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Aladdin Shamilov 《Physica A》2007,382(2):465-472
In the present study we have formulated a generalization of entropy optimization problems (GEOP), proposed sufficient conditions for the existence of solution. We have suggested also a new method based on a priori evaluations and Newton's methods for calculation of Langrange multipliers. Mentioned method allows calculating Langrange multipliers by starting from arbitrary initial point for Newton's approximations of constructed auxiliary equation. The solution of auxiliary equation is chosen as initial point for second constructed auxiliary equation. The recurring mentioned process for finite time leads to achieve an initial point for Newton's approximations of given equation and allows to find its unknown solution. 相似文献
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Maksim Kukushkin Vladimir Novotortsev Vadim Filatov Yan Ivanenkov Dmitry Skvortsov Mark Veselov Radik Shafikov Anna Moiseeva Nikolay Zyk Alexander Majouga Elena Beloglazkina 《Molecules (Basel, Switzerland)》2021,26(24)
A series of novel S-, O- and Se-containing dispirooxindole derivatives has been synthesized using 1,3-dipolar cycloaddition reaction of azomethine ylide generated from isatines and sarcosine at the double C=C bond of 5-indolidene-2-chalcogen-imidazolones (chalcogen was oxygen, sulfur or selenium). The cytotoxicity of these dispiro derivatives was evaluated in vitro using different tumor cell lines. Several molecules have demonstrated a considerable cytotoxicity against the panel and showed good selectivity towards colorectal carcinoma HCT116 p53+/+ over HCT116 p53−/− cells. In particular, good results have been obtained for LNCaP prostate cell line. The performed in silico study has revealed MDM2/p53 interaction as one of the possible targets for the synthesized molecules. However, in contrast to selectivity revealed during the cell-based evaluation and the results obtained in computational study, no significant p53 activation using a reporter construction in p53wt A549 cell line was observed in a relevant concentration range. 相似文献
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I. S. Nizamov R. R. Shamilov G. R. Sabirzyanova E. I. Nikitin A. R. Burilov M. A. Pudovik 《Russian Journal of General Chemistry》2012,82(5):859-863
The use of ultrasonic irradiation in the reactions of trialkyl borates with octahydroxytetraoctyl[l 4] metacyclophane allowed us obtaining tetraalkoxyboratocavitands with higher yields and under milder conditions. We first obtained 1,3,2-dioxaborolane and 1,3,2-dioxaborinane derivatives of tetraoctyl[l 4]metacyclophane using ultrasonic irradiation. Boratocavitands were converted into the corresponding amine complexes with isobutylamine. 相似文献
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R. R. Shamilov V. I. Nuzhdin V. F. Valeev Yu. G. Galyametdinov A. L. Stepanov 《Technical Physics》2016,61(11):1698-1703
Multilayer systems consisting of layers of hybrid quantum dots are fabricated. The quantum dots with the CdSe/CdS core/shell structure are chemically synthesized and deposited on the surface of quartz glass that contains ion-synthesized silver nanoparticles in the near-surface region. Silver nanoparticles exhibit optical absorption owing to the localized surface plasmon resonance. Variations in the photoluminescence intensity of the layer related to an increase in the distance from the quartz surface with metal nanoparticles are studied. An increase in the photoluminescence intensity is observed under excitation in the spectral region of the plasmon absorption of silver nanoparticles. An optimal distance between the layers is determined to maximize the enhancement of the photoluminescence of quantum dots in the presence of the near field of metal nanoparticles. 相似文献
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Rafael A. Cherkasov Ilyas S. Nizamov Yevgeniy M. Martianov Lyubov A. Almetkina Yevgeniy N. Nikitin Radik R. Shamilov 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-3):24-26
Abstract Novel organyldithiophosphonic and bis(aryldithiophosphonic) acids were obtained by the reaction of 2,4-diorganyl 1,3,2,4-dithiadiphosphetane-2,4-disulfides with paracetamol, 4-(1H-pyrrol-1-yl)phenol, ethambutol dihydrochloride, vitamin B6, and its acetonide derivatives. 相似文献