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Titration microcalorimetry is used to study the influences of iodide, bromide, and chloride counterions on the aggregation of vesicle-forming 1-methyl-4-(2-pentylheptyl)pyridinium halide surfactants. Formation of vesicles by these surfactants was characterised using transmission electron microscopy. When the counterion is changed at 303 K through the series iodide, bromide, to chloride, the critical vesicular concentration (cvc) increases and the enthalpy of vesicle formation changes from exo- to endothermic. With increase in temperature to 333 K, vesicle formation becomes strongly exothermic. Increasing the temperature leads to a decrease in enthalpy and entropy of vesicle formation for all three surfactants. However the standard Gibbs energy for vesicle formation is, perhaps surprisingly, largely unaffected by an increase in temperature, as a consequence of a compensating change in both standard entropy and standard enthalpy of vesicle formation. Interestingly, standard isobaric heat capacities of vesicle formation are negative, large in magnitude but not strikingly dependent on the counterion. We conclude that the driving force for vesicle formation can be understood in terms of overlap of the thermally labile hydrophobic hydration shells of the alkyl chains. Copyright 2000 Academic Press. 相似文献
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de Farias RF de Souza JM de Melo JV Airoldi C 《Journal of colloid and interface science》1999,212(1):123-129
The effects exhibited by adsorbed conducting polyaniline on the redox process on a molybdenum oxide surface were studied. Thermogravimetric results indicate a 4% polyaniline deposition. Cyclic voltammograms of the adsorbed polymer on MoO3 show that polyaniline exerts remarkable effects on the molybdenum blue oxidation-reduction process, with oxidation and reduction potentials of 0.33 and 0.18 V, respectively. This effect strongly enhances the electrode response, and can be used as an important tool in qualitative and/or quantitative determinations of molybdenum in solution as well as in any substrate. Copyright 1999 Academic Press. 相似文献
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We prove that the SLE
κ
trace in any simply connected domain G is continuous (except possibly near its endpoints) if κ < 8. We also prove an SLE analog of Makarov’s Theorem about the support of harmonic measure. 相似文献
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A quantum statistical formula for the equation of state of fully ionized plasmas in the mean temperature and mean density region is given. The complete second virial coefficient for the case of Debye screening is taken into account. The binary Slater sums are represented by interpolation between the analytical expressions for small and for large radii respectively. Using the interpolation formulae the equation of state is calculated numerically for the temperatures T = 20000 K and T = 80000 K. The resulting curves are in good agreement with the analytical equation of state for very small densities. 相似文献
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We study a family of control problems that arise in the design of dynamically loaded bearings which have a minimum power loss; in particular, we study the design of piston rings with minimum parasitic power loss.This research was partially supported by NSF Grant No. MCS-77-05624. 相似文献