 | 16篇 |
2004年 | 16篇 |
2003年 | 17篇 |
2002年 | 4篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 6篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 13篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1976年 | 1篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1972年 | 1篇 |
1971年 | 3篇 |
1970年 | 1篇 |
1962年 | 1篇 |
1961年 | 3篇 |
1960年 | 3篇 |
排序方式: 共有309条查询结果,搜索用时 15 毫秒
1.
2.
Tadeusz Balaban Michael O'Carroll Ricardo Schor 《Communications in Mathematical Physics》1989,122(2):233-247
Block renormalization group transformations (RGT) for lattice and continuum Euclidean Fermions in d dimensions are developed using Fermionic integrals with exponential and -function weight functions. For the free field the sequence of actionsD
k
generated by the RGT from D, the Dirac operator, are shown to have exponential decay; uniform ink, after rescaling to the unit lattice. It is shown that the two-point functionD
–1 admits a simple telescopic sum decomposition into fluctuation two-point functions which for the exponential weight RGT have exponential decay. Contrary to RG intuition the sequence of rescaled actions corresponding to the -function RGT do not have uniform exponential decay and we give examples of initial actions in one dimension where this phenomena occurs for the exponenential weight RGT also. 相似文献
3.
Ovanes Mekenyan Danail Bonchev Alexandru Balaban 《Journal of mathematical chemistry》1988,2(4):347-375
Whereas the internal fragment topological index (IFTI) is calculated in the normal manner as for any molecule, the external fragment topological index (EFTI) is calculated so as to reflect the interaction between the excised fragment F and the remainder of the molecule (G-F). For selected topological indices (TIs), a survey of EFTI values, formulas and examples is presented. Some requirements as to the fragment indices are formulated and examined. In the discussion of the results, it is shown that for some TIs regularities exist in the dependence of EFTI values upon the branching of fragment F, or upon the marginal versus central position of the fragment F in the graph G. New vortex invariants can be computed as EFTI values for one-atom fragments over all graph vertices; by iteration, it is in principle possible to devise an infinite number of now vertex invariants. 相似文献
4.
The influence of ionic strength on the complexes formed by natural bovine serum albumin (BSA), pH 5.4 (near the isoelectric point), and sodium dodecyl sulfate (SDS) in aqueous buffered (sodium acetate) solution was investigated by using surface tension, fluorescence and small angle X-ray scattering (SAXS) techniques. Ionic strength was varied by changing sodium acetate buffer concentration from 0.020 to 0.5 M. Surface tension revealed that SDS:BSA saturation binding occurs at psp = 42 +/- 2 mM, independent of the solution ionic strength. Further, SAXS curves are consistent with the necklace and bead model, where micelle-like aggregates are randomly distributed along the partial unfolded protein. Micelle-like aggregates grow from small spheres at 10 mM SDS to small ellipsoids (upsilon = 1.3 , ratio between the largest and the shortest axes) near psp, in good agreement with micellar aggregation numbers obtained by fluorescence, independent of salt concentration. Protein-bound micelles stop growing above psp and further SDS addition induces free-micelle formation. 相似文献
5.
Whereas the theory for the enumeration of the optical isomers of the lakyl radicals and the alkanes has long been understood, this is not the case for the corresponding archiral isomers. We present for the first time recurrence formulae for counting the number of archiral isomers of the alkyl radicals and the alkanes. For chiral and archiral alkanes and monosubstituted alkanes, numerical results up to C14 are tabulated.After presenting the history of the problem and the necessary definitions, we proceed to derive functional equations on the various generating functions, which readily yield the more explicit recurrence formulae usefule for numerical calculations. In the process, we first re-derive Pólya's expression for planted steric trees using his classical enumeration theorem. This result is then extended to the enumeration of free steric trees using the now standard tree-counting method due to Otter and known as a dissimilarity characteristic equation.By definition, a steric tree is a quartic tree (all points having degree 1 or 4) in which the four neighbors of every carbon point are given a tetrahedral configuration. Building on the methods of the first two authors for counting chiral and archiral trees in the plane, we obtain the formula for counting achiral steric trees, thus setting a problem first enunciated by van't Hoff and Le Bel in 1874. 相似文献
6.
A. T. Balaban I. Zugrâvescu S. Avramovici W. Silhan 《Monatshefte für Chemie / Chemical Monthly》1970,101(3):704-708
Zusammenfassung Frühere Strukturvorschläge für dastrans-Chalcon-oxim, semicarbazon und thiosemicarbazon1 werden mit Hilfe von NMR-Spektren richtiggestellt: Die sauer katalysierte Reaktion führt zwar zum Oxim, Semicarbazon und Thiosemicarbazon destrans-Chalcons; basische Katalysatoren bewirken dagegen eine interne Cyclisierung zu 3,5-Diphenyl-2-isoxazolin bzw. zu 1-substituierten 3,5-Diphenyl-2-pyrazolinen. Die Zuordnungen in den NMR-Spektren wurden durch Vergleich mittrans-Dypnon und seinem Semicarbazon getroffen.
NMR spectra of trans-chalcone oxime, semicarbazone and thiosemicarbazone and their cyclic isomers (3,5-diphenyl-2-isoxazoline and 1-substituted 3,5-diphenyl-2-pyrazolines)
Earlier tentatively assigned structures fortrans-chalcone oxime, semicarbazone and thiosemicarbazone, resp., have been corrected by means of NMR spectra: open-chain structures have been found for the title compounds formed in the acid catalyzed reaction, whereas basic catalysts lead to intramolecular cyclization with formation of 3,5-diphenyl-2-isoxazoline and 1-substituted 3,5-diphenyl-2-pyrazolines resp. Assignments in the NMR spectra were made by comparison with those from authentic samples oftrans-dypnone and its semicarbazone.相似文献
7.
Alexandry T. Balaban Danail Bonchev William A. Scitz 《Journal of Molecular Structure》1993,280(2-3):253-260
A set of priority rules is defined for obtaining the graph center in multigraphs, i.e. in molecular graphs with multiple bonds. In order to obtain closer agreement between experimental bond distances in molecules and the relative magnitudes of entries in the distance matrix, a new type of distance is defined, called the “chemical distance”: CD = bt-14, where b is the conventional bond multiplicity. 相似文献
8.
Cornelia Uncuta Teodor-Silviu Balaban Mircea D. Gheorghiu Ligia Stănescu Aurica Petride Alexandru T. Balaban 《Tetrahedron letters》1985,26(38):4673-4676
Two Isomeric pyridines were designed and prepared : 2-isopropyl-4,5,6-trimethyl-(3) and 2-isopropyl-3,4,6-trimethyl-pyridine (7); the latter, with a buttressed isopropyl, leads to much lower induced shifts by Eu(dpm)3 and Pr(dpm)3 than the former, owing to the conformation in which the Janus-type iPr group how to the LSR a t-butyl-like face. 相似文献
9.
Francesco Dallavalle Emilia Fisicaro Roberto Corradini Rosangela Marchelli 《Helvetica chimica acta》1989,72(7):1479-1486
Protonation and Cu(II) complexation equilibria of L -phenyhilaninamide, N2-methyl-L-phenylalaninamide, N2, N2-dimethyl-L-phenylalaninamide, L -valinamide, and L -prolinamide have been studied by potentiometry in aqueous solution. The formation constants of the species observed, CuL2+, CuL, CuLH, CuL2H and CuL2H?2, are discussed in relation to the structures of the ligands. Possible structures of bisamidato complexes are proposed on the ground of VIS and CD spectra. Since Cu(II) complexes of the present ligands (pH range 6–8) perform chiral resolution of dansyl- and unmodified amino acids in HPLC (reversed phase), it is relevant for the investigation of the resolution mechanism to know which are the species potentially involved in the recognition process. 相似文献
10.
It is shown that in several cases where planar delocalisation in organic cations would result in the formation of an anti-aromatic system, polyhedral delocalisation is the form of bonding actually preferred. This explains, for instance, why organic cations in such cases adopt cage-like structures. A full graph-theoretical analysis, similar to one previously published12 for polyhedral boranes, carboranes and metal clusters, indicates that the nido structure for (CH)5+ may readily be accounted for. Moreover, in the case of the dication (CH)62+ the fact that its energy minimum also corresponds to a nido structure is explained. In fact, no closo- or arachno-type structures appear to be possible for organic cations. A number of structural predictions concerning these species are given in the conclusion. 相似文献