排序方式: 共有27条查询结果,搜索用时 15 毫秒
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Joan Albaigés Josep M. Bayona Pilar Fernandez Joan Grimalt Antoni Rosell Rafel Simó 《Mikrochimica acta》1991,104(1-6):13-27
An analytical procedure is described for a comprehensive determination of the composition of hydrocarbons in the atmosphere, based on: (a) aerosol filtration and subsequent adsorption of the vapor phase onto active charcoal and polyurethane foam; (b) GPC and HPLC fractionation of the extracts, and (c) analysis of the fractions by GC-MS under EI and NICI modes. Special emphasis is placed onn-alkanes, PAHs and their oxygenated derivatives.The characterization of samples collected in a coastal urban area (Barcelona city), and far away over the Western Mediterranean, at sea level and at 1100 m of altitude, revealed significant changes in the aerosol composition, mainly attributed to initial vapor-particle partitioning processes, influenced by ambient temperature variations, and to others taking place during long-range atmospheric transport, related with the different compound photoreactivities and with an unexplained source-decoupling phenomenon. 相似文献
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Diego A. Ochoa Rafel Pérez Jose E. García 《Applied Physics A: Materials Science & Processing》2013,112(4):1081-1088
The alteration of the high-field electrical permittivity (nonlinear response) of PZT-based ceramics when an electrical bias field is applied is reported in this work. Large differences are observed between soft and hard PZT behaviours. While in soft PZT a bias field does not modify the nonlinear behaviour, a notable dependence is verified in hard PZT. The Preisach model is satisfactorily used to describe experimental results. A distribution function containing the first terms of the Maclaurin development series of a function composed by two Gaussian-like functions of different amplitudes is proposed. The model gives a satisfactory explanation for the fact that the permittivity depends not only on the amplitude of the applied electric field, but also on the bias field, both for soft and hard ceramics and for poled or unpoled samples. 相似文献
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We present a generator of virtual molecules that selects valid chemistry on the basis of the octet rule. Also, we introduce a mesomer group key that allows a fast detection of duplicates in the generated structures. Compared to existing approaches, our model is simpler and faster, generates new chemistry and avoids invalid chemistry. Its versatility is illustrated by the correct generation of molecules containing third-row elements and a surprisingly adept handling of complex boron chemistry. Without any empirical parameters, our model is designed to be valid also in unexplored regions of chemical space. One first unexpected finding is the high prevalence of dipolar structures among generated molecules. 相似文献
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We study the degree of elimination of imaginaries needed for the three main applications: to have canonical bases for types over models, to define strong types as types over algebraically closed sets and to have a Galois correspondence between definably closed sets B such that A ? B ? acl(A) and closed subgroups of the Galois group Aut(acl(A)/A). We also characterize when the topology of the Galois group is the quotient topology. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Rodrigues Ana Luísa Marques Rosa Dias Maria Isabel Prudêncio Maria Isabel Cardoso Guilherme Russo Dulce Fontanals Núria Rafel Soriano Eni 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(3):1397-1408
Journal of Radioanalytical and Nuclear Chemistry - Modern mining activities often leads to destruction of archaeological records, making difficult to date the contexts and tools. In this work, a... 相似文献
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Salvador Toms Rafel Prohens Ghislain Deslongchamps Pablo Ballester Antoni Costa 《Angewandte Chemie (International ed. in English)》1999,38(15):2208-2211
A set of weak CH⋅⋅⋅O interactions is responsible for the recognition of tetraalkylammonium ions (ball-and-stick structure) by the tripodal receptors depicted in the diagram, in which the binding pocket is lined with squaramide units. The association constants of the fluorescent receptors are remarkably high at about 105 M −1 and can be used for signaling the presence of selected choline phospholipids. Z=RNH, where R=alkyl, arylamino; X−=BH4−, Cl−, Br−, I−. 相似文献
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Rafel Carreras-Patxot Raymund Sänger 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1958,9(4):375-380
Zusammenfassung Es wird eine neue Methode entwickelt zur Erfassung der Diffusion des zur künstlichen Wetterbeeinflussung verwendeten AgI-Rauches in der freien Atmosphäre. Der durch Verwendung von I131 radioaktiv gemachte AgI-Rauch wird in speziellen Papierfiltern, die am Messflugzeug befestigt sind, aufgefangen; mittels eines chemischen Prozesses wird das AgI aus den Filtern gelöst und sodann auf eine Kernphotoplatte gebracht, wo die Zahl der -Spuren ein Mass für die Anzahl der in der Luft gefundenen AgI-Partikel darstellt.
Paper presented at the 3rd International Symposium on Atmospheric Condensation Nuclei, Cambridge, England, July 16–18, 1958. 相似文献
Paper presented at the 3rd International Symposium on Atmospheric Condensation Nuclei, Cambridge, England, July 16–18, 1958. 相似文献
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Nicola Mingirulli Jan Haschke Ralf Gogolin Rafel Ferré Tim F. Schulze J. Düsterhöft Nils‐Peter Harder Lars Korte Rolf Brendel Bernd Rech 《固体物理学:研究快报》2011,5(4):159-161
We present back‐contacted amorphous/crystalline silicon heterojunction solar cells (IBC‐SHJ) on n‐type substrates with fill factors exceeding 78% and high current densities, the latter enabled by a SiNx /SiO2 passivated phosphorus‐diffused front surface field. Voc calculations based on carrier lifetime data of reference samples indicate that for the IBC architecture and the given amorphous silicon layer qualities an emitter buffer layer is crucial to reach a high Voc, as known for both‐side contacted silicon heterojunction solar cells. A back surface field buffer layer has a minor influence. We observe a boost in solar cell Voc of 40 mV and a simultaneous fill factor reduction introducing the buffer layer. The aperture‐area efficiency increases from 19.8 ± 0.4% to 20.2 ± 0.4%. Both, efficiencies and fill factors constitute a significant improvement over previously reported values. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献