排序方式: 共有19条查询结果,搜索用时 15 毫秒
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Ban G Bodek K Daum M Henneck R Heule S Kasprzak M Khomutov N Kirch K Kistryn S Knecht A Knowles P Kuźniak M Lefort T Mtchedlishvili A Naviliat-Cuncic O Plonka C Quéméner G Rebetez M Rebreyend D Roccia S Rogel G Tur M Weis A Zejma J Zsigmond G 《Physical review letters》2007,99(16):161603
In case a mirror world with a copy of our ordinary particle spectrum would exist, the neutron n and its degenerate partner, the mirror neutron n', could potentially mix and undergo nn' oscillations. The interaction of an ordinary magnetic field with the ordinary neutron would lift the degeneracy between the mirror partners, diminish the n' amplitude in the n wave function and, thus, suppress its observability. We report an experimental comparison of ultracold neutron storage in a trap with and without superimposed magnetic field. No influence of the magnetic field is found and, assuming negligible mirror magnetic fields, a limit on the oscillation time taunn' > 103 s (95% C.L.) is derived. 相似文献
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A synthesis of an antagonist of E-selectin previously reported by a group at Novartis Pharma in Basel is described. An important feature involves the formation of an ether linkage based on a Rh(II)-catalyzed reaction. Stereocontrolled glycosylations rely on the anomeric activation of 2-pyridylthio carbonate as leaving group for the attachment of beta-D-galactopyranosyl and alpha-L-fucopyranosyl units on a common 1,5-anhydro D-glucitol scaffold. 相似文献
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Franz Rogel 《Mathematische Annalen》1890,36(2):304-315
Ohne Zusammenfassung 相似文献
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German Urbina-Villalba Estrella Rogel Maria Lupe Márquez Isaac Reif 《Journal of computer-aided molecular design》1994,8(3):273-282
Summary The semiempirical MNDO method has been used in order to examine the variation of the molecular properties of hydrocarbons CnH2n+2 (with 1n19) and ethylene oxide chains CH3(CH2CH2O)mCH3 (with 1m19) as a function of their molecular length. Least-square fits of those properties have been calculated, along with two mathematical relations between the hydrophile-lipophile balance of alkyl-phenol ethoxylated surfactants and (1) the ratio of molecular lengths between their lipophilic and hydrophilic branches; (2) the intermolecular energies between the molecules of surfactant, water and hexane. 相似文献
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D L Boger S H Kim Y Mori J H Weng O Rogel S L Castle J J McAtee 《Journal of the American Chemical Society》2001,123(9):1862-1871
Full details of studies leading to the total synthesis of the teicoplanin aglycon are provided. Key elements of the first generation approach (26 steps from constituent amino acids, 1% overall) include the coupling of an EFG tripeptide precursor to the common vancomycin/teicoplanin ABCD ring system and sequential DE macrocyclization of the 16-membered ring with formation of the diaryl ether via a phenoxide nucleophilic aromatic substitution of an o-fluoronitroaromatic (80%, 3:1 atropisomer diastereoselection) followed by 14-membered FG ring closure by macrolactamization (66%). Subsequent studies have provided a second generation total synthesis which is shorter, more convergent, and highly diastereoselective (22 steps, 2% overall). This was accomplished by altering the order of ring closures such that FG macrolactamization (95%) preceded coupling of the EFG tripeptide to the ABCD ring system and subsequent DE ring closure. Notably, DE macrocyclization via diaryl ether formation on substrate 57, the key intermediate in the latter approach incorporating the intact FG ring system, occurred with exceptional diastereoselection for formation of the natural atropisomer (>10:1, 76%) without problematic C(2)(3) epimerization provided the basicity of the reaction is minimized. 相似文献
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