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排序方式: 共有198条查询结果,搜索用时 15 毫秒
1.
The rate of electron transfer from organic sulfides to [CrV(ehba)2]− (ehba-2-ethyl-2-hydroxy butyric acid) decreases with a decrease in the polarity of the medium. The anionic surfactant, SDS and the cationic surfactant, CTAB have different effects on the kinetics of this reaction. The micellar inhibition observed in the presence of SDS is probably due to the decrease in the polarity and the electrostatic repulsion faced by the anionic oxidant from the anionic micelle and the partition of the hydrophobic substrate between the aqueous and micellar phases. The micellar catalysis in the presence of CTAB is attributed to the increase in the concentration of both reactants in the micellar phase. This micellar catalysis is observed to offset the retarding effects of the less polar micellar medium and the unfavorable charge-charge interaction between the + charge developed on S center in the transition state and the cationic micelle. This catalysis is contrary to the enormous micellar inhibition observed with IO4−, HSO5− and HCO4− oxidation of organic sulfides. 相似文献
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Arumugam Vasudevan Gayathri Devi Gurusamy Rajkumar Kathiresan Sakthipandi Venkatachlam Rajendran Nallaiyan Rajendran Mani Rajkumar 《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):1434-1449
Abstract Phosphate-based bioactive glasses and their glass ceramics for 47P2O5– (30.5)CaO–(22.5 ? x)Na2O–xZrO2 for different ZrO2 contents (x = 0, 1.5, 3.0, 4.5, and 6.0 mol%) were prepared through melt quenching and controlled heat treatment procedures. The amorphous nature of glasses and the presence of crystalline phases in glass ceramics were studied by means of X-ray diffraction (XRD) studies. The density, molar volume, ultrasonic velocities, attenuation, elastic constants, and microhardness of glass and glass ceramics were used to study the structural changes. The formation of hydroxyapatite layer on the surface of glasses and glass ceramics after immersion in simulated body fluid (SBF) was explored through XRD, Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) analyses. The results indicate that the added ZrO2 increases the crosslink density of glasses, resulting in network stability, and also induces the formation of an apatite layer on the surface of glasses. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献
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R. Anjibabu Samaresh Sau B. Jagan Mohan Reddy Rajkumar Banerjee B.V. Subba Reddy 《Tetrahedron letters》2013
A variety of aldehydes undergo a smooth coupling with (4-methylcyclohex-3-en-1-yl)methanol in the presence of 2 mol % of phosphomolybdic acid in dichloromethane to afford 3-oxabicyclo[3.3.1]non-7-ene in good yields through 3,5-oxonium-ene cyclization under mild conditions. The use of inexpensive, nontoxic, and readily available heteropoly acid catalyst makes this method simple, convenient, and environmental-friendly. 相似文献
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Poly-silicon based superhydrophobic surface (water contact angle >150°) is being fabricated and its electrowetting properties have been studied. The polysilicon thin film has been deposited over patterned gold electrodes. The polysilicon film is structured to form nanoscale features using Reactive Ion Etching. A thin film of HfO2 high k-dielectric is deposited over the structured polysilicon surface. The surface was chemically modified with Trichloro (1H, 1H, 2H, 2H-perfluorooctyl) silane (PFOS). Such a surface showed Superhydrophobic behavior with water contact angle of 172° and roll off angle <3°. The electrowetting properties of the fabricated device was studied by applying a DC voltage between the gold electrode and the droplet. The electrowetting commences when the applied voltage was 18 V and the contact angle is reduced to 152°. As the applied voltage was increased there was decrease in contact angles. 相似文献
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Nitro‐Substituted Bishomocubanes: Synthesis,Characterization, and Application as Energetic Materials 下载免费PDF全文
Sohan Lal Dr. Sundaram Rajkumar Amit Tare Dr. Sasidharakurup Reshmi Prof. Dr. Arindrajit Chowdhury Prof. Dr. Irishi N. N. Namboothiri 《化学:亚洲杂志》2014,9(12):3533-3541
Several high‐energy‐density strained polycyclic compounds nitromethyl‐l,3‐bishomocubane (NMBHC), nitromethylene‐1,3‐bishomocubane (NMyBHC), and bis(nitromethyl)‐1,3‐bishomocubane (DNTMBHC), which were synthesized for the first time from bishomocubanone, hold potential for application as standalone fuels in liquid bipropellant systems or as additives in liquid and solid propellant formulations. DFT analysis at the B3LYP/6‐31G(d) level of theory was employed to optimize the geometries of the compounds and to determine their densities, heats of formation, and various thermodynamic properties. The density specific impulse, determined by using equilibrium thermodynamics, demonstrated an improvement of 75 s for NMBHC and NMyBHC over standard hydrocarbons. The specific impulse with ammonium perchlorate showed an improvement of 25–30 s over hydroxy‐terminated polybutadiene. Thermogravimetric analysis revealed that NMBHC, NMyBHC, and DNTMBHC evaporated readily with activation energies of 58.8, 69.2, and 74.5 kJ mol?1, respectively. 相似文献
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Karuppasamy Kohila Rani Rajkumar Devasenathipathy Jia-Zheng Wang Xiao-Yuan Hui Jian-De Lin Yi-Miao Zhang Liu-Bin Zhao Jian-Zhang Zhou De-Yin Wu Zhong-Qun Tian 《Current Opinion in Electrochemistry》2022
Plasmonic noble metal nanostructures have been targeted due to their strong surface plasmon resonance at photoelectrochemical interfaces. Recently, it has been concluded that, the plasmonic noble metal nanostructures on photoexcitation permit the transfer of effective hot carriers (hot electron/hole pair) to nearby adsorbed molecules where, the transformed hot carriers can efficiently decrease the activation barrier of a reaction. In this review, our recent achievements in the plasmon-mediated chemical reactions of organic molecules such as para-aminothiophenol, substituted para-aminothiophenol and para-nitrothiophenol at nanostructures modified noble metal electrodes using surface enhanced Raman spectroscopy, electrochemical methods, and theoretical calculations will be discussed. 相似文献
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