全文获取类型
收费全文 | 280篇 |
免费 | 14篇 |
国内免费 | 1篇 |
专业分类
化学 | 179篇 |
晶体学 | 1篇 |
力学 | 5篇 |
数学 | 10篇 |
物理学 | 100篇 |
出版年
2024年 | 4篇 |
2023年 | 5篇 |
2022年 | 8篇 |
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 12篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 8篇 |
2014年 | 18篇 |
2013年 | 14篇 |
2012年 | 24篇 |
2011年 | 15篇 |
2010年 | 18篇 |
2009年 | 16篇 |
2008年 | 17篇 |
2007年 | 12篇 |
2006年 | 8篇 |
2005年 | 5篇 |
2004年 | 5篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 2篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 6篇 |
1996年 | 5篇 |
1994年 | 2篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 4篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1968年 | 2篇 |
排序方式: 共有295条查询结果,搜索用时 8 毫秒
1.
Absolute total electron scattering cross sections for carbon dioxide have been measured at low electron energies using a photoelectron
source. The measurements have been carried out at 27 electron energies varying from 0.91–9.14 eV with an accuracy of ±3%.
The cross sections obtained in the present experiment have been compared with other measurements and theoretical computations. 相似文献
2.
3.
Kamlakar Avasthi Diwan S. Rawat Tilak Chandra Ashoke Sharon Prakas R. Maulik 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(6):o311-o313
In 5-benzyl-1,7-dimethyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-d]pyrimidine-4,6-dione, C14H14N4O2, which crystallizes in space group P, weak intermolecular C—H⋯O hydrogen bonds generate dimers. The isomeric compound 1-benzyl-5,7-dimethyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-d]pyrimidine-4,6-dione, C14H14N4O2, crystallizes in space group P21/n, and shows no such dimerization. Instead, it exhibits C—H⋯π interactions with the phenyl ring. In both structures, the molecules are linked by aromatic π–π-stacking interactions. 相似文献
4.
A new chelating resin was synthesised by the modification of styrene-divinylbenzene (2%) copolymer and incorporation of dithiocarbamate groups. The polydithiocarbamate resin was characterised by elemental analysis, thermal studies and IR studies. The analytical characteristics of the sorbent were established and optimum sorption conditions for Cu, Ni, Pb, Fe, As and Mn determined. The total sorption capacity of the resin was 37 mg g−1 for Ni(II), 35 mg g−1 for Cu(II), 29 mg g−1 for Fe(III) and 23 mg g−1 for Pb(II). The optimum pH for the removal of metal ions was 3-5 for Ni(II), 5 for Cu(II), 4 for Fe(III) and 4-5 for Pb(II). High sorption capacity was observed when compared with other conventional chelating polymers. The sorption kinetics was fairly rapid, as apparent from the loading half time t1/2 values, indicating a better accessibility of the chelating sites. 相似文献
5.
In this paper, the effect of bismuth doping on the structural, morphological, optical and electrical properties of Cu2ZnSnS4 (CZTS) films has been investigated. The undoped and bismuth doped CZTS films (0, 0.5, 1, 1.5 and 2 mol%) were deposited on glass substrates by solution based method. The XRD result shows a significant improvement in the crystallinity of the films with increase in bismuth concentration. The Raman spectra of the films show the dominant peak at 334 cm–1 corresponding to A1 vibrational mode of CZTS kesterite phase. The FESEM micrographs of the films show an enhancement in the grain size and densification with the addition of bismuth ion concentration. The optical bandgap of the films was found to vary (1.59–1.40 eV) with the doping of bismuth ions. The I –V characteristics indicate twofold increment in the photoconductivity for the bismuth doped CZTS films under 100 mW/cm2 illumination suggesting their potential application in photovoltaic devices. (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
6.
Anil M. Shelke Varun Rawat Gurunath Suryavanshi Arumugam Sudalai 《Tetrahedron: Asymmetry》2012,23(22-23):1534-1541
A new enantioselective synthesis of two important fungal metabolites, (+)-stagonolide C and (?)-aspinolide A, has been described from readily available raw materials. Proline catalyzed asymmetric α-aminooxylation and Jorgensen’s epoxidation of aldehydes are the key reactions employed in the introduction of chirality. The formation of the 10-membered lactone core structure was finally accomplished via Steglich esterification and ring closing metathesis reactions. 相似文献
7.
Eric Johnsen Johan Larsson Ankit V. Bhagatwala William H. Cabot Parviz Moin Britton J. Olson Pradeep S. Rawat Santhosh K. Shankar Bj?rn Sj?green H.C. Yee Xiaolin Zhong Sanjiva K. Lele 《Journal of computational physics》2010,229(4):1213-1237
Flows in which shock waves and turbulence are present and interact dynamically occur in a wide range of applications, including inertial confinement fusion, supernovae explosion, and scramjet propulsion. Accurate simulations of such problems are challenging because of the contradictory requirements of numerical methods used to simulate turbulence, which must minimize any numerical dissipation that would otherwise overwhelm the small scales, and shock-capturing schemes, which introduce numerical dissipation to stabilize the solution. The objective of the present work is to evaluate the performance of several numerical methods capable of simultaneously handling turbulence and shock waves. A comprehensive range of high-resolution methods (WENO, hybrid WENO/central difference, artificial diffusivity, adaptive characteristic-based filter, and shock fitting) and suite of test cases (Taylor–Green vortex, Shu–Osher problem, shock-vorticity/entropy wave interaction, Noh problem, compressible isotropic turbulence) relevant to problems with shocks and turbulence are considered. The results indicate that the WENO methods provide sharp shock profiles, but overwhelm the physical dissipation. The hybrid method is minimally dissipative and leads to sharp shocks and well-resolved broadband turbulence, but relies on an appropriate shock sensor. Artificial diffusivity methods in which the artificial bulk viscosity is based on the magnitude of the strain-rate tensor resolve vortical structures well but damp dilatational modes in compressible turbulence; dilatation-based artificial bulk viscosity methods significantly improve this behavior. For well-defined shocks, the shock fitting approach yields good results. 相似文献
8.
Zinc salicylaldimine complex immobilized on silica gel was used as a promising catalyst for the transesterification reaction of dimethyl terephthalate (DMT) and ethylene glycol (EG).The catalyst was characterized by Fourier transform infra‐red spectroscopy (FT‐IR), thermogravimetric analysis (TGA) and atomic absorption spectroscopy (AAS). The product bis‐(2‐hydroxyethyl)terephthalate (BHET)was confirmed by mass and 1H‐NMR studies. In comparison to zinc acetate i.e., homogeneous catalyst, a polymer supported catalyst showed better stability, catalytic activity and ease of separation from the reaction product. The catalyst can be reutilized during successive catalytic cycles. 相似文献
9.
The standard molar enthalpy of formation of LaPO4(s), NdPO4(s), and SmPO4(s) has been determined using an isoperibol solution calorimeter. The solution calorimeter vessel was held at 298.15 K. The precipitation reaction between aqueous solution of rare-earth chloride (LnCl3(aq.)) and ammoniacal solution of ammonium dihydrogen phosphate (NH4H2PO4(aq.)) was studied. The temperature of the calorimeter vessel was measured before, during, and after the reaction. The enthalpy change due to precipitation of LaPO4(s), NdPO4(s), or SmPO4(s) from required solutions was measured at 298.15 K. Using these values and other auxiliary data from the literature, thermochemical reaction scheme were devised to calculate the standard enthalpy of formation of each phosphate compound i.e., LaPO4(s), NdPO4(s), and SmPO4(s). The calculated values for LaPO4(s), NdPO4(s), and SmPO4(s) at 298.15 K were found to be ?1947.5 ± 3.2, ?1938.3 ± 3.6, and ?1942.9 ± 3.4 kJ mol?1, respectively. 相似文献
10.
Manjulata Yadav Mukesh Rawat Anoop Dangwal Mukesh Prasad G. S. Gusain R. C. Ramola 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(2):869-873
Distribution of natural radionuclide gives significant parameter to assess the presence of gamma radioactivity and its radiological effect in our environment. Natural radionuclides are present in the form of 226Ra, 232Th and 40K in soil, rocks, water, air, and building materials. Distribution of natural radionuclides depends on the type of minerals present in the soil and rocks. For this purpose gamma spectrometer is used as tool for finding the concentration of these radionuclides. The activity concentration of naturally occurring radionuclides 226Ra, 232Th and 40K in these soil samples were found to vary from of 8 ± 1 Bq/kg to 50 ± 10 Bq/kg with an average 20 Bq/kg, 7 ± 1–88 ± 16 Bq/kg with an Average 26 Bq/kg and 115 ± 18–885 ± 132 Bq/kg with an average 329 Bq/kg, respectively. In this paper, we are presenting the radiological effect due to distribution of natural radionuclide present in soil of Garhwal Himalaya. 相似文献