首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1389篇
  免费   74篇
  国内免费   24篇
化学   1052篇
晶体学   14篇
力学   45篇
数学   127篇
物理学   249篇
  2024年   11篇
  2023年   18篇
  2022年   86篇
  2021年   91篇
  2020年   68篇
  2019年   60篇
  2018年   53篇
  2017年   41篇
  2016年   64篇
  2015年   46篇
  2014年   67篇
  2013年   83篇
  2012年   124篇
  2011年   110篇
  2010年   64篇
  2009年   63篇
  2008年   61篇
  2007年   56篇
  2006年   41篇
  2005年   48篇
  2004年   22篇
  2003年   23篇
  2002年   23篇
  2001年   9篇
  2000年   6篇
  1999年   4篇
  1998年   5篇
  1997年   11篇
  1996年   9篇
  1995年   5篇
  1994年   3篇
  1993年   7篇
  1992年   4篇
  1991年   5篇
  1990年   3篇
  1988年   3篇
  1987年   4篇
  1986年   7篇
  1985年   4篇
  1984年   8篇
  1982年   7篇
  1981年   4篇
  1980年   5篇
  1978年   6篇
  1976年   5篇
  1975年   6篇
  1973年   8篇
  1972年   5篇
  1970年   3篇
  1968年   4篇
排序方式: 共有1487条查询结果,搜索用时 15 毫秒
1.
A closed-form expression is presented to find the location of solid-liquid interface motion in convection-dominated solidification and melting problems. In this regard, the solutions are expressed in terms of the generalized representations of error functions,E (u, v) andF (u, v), which are useful to heat-conduction problems with convective-type boundary conditions. It is demonstrated that for constant surface temperature, the interface solution reduces to the classical Neumann solution.  相似文献   
2.
The solubility and diffusion coefficient of carbon dioxide in intermediate‐moisture starch–water mixtures were determined both experimentally and theoretically at elevated pressures up to 16 MPa at 50 °C. A high‐pressure decay sorption system was assembled to measure the equilibrium CO2 mass uptake by the starch–water system. The experimentally measured solubilities accounted for the estimated swollen volume by Sanchez–Lacombe equation of state (S‐L EOS) were found to increase almost linearly with pressure, yielding 4.0 g CO2/g starch–water system at 16 MPa. Moreover, CO2 solubilities above 5 MPa displayed a solubility increase, which was not contributed by the water fraction in the starch–water mixture. The solubilities, however, showed no dependence on the degree of gelatinization (DG) of starch. The diffusion coefficient of CO2 was found to increase with concentration of dissolved CO2, which is pressure‐dependent, and decrease with increasing DG in the range of 50–100%. A free‐volume‐based diffusion model proposed by Areerat was employed to predict the CO2 diffusivity in terms of pressure, temperature, and the concentration of dissolved CO2. S‐L EOS was once more used to determine the specific free volume of the mixture system. The predicted diffusion coefficients showed to correlate well with the measured values for all starch–water mixtures. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 607–621, 2006  相似文献   
3.
Iqbal MS  Rashid F  Javed NA 《Talanta》1991,38(6):603-605
An electrolytic device for decomposition of water has been developed which readily gives hydrogen and oxygen for isotopic measurement with a mass spectrometer. A 20-mul sample can be decomposed quantitatively in 10 min with good reproducibility. The results produced are comparable with those obtained by reduction with uranium.  相似文献   
4.
Virion polypeptides (35 S), methionine-labeled and purified by CsCl gradient centrifugation, were separated by SDS-gel electrophoresis. Analysis of their band pattern was performed by scanning the images of the SDS-gels shown on a 35-mm slide. The densitometric tracings revealed the presence of 17 protein bands, although only 15 of them were visible to the naked eye. The high sensitivity and resolving capacities of the soft-laser scanning densitometer enabled us to detect trace amounts of protein bands separated in SDS-gels and to obtain a resolution compatible to that of electrophoresis. Fourfold electronic amplification of the densitometric tracings, produced by a computer, generated new information regarding the pattern of the electrophoregram. The facility to amplify peaks of importance is particularly advantageous when faint or overlapping protein bands revealed on a gel are assessed.  相似文献   
5.
A study on the concentration of natural and fallout radionuclides in environmental samples collected from different localities of Islamabad was performed. For the determination of gamma-emitters such as 238U, 232Th, 40K and 137Cs high purity germanium (HPGe) detector was used while for the analysis of 90Sr, a beta-emitter, liquid scintillation counting system was used. The indoor absorbed dose rate was measured by a CaF2 : Dy thermoluminescence detector. Other radiation parameters were also determined to evaluate the radiation hazard. All the results were well within the permissible limits showing that there is no radiation hazard in the environment of Islamabad.  相似文献   
6.
7.
In view of the attributed medicinal properties of beta-carboline alkaloids, some new O-acyl derivatives of beta-carboline alkaloid--harmol, were prepared and tested for possible antimycobacterial activity against Mycobacterium tuberculosis H37Rv.  相似文献   
8.
Summary A parametric study of catalytic reforming process in a pilot plant was carried out by varying the pressure, H2/HC ratio, and space velocity. The results show that lower aromatics and higher hydrogen yields can be accomplished by increasing the space velocity in existing reformers, which will also result in better C5+yield.  相似文献   
9.
The investigation of the chemical constituents of Symplocos racemosa Roxb led to the isolation of two new glycosides, symcomoside A (1) and symcomoside B (2), together with one known glycoside, tortoside C (3), which is reported for the first time from this plant. The structures of the new compounds were determined by 1D and 2D homonuclear and heteronuclear NMR spectroscopy, from chemical evidence and by comparison with published data for closely related compounds. Symcomoside B (2) showed potent inhibitory activity against alpha-glucosidase in a concentration-dependent fashion with an IC50 value of 0.733 +/- 0.033 mM whereas symcomoside A (1) showed very weak inhibitory activity against alpha-glucosidase (9.90% in 0.70 mM).  相似文献   
10.
Substituted 2-arylbenzimidazoles, 2-arylbenzoxazoles and 2-arylbenzothiazoles were obtained in good yield by the reaction of hydroximoyl chlorides with ortho-substituted aromatic amines. The benzo moiety of the benzimidazoles was shown by nmr to be symmetrical, indicating that the N-H group proton of the imidazole ring is exchanging with the water protons in the DMSO-d6 solvent.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号