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1.
Michael R. Caputo 《Natural Resource Modeling》1989,3(2):241-259
This paper analyzes the extent to which standard dynamic renewable resource models possess refutable implications. Both the steady state comparative static and local comparative dynamic properties of the standard model are studied. A unified framework is developed which enables one to analyze the qualitative properties of any standard renewable resource model. This is achieved by explicitly linking the local stability, steady state comparative static, and local comparative dynamic properties of the model. 相似文献
2.
The influence of steric factors on the autoxidation of aldehydes having tertiary formyl groups has been investigated. These afford nor-derivatives by loss of carbon monoxide, and carboxylic acids. Steric interactions have been shown to affect strongly the ratio between carboxylic acid and nor-derivatives and, in addition, to increase the autoxidation rate. For the first time, formation of formates from aldehydes by autoxidation conditions, has been demonstrated. 相似文献
3.
The synthesis of marrubiin has been achieved starting from the keto lactone (II) which was prepared stereoselectively from the known keto ester (XI). 相似文献
4.
The fourth-rank hypermagnetizability tensor of the benzene molecule has been evaluated at the coupled Hartree-Fock level of accuracy within the conventional common-origin approach, adopting gaugeless basis sets of increasing size and flexibility. The degree of convergence of theoretical tensor components has been estimated allowing for two different coordinate systems. It is shown that a strong magnetic field perpendicular to the plane of the molecule causes a distortion of the electron charge density, which tends to concentrate in the region of the C-C bonds. This charge contraction has a dynamical origin, and can be interpreted as a feedback effect in terms of the classical Lorentz force acting on the electron current density. 相似文献
5.
The interaction Hamiltonian within the Bloch gauge for the potentials of the electromagnetic field has been used to define magnetic multipole moment operators and operators for the magnetic field of electrons acting on the nuclei of a molecule in the presence of nonhomogeneous external magnetic field. Perturbation theory has been applied to evaluate the induced electronic moments and magnetic field at the nuclei. Multipole magnetic susceptibility and nuclear magnetic shielding tensors have been introduced to describe the contributions arising in nonuniform fields, and their origin dependence has been analyzed. Extended numerical tests on the ammonia molecule in a static, nonuniform magnetic field have been carried out, using the random-phase approximation within the framework of accurate Hartree-Fock zero-order wavefunctions, and allowing for both angular momentum and torque formalisms in the calculation of paramagnetic contributions. 相似文献
6.
Romualdo Caputo Marina Della Greca Luigi Longobardo Gabriella Pinto 《Tetrahedron letters》2007,48(8):1425-1427
The general synthesis of a new class of non-natural diamino acids, 2-amino-3-[(2′-aminoalkyl)seleno]propanoic acids, or Se-(aminoalkyl)selenocysteines, is reported. Under the conditions devised, enantiopure N-Boc-protected β-l-iodoamines, which are readily generated from proteinogenic α-amino acids, were treated with the selenolate anion obtained from NaBH4 splitting of the Se-Se bond in commercial l-selenocystine. The Se-alkylation products were enantiomerically pure and the reaction is high yielding (92-98%), without any detectable traces of accompanying by-products. 相似文献
7.
The carbon footprint reduction mandate and other eco-friendly policies currently in place are constantly driving the trend of the synthesis and application of sustainable functional materials. The bitumen industry is not an exception to this trend and, every day, new technologies that facilitate safer, cost effective and more sustainable industrial processes and road paving operations are being researched and brought to light. A lot of research is currently ongoing to improve bitumen’s properties due to its use as a binder in road paving processes. Over the years, the most common method to improve bitumen’s properties has been with the use of additives. The major drawback in the use of these additives is the fact that they are substances of strong chemical nature which are either too acidic, too basic or emit toxic fumes and volatile organic compounds into the environment. In the long run, these chemicals are also toxic to the road pavement personnel that carry out the day to day industrial and paving operations. This led researchers to the initiative of synthesizing and applying biomaterials to be used as additives for bitumen. In this light, several studies have investigated the use of substances such as bio-oils, natural waxes, gum, polysaccharides and natural rubber. This literature review is aimed at classifying the different bio-based materials used to improve bitumen’s properties and to provide a deeper knowledge of the application of these biomaterials in bitumen technology. In general, we highlight how the research efforts elaborated herein could potentially foster safer, sustainable, eco-friendly approaches to improving bitumen’s properties while also promoting a circular economy. 相似文献
8.
In studying the factors which contribute to the Lewis acidity of organoboron compounds we investigated approaches to the design of robust, novel Lewis acids purposed for metal-free catalysis. Based on a sterically encumbered catechol motif, a series of boronate esters are shown to demonstrate modest Lewis acidities for the conventional Gutmann-Beckett test as an inquisitive investigation. 相似文献
9.
10.
(2Z,1S)-1,3-diphenyl-2-propenol (3) is obtained from the chiral 5,6-dihydro-1,4-dithiin 1b in two steps and 60% enantiomeric excess. Combining our previously reported stereoselective double bond formation and this 1,4 asymmetric induction introduces a new route to chiral allylic alcohols with cis geometry from simple aldehydes and methyl ketones. 相似文献