全文获取类型
收费全文 | 58085篇 |
免费 | 13528篇 |
国内免费 | 4448篇 |
专业分类
化学 | 56590篇 |
晶体学 | 590篇 |
力学 | 2212篇 |
综合类 | 241篇 |
数学 | 4679篇 |
物理学 | 11749篇 |
出版年
2024年 | 59篇 |
2023年 | 499篇 |
2022年 | 693篇 |
2021年 | 991篇 |
2020年 | 2125篇 |
2019年 | 3381篇 |
2018年 | 1764篇 |
2017年 | 1328篇 |
2016年 | 4400篇 |
2015年 | 4574篇 |
2014年 | 4711篇 |
2013年 | 5707篇 |
2012年 | 4990篇 |
2011年 | 4406篇 |
2010年 | 4324篇 |
2009年 | 4195篇 |
2008年 | 3763篇 |
2007年 | 3061篇 |
2006年 | 2736篇 |
2005年 | 2670篇 |
2004年 | 2323篇 |
2003年 | 1971篇 |
2002年 | 2624篇 |
2001年 | 1931篇 |
2000年 | 1802篇 |
1999年 | 893篇 |
1998年 | 525篇 |
1997年 | 442篇 |
1996年 | 430篇 |
1995年 | 393篇 |
1994年 | 384篇 |
1993年 | 288篇 |
1992年 | 304篇 |
1991年 | 262篇 |
1990年 | 217篇 |
1989年 | 205篇 |
1988年 | 128篇 |
1987年 | 125篇 |
1986年 | 91篇 |
1985年 | 90篇 |
1984年 | 53篇 |
1983年 | 55篇 |
1982年 | 41篇 |
1981年 | 31篇 |
1980年 | 17篇 |
1979年 | 9篇 |
1977年 | 5篇 |
1975年 | 6篇 |
1969年 | 4篇 |
1957年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Zhang Bing Yang Jie-qin Liu Ying Hu Bin Yang Yang Zhao Li Lu Qiang 《Cellulose (London, England)》2022,29(12):6565-6578
Cellulose - Heating is essential in various biomass pre-treatments and thermal conversion processes. It is of practical significance to study the characteristics of cellulose-lignin and... 相似文献
2.
Qianqian Fan Zirui Liu Feng Qiu Prof. Yong Mao Prof. Qingju Liu Prof. Longzhou Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(63):e202202700
The artificially accurate design of nonmetal electrocatalysts’ active site has been a huge challenge because no pure active species with the specific structure could be strictly controlled by traditional synthetic methods. Species with a multiconfiguration in the catalyst hinder identification of the active site and the subsequent comprehension of the reaction mechanism. We have developed a novel electro-assisted molecular assembly strategy to obtain a pure pentagon ring on perfect graphene avoiding other reconstructed structures. More importantly, the active atom was confirmed by the subtle passivation process as the topmost carbon atom. Recognition of the carbon-defect electrocatalysis reaction mechanism was first downsized to the single-atom scale from the experimental perspective. It is expected that this innovative electro-assisted molecular assembly strategy could be extensively applied in the active structure-controlled synthesis of nonmetal electrocatalysts and verification of the exact active atom. 相似文献
3.
Yujie Gao Zhiye Qiu Lei Liu Mengmeng Li Bingjie Xu Dan Yu Dongming Qi Jindan Wu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(15):2191-2212
Refractory wounds have always been an important issue to healthcare systems, whose healing process is always delayed by multiple factors, including bacterial infections, chronic inflammation, and excessive exudates, etc. Employing multifunctional wound dressings is recognized as an effective strategy to deal with refractory wounds, which has yielded promising outcomes in recent years. Among these advanced wound dressings, fibrous dressings have gained growing attention due to their unique merits. Such wound dressings have demonstrated great potential in delivering theranostic agents, such as antibacterial agents, anti-inflammatory drugs, growth factors, and diagnostic probes, etc., for the purposes of accelerating wound healing. This paper reviews the development of multifunctional fibrous dressings and their applications in treating refractory wounds. The construction approaches of novel fibrous dressing with capabilities of antibacterial, anti-inflammation, exudate management and diagnosis were also introduced. Furthermore, the existing problems and challenges are also discussed briefly. 相似文献
4.
Tian Jie Yang Weifeng Chen Min Zheng Minfang Chen Ding Qiu Yusheng 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):1039-1049
Journal of Radioanalytical and Nuclear Chemistry - This study presents a time-efficient method of analysing 210Pb, 210Bi, and 210Po in natural waters. The optimum pH (1.00), temperature... 相似文献
5.
Hu Duo-Duo Gao Qian Dai Jing-Cheng Cui Ru Li Yuan-Bo Li Yuan-Ming Zhou Xiao-Guo Bian Kang-Jie Wu Bing-Bing Zhang Kai-Fan Wang Xi-Sheng Li Yan 《中国科学:化学(英文版)》2022,65(4):753-761
Science China Chemistry - A light-induced, nickel-catalyzed three-component arylsulfonation of 1,3-enynes in the absence of photocatalyst is reported. This methodology exhibited mild conditions,... 相似文献
6.
7.
8.
Chemical versus Electrochemical Synthesis of Carbon Nano‐onion/Polypyrrole Composites for Supercapacitor Electrodes 下载免费PDF全文
Olena Mykhailiv Monika Imierska Martyna Petelczyc Prof. Dr. Luis Echegoyen Dr. Marta E. Plonska‐Brzezinska 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(15):5783-5793
The development of high‐surface‐area carbon electrodes with a defined pore size distribution and the incorporation of pseudo‐active materials to optimize the overall capacitance and conductivity without destroying the stability are at present important research areas. Composite electrodes of carbon nano‐onions (CNOs) and polypyrrole (Ppy) were fabricated to improve the specific capacitance of a supercapacitor. The carbon nanostructures were uniformly coated with Ppy by chemical polymerization or by electrochemical potentiostatic deposition to form homogenous composites or bilayers. The materials were characterized by transmission‐ and scanning electron microscopy, differential thermogravimetric analyses, FTIR spectroscopy, piezoelectric microgravimetry, and cyclic voltammetry. The composites show higher mechanical and electrochemical stabilities, with high specific capacitances of up to about 800 F g?1 for the CNOs/SDS/Ppy composites (chemical synthesis) and about 1300 F g?1 for the CNOs/Ppy bilayer (electrochemical deposition). 相似文献
9.
Dr. Sabin Llona‐Minguez Dr. Matthieu Desroses Artin Ghassemian Dr. Sylvain A. Jacques Dr. Lars Eriksson Rebecka Isacksson Tobias Koolmeister Dr. Pål Stenmark Dr. Martin Scobie Prof. Thomas Helleday 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(20):7394-7398
A two‐step synthesis of structurally diverse pyrrole‐containing bicyclic systems is reported. ortho‐Nitro‐haloarenes coupled with vinylic N‐methyliminodiacetic acid (MIDA) boronates generate ortho‐vinyl‐nitroarenes, which undergo a “metal‐free” nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide substrate tolerance and it is applicable in the preparation of more complex “drug‐like” molecules. Interestingly, an ortho‐nitro‐allylarene derivative furnished a cyclic β‐aminophosphonate motif. 相似文献
10.
Interactions of Pt‐ttpy with G‐Quadruplexes Originating from Promoter Region of the c‐myc Gene Deciphered by NMR and Gel Electrophoresis Analysis 下载免费PDF全文