含R_2dtc配体Mo-Cu化合物的动态~(95)Mo NMR

本实验利用动态~(95)Mo NMR监测Mo-Cu系列化合物的形成过程,对反应CuCl+NaR_2dtc+MoO_nS,摩尔比3:3:1,溶剂为DMF;R=Et,n=0(Ⅰ);R=Me,n=0(Ⅱ);R=Et,n=2(Ⅲ)进行了研究,观察到具有不同簇骼的多种中间产物的存在及随反应进程相互转化等现象。     

An Analog for the Frattini Factorization of Finite Groups

Using the classification of finite simple groups, we prove that if H is an insoluble normal subgroup of a finite group G, then H contains a maximal soluble subgroup S such that G=HN_G(S). Thereby Problem 14.62 in the Kourovka Notebook is given a positive solution. As a consequence, it is proved that in every finite group, there exists a subgroup that is simultaneously a -projector and a -injector in the class, , of all soluble groups.     

On the local case in the Aschbacher theorem for linear and unitary groups

We consider the subgroups H in a linear or a unitary group G over a finite field such that O _r (H) ? Z(G) for some odd prime r. We obtain a refinement of the well-known Aschbacher theorem on subgroups of classical groups for this case.     

On the class of groups with pronormal hall π-subgroups

Given a set π of prime numbers, we define the class of all finite groups in which Hall π-subgroups exist and are pronormal by analogy with the Hall classes , , and . We study whether is closed under the main class-theoretic closure operations. In particular, we establish that is a saturated formation.     

[2+4] Cycloaddition of η6-(styrene)chromium tricarbonyl and conjugated dienes

Cycloaddition of η⁶-(styrene)chromium tricarbonyl to hexa-2,4-diene or cyclopentadiene afford the Diels-Alder adducts with retention of the Cr(CO)₃ group, whereas cyclohexa-1,3-diene undergoes aromatization to give η⁶-(benzene)chromium tricarbonyl. The counter synthesis of these (arene)chromium tricarbonyl derivatives from uncoordinated adducts of the Diels-Alder reaction and chromium hexacarbonyl was carried out.