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Antoni W. Morawski Ewelina Kusiak-Nejman Jacek Przepiórski Roksana Kordala Juliusz Pernak 《Cellulose (London, England)》2013,20(3):1293-1300
TiO2/N-cellulose nanocomposite was successfully prepared in the (cyclohexyl)hexyl-dimethylammonium acetate–dimethyl sulfoxide solution. The obtained composite was characterized with various techniques like UV–Vis/DR, FTIR/DRS, X-ray diffraction, thermogravimetric analysis, DLS method and BET SSA measurements. TiO2/N-cellulose nanocomposite exhibited high UV–Vis light absorption with energy gap shifted to the visible region. Additive of TiO2/N photocatalyst to cellulose-IL-DMSO solution leads to obtaining the material with higher thermostability and limited photoactivity. 相似文献
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We investigate the doping dependence of the penetration depth versus temperature in electron-doped Pr(2-x)Ce(x)CuO(4-delta) using a model which assumes the uniform coexistence of (mean-field) antiferromagnetism and superconductivity. Despite the presence of a d(x2-y2) pairing gap in the underlying spectrum, we find nodeless behavior of the low-T penetration depth in the underdoped case, in accord with experimental results. As doping increases, a linear-in-T behavior of the penetration depth, characteristic of d-wave pairing, emerges as the lower magnetic band crosses the Fermi level and creates a nodal Fermi surface pocket. 相似文献
4.
Preparation and Regioselective Metalation of Bis(trimethylsilyl)methyl‐Substituted Aryl Derivatives
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Veronika Werner Thomas Klatt Masaya Fujii Jenifer Markiewicz Prof. Dr. Yitzhak Apeloig Prof. Dr. Paul Knochel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(27):8338-8342
A range of bis(trimethylsilyl)methyl‐substituted aryl derivatives was prepared by using a Kumada–Corriu cross‐coupling reaction. The regioselective metalation of the resulting bis(trimethylsilyl)methyl‐substituted aryl derivatives bearing this bulky silyl group allowed the generation of functionalized aromatics. A regioselective switch in the presence or in the absence of the bis(trimethylsilyl)methyl group has been demonstrated. Furthermore, this silyl group was converted into a formyl group or a styryl group, enhancing the scope of application of such bis(trimethylsilyl)methyl‐substituted arenes. 相似文献
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In this paper we theoretically analyze two mechanisms which could account for the experimentally observed increase in pair density for the strain-confined electron-hole liquid (EHL) in Ge. We find that the change in drop density with uniform stress is insufficient to explain the experimental result. However, we find that the strain gradient in the well acts to compress the liquid sufficiently to explain the observed density increases. Densities of twice the equilibrium value can be easily obtained for large enough drop size, but the density should vary by < 10% if the drop radius is < 100 μm. 相似文献
6.
R.S. Markiewicz H.R. Hart L.V. Interrante J.S. Kasper 《Solid State Communications》1980,35(7):513-517
Both Shubnikov-de Haas and de Haas-van Alphen oscillations are reported for C8nAsF5 (n=1,2, is the stage number). The observed oscillations are interpreted in terms of a tight-binding model for the band structure, and good agreement with both band parameters and effective carrier masses is found. In addition, the effective charge transfer per AsF5 molecule (f=.37 for stage 1, =.41 for stage 2) is in basic agreement with previous determinations. 相似文献
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Theoretical expressions and their approximate formulae for the intensities of light diffracted by two adjacent ultrasonic beams are discussed and compared with experimental data for the case when the second beam is an even harmonic of the first (fundamental). In the special case of the fundamental and its second or fourth harmonic, relatively simple formulae are found for the first and second diffraction orders describing the variation of light intensity with phase shift and intensity ratio.The approximate formulae describe the experiments satisfactorily only for small values of ζ1 and αn. For higher values the exact formulae give better agreement. Only the Raman-Nath region is considered. 相似文献
10.
We present a three-band Hubbard Hamiltonian and the associated Cu Kappa-edge resonant inelastic x-ray scattering (RIXS) spectra for electron- and hole-doped cuprates over a wide range of energy and momentum transfers. By comparing computed spectra for the unfilled case with the corresponding results for 15% electron or hole doping at two different values of the effective Hubbard parameter , generic signatures of the collapse of the magnetic gap and the characteristic momentum dependencies and evolution of the spectra with doping are identified. Available RIXS data support the gap collapse scenario for electron-doped cuprates, but the situation in hole-doped systems is found to be less clear. 相似文献