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排序方式: 共有452条查询结果,搜索用时 578 毫秒
1.
2.
Priya Jaiswal Vijaykumar Ijeri Ashwini Srivastava 《Journal of inclusion phenomena and macrocyclic chemistry》2004,49(3-4):219-224
This paper is a report on the complexation studies of silverions with certain water soluble crown ethers viz., 15-crown-5,18-crown-6, cyclam, diaza 15-crown-5 and certain water insolublecrown ethers viz., benzo 15-crown-5, dibenzodiaza 15-crown-4,dibenzyldiaza 18-crown-6 in some nonionic surfactants viz.,polyoxyethylated alkyl phenol (TX 100), polyoxyethylene (20)sorbiton monolaurate (Tween 20), polyoxyethylene (20) sorbitonmonoleate (Tween 80) and polyoxyethylated glyco monolaurylether (Brij 35) by potentiometry. In addition, conductometry wasalso used to study the complexation of oxa crown ethers to comparethe results obtained by potentiometry, which were found to be ingood agreement with each other. The complexation studies indicate1:1 complex formation between the silver ion and macrocycle, thelogML n+ values being in the range 1 to 9. 相似文献
3.
B Ramachandra Reddy P Radhika J Rajesh Kumar D Neela Priya K Rajgopal 《Analytical sciences》2004,20(2):345-349
Cyanex 923 has been proposed as a sensitive analytical reagent for the direct extractive spectrophotometric determination of cobalt(II). Cobalt(II) forms a blue-colored complex with Cyanex 923 in the organic phase. The maximum absorbance of the complex is measured at 635 nm. Beer's law was obeyed in the range 58.9 - 589.0 microg of cobalt. The molar absorptivitiy and Sandell's sensitivity of the complex was calculated to be 6.79 x 10920 l mol(-1) cm(-1) and 0.088 microg cm(-2), respectively. The nature of the extracted species was found to be Co(SCN)2 x 2S. An excellent linearity with a correlation coefficient value of 0.999 was obtained for the Co(II)-Cyanex 923 complex. Stability and regeneration of the reagent (Cyanex 923) for reuse is the main advantage of the present method. The method was successfully applied to the determination of cobalt in synthetic mixtures and pharmaceutical samples was found to give values close to the actual ones. Standard alloy samples, such as high-speed tool BCS 484 and 485, have been tested for the determination of cobalt for the purpose of validating the present method. The results of the proposed method are comparable with atomic absorption spectrometry and were found to be in good agreement. 相似文献
4.
Ram C. Maurya Deen D. Mishra Surendra K. Jaiswal Sudipta Mukherjee 《Transition Metal Chemistry》1992,17(5):381-383
Some new low-spin hexacoordinated cyanonitrosyl complexes of Cr1 of the type [Cr(NO)(CN)2(L)2(H2)], where L is an aromatic aldehyde oxime or Mannich base, have been prepared by the interaction or K3[Cr(NO)(CN)5]· H2O with L in aqueous AcOH, and characterized by a range of physico-chemical techniques, I.r. data suggest that all the oxime
derivatives and Mannich bases act as monodentate ligands by coordinating through the aromatic nitrogen.
TMC 2564 相似文献
5.
The present paper describes various classification techniques like cluster analysis, principal component (PC)/factor analysis to classify different types of base stocks. The API classification of base oils (Group I-III) has been compared to a more detailed NMR derived chemical compositional and molecular structural parameters based classification in order to point out the similarities of the base oils in the same group and the differences between the oils placed in different groups. The detailed compositional parameters have been generated using and nuclear magnetic resonance (NMR) spectroscopic methods. Further, oxidation stability, measured in terms of rotating bomb oxidation test (RBOT) life, of non-conventional base stocks and their blends with conventional base stocks, has been quantitatively correlated with their NMR and elemental (sulphur and nitrogen) data with the help of multiple linear regression (MLR) and artificial neural networks (ANN) techniques. The MLR based model developed using NMR and elemental data showed a high correlation between the ‘measured’ and ‘estimated’ RBOT values for both training (R=0.859) and validation (R=0.880) data sets. The ANN based model, developed using fewer number of input variables (only NMR data) also showed high correlation between the ‘measured’ and ‘estimated’ RBOT values for training (R=0.881), validation (R=0.860) and test (R=0.955) data sets. 相似文献
6.
H. S. Dang H. B. Desai D. D. Jaiswal S. R. Kayasth S. Somasundaram 《Journal of Radioanalytical and Nuclear Chemistry》1983,77(1):65-70
A simple separation scheme for the analysis of As, Mn, Mo, Cu and Zn using neutron activation is described. It has been checked
using three standard reference materials, A-11 milk powder (IAEA) and bovine liver and orchard leaves (USNBS) and found to
give acceptable results. This scheme was applied for determination of these trace elements in mature human milk samples. The
concentrations of As, Mn, Mo, Cu in samples obtained from two socio-economic groups—low and middle incomes—were not significantly
different. However, Zn levels in samples obtained from the poor income group were significantly lower than in those obtained
from the other group.
Work carried out under Research Contract No. 2598/RB of International Atomic Energy, Vienna.
Health Physics Division.
Analytical Chemistry Division. 相似文献
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9.
Hassan Amirhashchi Anirudh Pradhan Rekha Jaiswal 《International Journal of Theoretical Physics》2013,52(8):2735-2752
Some new exact solutions of Einstein’s field equations have come forth within the scope of a spatially homogeneous and anisotropic Bianchi type-III space-time filled with barotropic fluid and dark energy by considering a variable deceleration parameter. We consider the case when the dark energy is minimally coupled to the perfect fluid as well as direct interaction with it. Under the suitable condition, the anisotropic models approach to isotropic scenario. We also find that during the evolution of the universe, the equation of state (EoS) for dark energy ω (de), in both cases, tends to ?1 (cosmological constant, ω (de)=?1), by displaying various patterns as time increases, which is consistent with recent observations. The cosmic jerk parameter in our derived models are in good agreement with the recent data of astrophysical observations under appropriate condition. It is observed that the universe starts from an asymptotic Einstein static era and reaches to the ΛCDM model. So from recently developed Statefinder parameters, the behaviour of different stages of the universe has been studied. The physical and geometric properties of cosmological models are also discussed. 相似文献
10.
The wavelengths of the vibronic peaks of the low temperature photoluminescence of anthracene, phenanthrene, benzophenone and phthalic acid crystals do not change considerably, but their relative intensity changes significantly with grinding. The dislocations may change both the absorption coefficient and absorption spectra of the crystals, hence the photoluminescence emission may be affected by the grinding. 相似文献