全文获取类型
收费全文 | 261篇 |
免费 | 2篇 |
专业分类
化学 | 146篇 |
力学 | 5篇 |
数学 | 17篇 |
物理学 | 95篇 |
出版年
2022年 | 2篇 |
2021年 | 4篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 8篇 |
2012年 | 9篇 |
2011年 | 11篇 |
2010年 | 11篇 |
2009年 | 7篇 |
2008年 | 9篇 |
2007年 | 6篇 |
2006年 | 7篇 |
2005年 | 7篇 |
2004年 | 6篇 |
2003年 | 9篇 |
2002年 | 6篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 7篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 7篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1976年 | 8篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1972年 | 3篇 |
1968年 | 2篇 |
1921年 | 3篇 |
1919年 | 2篇 |
1914年 | 2篇 |
1884年 | 2篇 |
排序方式: 共有263条查询结果,搜索用时 15 毫秒
1.
Julia K Pruns Jens-Peter Vietzke Manfred Strassner Claudius Rapp Ulrich Hintze Wilfried A K?nig 《Rapid communications in mass spectrometry : RCM》2002,16(3):208-211
A new solvent-free sample preparation method using silver trifluoroacetate (AgTFA) was developed for the analysis of low molecular weight paraffins and microcrystalline waxes by laser desorption/ionization time-of-flight mass spectrometry (LDI-TOFMS). Experiments show that spectral quality can be enhanced by dispersing AgTFA directly in liquid paraffins without the use of additional solvents. This preparation mixture is applied directly to the MALDI probe. Solid waxes could be examined by melting prior to analysis. The method also provides sufficiently reproducible spectra that peak area ratios between mono- and bicyclic alkane peaks indicated variations in the cycloalkane content of paraffin samples. Dehydrogenation of hydrocarbons observed during the desorption/ionization process was studied by analysis of alkane standards. 相似文献
2.
3.
Wagner F Gruber O Lackner K Murmann HD Speth E Becker G Bosch HS Brocken H Cattanei G Dorst D Eberhagen A Elsner A Erckmann V Fussmann G Gehre O Gernhardt J Gierke Gv Glock E Grieger G Grigull P Haas G Hacker H Hartfuss HJ Jäckel H Jaenicke R Janeschitz G Junker J Karger F Kasparek W Keilhacker M Kick M Klüber O Kornherr M Kroiss H Kuehner M Lenoci M Lisitano G Maassberg M Mahn C Marlier S Mayer HM McCormick K Meisel D Mertens V Müller ER Müller Müller G Niedermeyer H Ohlendorf W 《Physical review letters》1986,56(20):2187-2190
4.
Abstract— The quantum efficiency for the photodimerization of trans -cinnamic acid in the solid state is independent of intensity and is found to have a value approaching two. Thus, the reaction involves one excited and one un-excited molecule.
During the exposure, a dimer film developing on the surface of the cinnamic acid layer attenuates the intensity of the radiation incident on the unreacted cinnamic acid. This gives the appearance of a decrease in the quantum yield with increasing number of photons incident. 相似文献
During the exposure, a dimer film developing on the surface of the cinnamic acid layer attenuates the intensity of the radiation incident on the unreacted cinnamic acid. This gives the appearance of a decrease in the quantum yield with increasing number of photons incident. 相似文献
5.
6.
Attempts to obtain a molecular ion from the polyene macrolide antibiotic pimaricin by EI and FD mass spectrometry were unsuccessful The loss of carbon dioxide and a varying number of water molecules from the molecular ion made a molecular-weight determination impossible 13C NMR spectroscopy of N-acetylpimaricin, its dodecahydroderivative, and of HH-2, a hydrogenation-hydrogenolysis product of N-acetylpimaricin, confirmed that the antibiotic has structure 3 containing a hemi-ketalic ring and lacking an OH group at C-8. The value of the anomeric coupling constant, Jc-1-h-1, indicates that the mycosamine moiety is β-glycosidically bound to the aglycone.The structure and configuration of the antibiotic have been studied by analysis of the 270 MHz 1H-NMR spectra of N acetylpimaricin and HH-2. By comparison of the two spectra and by extensive decoupling experiments, all signals in the spectrum of N-acetylpimaricin have been assigned to the protons in structure 3. From chemical-shift, coupling constant, and integral values, it was deduced that the mycosamine ring is pyranoid with a chair conformation, the hemi-ketal is 6 membered and occupies a chair conformation with the substituents in equatorial positions, the epoxy protons as well as the olefinic protons are trans to each other, and the antibiotic is diastereomerically pure. 相似文献
7.
Rapp E Jakob A Schefer AB Bayer E Albert K 《Analytical and bioanalytical chemistry》2003,376(7):1053-1061
A mixture of unsaturated fatty acid methyl esters was separated with a new splitless capillary set-up. With the employed apparatus configuration different capillary separation techniques such as capillary high-performance liquid chromatography (cHPLC), capillary electrochromatography (CEC) and pressurized capillary electrochromatography (pCEC) could be applied. The detection and identification of the sample compounds were accomplished by hyphenating these capillary separation techniques with nuclear magnetic resonance (NMR) spectroscopy using a novel configuration of the detection capillary set-up. Using modified electrokinetically driven separation techniques, the electric field was applied solely across the separation column. With this improved interface for capillary liquid chromatography-NMR on-line coupling, the stereochemical assignment of the cis and trans configuration of unsaturated fatty acids could be easily accomplished. Finally, the results of cHPLC-NMR, CEC-NMR and pCEC-NMR coupling experiments were compared.Dedicated to Professor Günter Häfelinger on the occasion of his 65th birthday 相似文献
8.
9.
The distance function \({\varrho(p, q) ({\rm or} d(p, q))}\) of a distance space (general metric space) is not differentiable in general. We investigate such distance spaces over \({\mathbb{R}^n}\), whose distance functions are differentiable like in case of Finsler spaces. These spaces have several good properties, yet they are not Finsler spaces (which are special distance spaces). They are situated between general metric spaces (distance spaces) and Finsler spaces. We will investigate such curves of differentiable distance spaces, which possess the same properties as geodesics do in Finsler spaces. So these curves can be considered as forerunners of Finsler geodesics. They are in greater plenitude than Finsler geodesics, but they become geodesics in a Finsler space. We show some properties of these curves, as well as some relations between differentiable distance spaces and Finsler spaces. We arrive to these curves and to our results by using distance spheres, and using no variational calculus. We often apply direct geometric considerations. 相似文献
10.