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1.
Reinvestigation of the reaction of 3-aroylmethyleneindol-2-ones with hydrogen peroxide has revealed that a 1:1 isomeric mixture of spiro[3H-indole-3,2′-oxiran]-2(1H)-ones is formed. The structures of the two isomers have been confirmed by their ir, pmr and mass spectral studies. Mass fragmentation patterns of these compounds are discussed. 相似文献
2.
Krishna C. Joshi Renuka Jain Anshu Dandia Vandana Sharma 《Journal of heterocyclic chemistry》1986,23(1):97-99
A novel system 2-oxo-1′,2′,4′,5′-tetrahydrospiro[3H-indole-3,3′-1,2,4,5-tetrazine]-6′-thione has been synthesized by the treatment of fluorinated isatins with thiocarbohydrazide in aqueous ethanolic medium. Under exactly similar conditions, N-acetylisatin gave exclusively thiocarbohydrazone. The spiro product, on treatment with acetic acid, gave fluorinated isoindigo. Characterization of these products have been done by elemental analyses, ir, pmr and mass spectral studies. 相似文献
3.
The separation characteristics of alkylchloroformate-derivatised amino acids (AAs) by using comprehensive two-dimensional gas chromatography (GC×GC) is reported. The use of a low-polarity/polar column set did not provide as good a separation performance as that achieved with a polar/non-polar column set, where the latter appeared to provide less correlation over the separation space. The degree of component correlation in each column set was estimated by using the correlation coefficient (r2; for 1tR and 2tR data) with the low-polarity/polar and polar/low-polarity sets returning correlation coefficients of 0.86, and 0.00 respectively, under the respective conditions employed for the experiments. The 1.5-m non-polar 2D column (0.1-mm ID; 0.1-m film thickness) gave peak halfwidths of the order of 50–80 ms. Linearity of detection was good, over a three order of magnitude concentration range, with typical lower detection limit of ca. 0.01 mg L–1, compared with 0.5 mg L–1 for normal GC operation with splitless injection. The method was demonstrated for analysis of AAs in a range of food and beverage products, including wine, beer and honey. The major AA in these samples was proline. The Heineken beer sample had a relatively more complex and more abundant AA content compared with the other beer sample. The wine and honey samples also gave a range of AA compounds. Repetition of the sample preparation/analysis procedure for the honey sample gave acceptable reproducibility for individual AAs. 相似文献
4.
A facile one‐pot, three‐component protocol for the synthesis of novel spiro[3H‐indole‐3,2′‐thiazolidine]‐2,4′(1H)‐diones by condensing 1H‐indole‐2,3‐diones, 4H‐1,2,4‐triazol‐4‐amine and 2‐sulfanylpropanoic acid in [bmim]PF6 (1‐butyl‐3‐methyl‐1H‐imidazolium hexafluorophosphate) as a recyclable ionic‐liquid solvent gave good to excellent yields in the absence of any catalyst (Scheme 1 and Table 2). The advantages of this protocol over conventional methods are the mild reaction conditions, the high product yields, a shorter reaction time, as well as the eco‐friendly conditions. 相似文献
5.
The Barbier type allylation of carbonyl compounds is a useful organic transformation as the resultant homoallylic alcohols are important building blocks for many biologically active molecules. Tin mediated Barbier allylation of different carbonyl compounds in room temperature ionic liquid, [BMIM][BF4] afforded the corresponding homoallylic alcohols in good to excellent yields. The ionic liquid was successfully recycled and reused in allylation reactions. 相似文献
6.
Nilmini K. Abayasinghe Sibylle Glaser K. Prasanna U. Perera Dennis W. Smith 《Journal of polymer science. Part A, Polymer chemistry》2005,43(21):5257-5266
Oligoethylene‐end‐capped polylactides were synthesized through the ring‐opening polymerization of L ‐lactide with alcohol‐terminated oligoethylenes as macroinitiators. The polymerization of L ‐lactide was carried out in bulk at 130 °C in the presence of stannous octoate and primary alcohols with four different molecular weights: 350, 425, 550, and 700 g/mol. The end‐capped copolymers that formed had a number‐average molecular weight of approximately 40,000 (weight‐average molecular weight/number‐average molecular weight = 1.7) according to gel permeation chromatography and were highly crystalline in comparison with the similarly formed homopolymer of L ‐lactide. The copolymer structure was characterized by Fourier transform infrared, NMR, matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry, and differential scanning calorimetry analysis. This work focused on developing more crystallizable and hydrolytically stable polylactide derivatives that could potentially be used as compatibilizers in polylactide–polyolefin blends or as nucleating agents for poly(L ‐lactide) or other polyesters. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5257–5266, 2005 相似文献
7.
Alexandra Brown Victoria Hogan Jacob Perry Renuka Manchanayakage 《Tetrahedron letters》2017,58(11):1061-1065
Chiral ionic liquids show promising applications in various different fields. A series of pyrrolidinium-based chiral ionic liquids bearing a chiral cation, a chiral anion or both was prepared in good yields using an efficient, economic and simple pathway. The chirality was introduced using (l)-lactate and (l)-menthol derivatives. The resultant chiral compounds were characterized by both spectroscopy and polarimetry. We envision that these new chiral compounds can serve as effective reaction media and chiral catalysts for asymmetric reactions, which are presently being investigated in our lab. 相似文献
8.
Effect of various abiotic (methyl jasmonate, salicylic acid) and biotic (yeast extract, Aspergillus niger) elicitors on furanocoumarin production and in situ product removal was studied using shoot cultures of Ruta graveolens L. Elicitation by yeast extract (1% w/v) on day 15 was most effective. It led to 7.8-fold higher furanocoumarin production that was attained 24 h after elicitation
and 43% of the product was released into the medium. Changes in the relative concentration of furanocoumarins produced depend
on the elicitor used. Molar ratio of bergapten increased to 93% in response to yeast extract. With the perspective of developing
a commercially feasible process, an approach for preserving viability of biomass and its reuse needs to be developed. For
this, medium renewal strategy was investigated. Removal of the spent medium 48 h after elicitation allowed in situ product
removal and proved effective in revival of cultures, allowing reuse of biomass. A week after medium renewal, the revived biomass
was re-elicited and a second furanocoumarin production peak was obtained. A perfusion-based bioprocess optimization approach,
employing elicitation coupled with medium renewal with subsequent re-elicitation, as a new strategy for improved furanocoumarin
production, has been suggested. 相似文献
9.
R. Renuka S. Rajasekaran Ganga Radhakrishnan 《Applied biochemistry and biotechnology》2001,96(1-3):83-92
Among the possible new materials for microelectronics, quinones have a number of significant advantages. Similarly, polymers
with quinone functionality possess biodegradability. Because natural polymers are promising candidates for functional materials
for the future, we have initiated studies on the polymers of natural products. In the present study, a natural quinone (a
plant substance) extracted from Embelier libes distributed in the Kerala state of India was electrochemically polymerized and its properties were investigated. The redox
activity, electrical conductivity, and biodegradability are discussed. 相似文献
10.
For axially symmetric deformations of the perfectly elastic neo-Hookean and Mooney materials, formal series solutions are
determined in terms of expansions in appropriate powers of 1/R, where R is the cylindrical polar coordinate for the material coordinates. Remarkably, for both the neo-Hookean and Mooney materials,
the first three terms of such expansions can be completely determined analytically in terms of elementary integrals. From
the incompressibility condition and the equilibrium equations, the six unknown deformation functions, appearing in the first
three terms can be reduced to five formal integrations involving in total seven arbitrary constants A, B, C, D, E, H and k
2, and a further five integration constants, making a total of 12 integration constants for the deformation field. The solutions
obtained for the neo-Hookean material are applied to the problem of the axial compression of a cylindrical rubber tube which
has bonded metal end-plates. The solution so determined is approximate in two senses; namely as an approximate solution of
the governing equations and for which the stress free and displacement boundary conditions are satisfied in an average manner
only. The resulting load-deflection relation is shown graphically. The solution so determined, although approximate, attempts
to solve a problem not previously tackled in the literature.
相似文献