全文获取类型
收费全文 | 1441篇 |
免费 | 67篇 |
国内免费 | 7篇 |
专业分类
化学 | 1146篇 |
晶体学 | 8篇 |
力学 | 27篇 |
数学 | 155篇 |
物理学 | 179篇 |
出版年
2023年 | 4篇 |
2022年 | 36篇 |
2021年 | 54篇 |
2020年 | 38篇 |
2019年 | 46篇 |
2018年 | 25篇 |
2017年 | 30篇 |
2016年 | 55篇 |
2015年 | 61篇 |
2014年 | 49篇 |
2013年 | 99篇 |
2012年 | 108篇 |
2011年 | 130篇 |
2010年 | 77篇 |
2009年 | 76篇 |
2008年 | 101篇 |
2007年 | 94篇 |
2006年 | 74篇 |
2005年 | 75篇 |
2004年 | 60篇 |
2003年 | 42篇 |
2002年 | 39篇 |
2001年 | 19篇 |
2000年 | 18篇 |
1999年 | 12篇 |
1998年 | 10篇 |
1997年 | 3篇 |
1996年 | 10篇 |
1995年 | 10篇 |
1994年 | 7篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 8篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1979年 | 3篇 |
1977年 | 3篇 |
1966年 | 1篇 |
1932年 | 1篇 |
1914年 | 1篇 |
1913年 | 1篇 |
1905年 | 1篇 |
1904年 | 1篇 |
1890年 | 1篇 |
排序方式: 共有1515条查询结果,搜索用时 265 毫秒
1.
Cardin Pedro Toniol Teixeira Marco Antonio 《Journal of Dynamics and Differential Equations》2022,34(2):775-787
Journal of Dynamics and Differential Equations - In this paper we focus on a class of symmetric vector fields in the context of singularly perturbed fast-slow dynamical systems. Our main question... 相似文献
2.
3.
Antonio Guirado Enrique LópezSánchez Raquel Andreu Andrés Zapata 《Tetrahedron letters》2004,45(10):2075-2076
The first method for the synthesis of the title compounds has been established involving a stereoselective electrochemical diacylation process. The cathodic reductions of monothiobenzils in an aprotic medium, under constant potential, in the presence of twofold molecular amounts of aroyl chlorides provide previously unknown (Z)-α-benzoyloxy-β-benzoythiostilbenes in high to quantitative yields. 相似文献
4.
A sequential injection methodology for the spectrophotometric determination of calcium, magnesium and alkalinity in water samples is proposed. A single manifold is used for the determination of the three analytes, and the same protocol sequence allows the sequential determination of calcium and magnesium (the sum corresponds to the water hardness). The determination of both metals is based on their reaction with cresolphtalein complexone; mutual interference is minimized by using 8-hydroxyquinoline for the determination of calcium and ethylene glycol-bis(beta-aminoethyl ether)-N,N,N',N'-tetraacetic acid (EGTA) for the determination of magnesium. Alkalinity determination is based on a reaction with acetic acid, and corresponding color change of Bromcresol Green. Working ranges of 0.5 - 5 mg dm(-3) for Ca, 0.5 - 10 mg dm(-3) for Mg, and 10 - 100 mg HCO3- dm(-3), for alkalinity have been achieved. The results for water samples were comparable to those of the reference methods and to a certified reference water sample. RSDs lower than 5% were obtained, a low reagent consumption and a reduced volume of effluent have been accomplished. The determination rate for calcium and magnesium is 80 h(-1), corresponding to 40 h(-1) per element, while 65 determinations of alkalinity per hour could be carried out. 相似文献
5.
J. Teixeira 《Il Nuovo Cimento D》1994,16(9):1433-1437
Summary The dynamics of water molecules occupying very small volumes can be probed by incoherent quasi-elastic neutron scattering.
We summarise some results obtained with wet samples of porous silica and hydrated proteins. The movements of the molecules
in the vicinity of the substrate are extremely reduced as compared to those of bulk water at the same temperature. Almost
only rotational movements subsist and the local diffusion is of the order of that observed in deeply supercooled water.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献
6.
Alejandro Balbs Raquel Balbs Silvia Mayoral 《Mathematical and Computer Modelling》2007,45(11-12):1308-1318
The first Fundamental Theorem of Asset Pricing establishes the equivalence between the absence of arbitrage in financial markets and the existence of Equivalent Martingale Measures, if appropriate conditions hold. Since the theorem may fail when dealing with infinitely many trading dates, this paper draws on the A.A. Lyapunov Theorem in order to retrieve the equivalence for complete markets such that the Sharpe Ratio is adequately bounded. 相似文献
7.
Push-pull dithiafulvenes with reduced bond length alternation (BLA) and high optical nonlinearities have been prepared. The interplay between the proaromaticity of the donor and the structural and optical properties of these merocyanines is discussed. The donor ability of dithiafulvenes can reach that of ferrocene or dialkylaminophenyl groups. 相似文献
8.
Here we study the behaviour of the spin 0 sector of the DKP field in spaces with torsion. First we show that in a Riemann-Cartan manifold the DKP field presents an interaction with torsion when minimal coupling is performed, contrary to the behaviour of the KG field, a result that breaks the usual equivalence between the DKP and the KG fields.Next we analyse the case of the Teleparallel Equivalent of General Relativity (Weitzenböck manifold), showing that in this case there is a perfect agreement between KG and DKP fields. The origins of both results are also discussed.On leave from 相似文献
9.
10.
Ana C. Albniz Pablo Espinet Raquel Lpez‐Fernndez 《Journal of polymer science. Part A, Polymer chemistry》2006,44(19):5682-5691
[Pd2(μ‐Cl)2(C6F5)2(tht)2] ( 1 ) is a very efficient initiator of the radical polymerization of methyl acrylate, but it is not active in the polymerization of methyl methacrylate or in the copolymerization with 1‐hexene. The addition of an excess of NBu4Cl to solutions of [Pd2(μ‐Cl)2(C6F5)2(tht)2] ( 1 ) provides an initiator system that copolymerizes methyl acrylate and 1‐hexene by an insertion‐triggered radical mechanism. Random copolymers are obtained with 11% incorporation of 1‐hexene in moderate yields (about 35%). Studies of the decomposition products obtained after the first insertion of methyl acrylate in the Pd? C6F5 bond of 1 show that the addition of excess halide in the presence of monomer favors the homolytic cleavage of the Pd? C bond, and the generation of the radicals that are active species in the polymerization, versus alternative evolution pathways. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5682–5691, 2006 相似文献