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排序方式: 共有59条查询结果,搜索用时 15 毫秒
1.
S. V. Basenko I. A. Gebel M. G. Voronkov L. V. Klyba R. G. Mirskov 《Russian Chemical Bulletin》1998,47(8):1571-1573
Methyl(vinyl)dichlorosilane reacts with DMSO in the presence of hexamethyldisiloxane to give the corresponding linear oligosiloxanes
of the general formula Me3Si(OSiMeVin)
n
OSiMe3 (n=1–6) as well as MeSi(OSiMe3)3 and Me3Si(MeOSiVin)
m
OSi(OSiMe3)(Me)OSiMe3 (m=1–2). The same reaction in the presence of chlorotrimethylsilane results in oligomers of the general formula Me3Si(OSiMeVin)
n
Cl (n=1–3). A possible scheme of their formation is discussed.
Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 8, pp. 1614–1616, August, 1998. 相似文献
2.
Excitation functions of the analyzing power in elastic proton-proton scattering from 0.45 to 2.5 GeV
M. Altmeier F. Bauer J. Bisplinghoff K. Büßer M. Busch T. Colberg L. Demirörs H. P. Engelhardt P. D. Eversheim K. O. Eyser O. Felden R. Gebel M. Glende J. Greiff F. Hinterberger E. Jonas H. Krause T. Lindemann J. Lindlein B. Lorentz R. Maier R. Maschuw A. Meinerzhagen D. Prasuhn H. Rohdjeß D. Rosendaal P. von Rossen N. Schirm V. Schwarz W. Scobel H. -J. Trelle K. Ulbrich E. Weise A. Wellinghausen R. Ziegler 《The European Physical Journal A - Hadrons and Nuclei》2005,23(2):351-364
Excitation functions AN(plab,c.m.) of the analyzing power in elastic proton-proton scattering have been measured in an internal target experiment at the Cooler Synchrotron COSY with an unpolarized proton beam and a polarized atomic hydrogen target. Data were taken continuously during the acceleration and deceleration for proton kinetic energies Tlab (momenta plab) between 0.45 and 2.5 GeV (1.0 and 3.3 GeV/c) and scattering angles 30 ° c.m. 90°. The results provide excitation functions and angular distributions of high precision and internal consistency. The data can be used as calibration standard between 0.45 and 2.5 GeV. They have significant impact on phase shift solutions, in particular on the spin triplet phase shifts between 1.0 and 1.8 GeV. 相似文献
3.
Konrad Güth Julia Lyubina Bernhard Gebel Ludwig Schultz Oliver Gutfleisch 《Journal of magnetism and magnetic materials》2012
This paper reports on the grain refinement in dynamic hydrogenation disproportionation desorption and recombination (d-HDDR) processed Nd-rich Nd2Fe14B and stoichiometric Nd2Fe14B powders using high pressure reactive milling (HPRM) followed by a subsequent desorption and recombination. In contrast to the dynamic-HDDR processed anisotropic powder with a grain size of the Nd2Fe14B phase of 300 nm, the new approach yields a further reduction of the Nd2Fe14B1 grain size to less than 70 nm. Nd-rich Nd2Fe14B powder produced by HPRM and subsequent desorption exhibits a coercivity μ0iHc=1.35 T and a remanence of 0.80 T. In the stoichiometric material, the reduction of the Nd-content leads to an increase in remanence to 0.85 T. Additionally, it is demonstrated that highly anisotropic powders can also be obtained by dynamic-HDDR processing of stoichiometric Nd2Fe14B powders. 相似文献
4.
Dr. Valentin Radtke Niklas Gebel Denis Priester Andreas Ermantraut Monika Bäuerle Dr. Daniel Himmel Regina Stroh Prof. Thorsten Koslowski Prof. Ivo Leito Prof. Ingo Krossing 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(40):e202200509
Utilizing the “ideal” ionic liquid salt bridge to measure Gibbs energies of transfer of silver ions between the solvents water, acetonitrile, propylene carbonate and dimethylformamide results in a consistent data set with a precision of 0.6 kJ mol−1 over 87 measurements in 10 half-cells. This forms the basis for a coherent experimental thermodynamic framework of ion solvation chemistry. In addition, we define the solvent independent - and the values that account for the electronating potential of any redox system similar to the value of a medium that accounts for its protonating potential. This scale is thermodynamically well-defined enabling a straightforward comparison of the redox potentials (reducities) of all media with respect to the aqueous redox potential scale, hence unifying all conventional solvents′ redox potential scales. Thus, using the Gibbs energy of transfer of the silver ion published herein, one can convert and unify all hitherto published redox potentials measured, for example, against ferrocene, to the scale. 相似文献
5.
6.
Summary This paper concerns the study of a diffusion layer of macromolecular solutions annularly injected in a cylindric pipe in turbulent flow. The study includes firstly the analysis of the longitudinal and transversal projections of the concentration gradient, secondly the study of the state of turbulence in the diffusion layer.The concentrations are determined by the measurement of the concentration salt (salt was added to the injected solution). A mathematical model of the development of concentration is proposed.The turbulent state of diffusion layer has been studied with Laser-Doppler-Anemometry. An analysis of Eulerian autocorrelation and the power spectral density has been done.
Nomenclature c polymer concentration (wppm) - c 0 wall value ofc - c i value ofc at the slot - D diameter of the pipe - e slot thickness - L 0 distance from the slot at which the wall concentration drops toe –1of its original value - m distance in meter from the slot - U means freestream velocity - u i injection velocity - x distance from the slot - y normal distance from the surface - boundary layer thickness - characteristic height of the diffusion, i. e. the value ofy at whichc/c 0 = 0.5 With 4 figures 相似文献
Zusammenfassung Es werden Ergebnisse über die turbulente Diffusionsschicht von nicht-newtonschen Flüssigkeiten (PÄO) mitgeteilt, die an der Wand eines kreiszylindrischen Rohrs injiziert werden. Diese Untersuchungen betreffen die Analyse der Längs- und Querkomponenten des Konzentrationsgradienten in der Diffusionsschicht und im Turbulenzfeld.Die Konzentrationen werden mit Hilfe von Salz (NaCl) gemessen, das der injizierten Polymerlösung beigefügt worden ist. Ein mathematisches Modell für die Konzentrationsverteilung wird vorgeschlagen.Der Turbulenzzustand der Diffusionsschicht wird mit Hilfe der Laser-Doppler-Anemometrie untersucht. Die Eulersche Autokorrelation und das Intensitätsspektrum werden analysiert.
Nomenclature c polymer concentration (wppm) - c 0 wall value ofc - c i value ofc at the slot - D diameter of the pipe - e slot thickness - L 0 distance from the slot at which the wall concentration drops toe –1of its original value - m distance in meter from the slot - U means freestream velocity - u i injection velocity - x distance from the slot - y normal distance from the surface - boundary layer thickness - characteristic height of the diffusion, i. e. the value ofy at whichc/c 0 = 0.5 With 4 figures 相似文献
7.
Yaschenko S Dymov S Kacharava A Komarov V Macharashvili G Rathmann F Barsov S Gebel R Hartmann M Khoukaz A Kulessa P Kulikov A Kurbatov V Lang N Lehmann I Lorentz B Mersmann T Merzliakov S Mikirtytchiants S Mussgiller A Nioradze M Ohm H Prasuhn D Schleichert R Seyfarth H Steffens E Stein HJ Ströher H Uzikov Y Zalikhanov B Zhuravlev N 《Physical review letters》2005,94(7):072304
A measurement of the analyzing power A(y) of the p-->d--> (p p) + n reaction was carried out at the ANKE spectrometer at COSY at beam energies of 0.5 and 0.8 GeV by detection of a fast forward proton pair of small excitation energy E(pp) < 3 MeV. The S-wave dominance in the fast diproton is experimentally demonstrated in this reaction. While at T(p) = 0.8 GeV the measured analyzing power almost vanishes, it rises to nearly unity at T(p) = 0.5 GeV for neutrons emitted at theta(c.m.)(n) = 167 degrees. The results are compared with a model taking into account one-nucleon exchange, single scattering, and Delta(1232) excitation in the intermediate state. The model describes fairly well the unpolarized cross section obtained earlier and the analyzing power at 0.8 GeV; it fails to reproduce A(y) at 0.5 GeV. 相似文献
8.
Sandra Ristori Grard Gebel Giacomo Martini 《Colloids and surfaces. A, Physicochemical and engineering aspects》1993,80(2-3):113-120
The aggregation properties of ammonium perfluorooctanoate (NH4-PFO) in concentrated aqueous phases have been investigated by magnetic resonance techniques and have been compared with the aggregation properties in dilute solutions. Magnetic resonance methods indicated that NH4-PFO—water systems with surfactant concentrations below 45% (w/w) behaved as isotropic purely micellar solutions in the temperature range 285–340 K. For higher concentrations the system exhibited a rather complex structure, having both isotropic and anisotropic components. The nematic nature of the anisotropic fraction was demonstrated by 19F NMR studies. The 19F NMR and EPR of nitroxides (TempTMA+, 5- and 16-DXSA) inserted as paramagnetic probes into the concentrated NH4-PFO—water systems allowed us to establish that the lamellar phase could be mechanically oriented between quartz slides. The EPR investigation also gave details concerning the dynamics of both the oriented and non-oriented structures. 相似文献
9.
10.
H. Gr?ssler D. Lanske R. Schulte G.T. Jones R.P. Middleton S.W. ONeale K. B?ckmann W. Gebel C. Geich-Gimbel B. Nellen A. Grant H. Klein D.R.O. Morrison P. Schmid H. Wachsmuth J.S. Chima M.M. Mobayyen J. Wells 《Nuclear Physics B》1983,223(2):269-295
In an experiment with the hydrogen bubble chamber BEBC at CERN multiplicities of hadrons produced in νp and interactions have been investigated. Results are presented on the multiplicities of charged hadrons and neutral pions, forward and backward multiplicities of charged hadrons and correlations between forward and backward multiplicities. Comparisons are made with hadronic reactions and e+e? annihilation. In the framework of the quark-parton model the data imply similar charged multiplicities for the fragments of a u- and a d-quark, and a larger multiplicities for the fragments of a uu- than for a ud-diquark. The correlation data suggest independent fragmentation of the quark and diquark for hadronic masses above ~ 7 GeV and local charge compensation within an event. 相似文献